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1. 发明授权

US09012547B2 Hydrosilylation cured silicone resins plasticized by organophosphorous compounds 有权
标题翻译：由有机磷化合物增塑的硅烷化固化硅树脂
公开(公告)号：US09012547B2
公开(公告)日：2015-04-21
申请号：US13820867
申请日：2011-10-31
申请人： Marilyn P. Shope , Bizhong Zhu
发明人： Marilyn P. Shope , Bizhong Zhu
IPC分类号： C08L83/06 , C09J183/06 , C08L83/04 , C08K5/521 , C08K5/523 , C09J183/04 , B32B5/02 , B32B7/12 , B32B27/20 , B32B27/28 , C08J5/24 , C08G77/12 , C08K5/5419 , C08K5/5425 , C08G77/20
CPC分类号： C08L83/06 , B32B5/02 , B32B7/12 , B32B27/20 , B32B27/283 , B32B2260/021 , B32B2260/046 , B32B2307/412 , C08G77/12 , C08G77/20 , C08J5/24 , C08J2383/04 , C08K5/521 , C08K5/523 , C08K5/5419 , C08K5/5425 , C08L83/04 , C09J183/04 , C09J183/06 , Y10T428/31663 , C08L83/00
摘要： In various embodiments, provided are novel curable silicone compositions; films and adhesives comprising one or more cured products of said compositions, the films and adhesives exhibiting properties of mechanical flexibility and low flammability. Additionally, the films and adhesives may exhibit one or more of high transparency, low haze, and high refractive index.
摘要翻译：在各种实施方案中，提供了新的可固化硅氧烷组合物; 包括所述组合物的一种或多种固化产物的膜和粘合剂，所述膜和粘合剂具有机械柔性和低可燃性的特性。此外，膜和粘合剂可以表现出高透明度，低雾度和高折射率的一种或多种。

2. 发明授权

US08912268B2 Silicone resin film, method of preparing same, and nanomaterial-filled silicone composition 有权
标题翻译：硅树脂膜，其制备方法和纳米材料填充的有机硅组合物
公开(公告)号：US08912268B2
公开(公告)日：2014-12-16
申请号：US12086448
申请日：2006-11-22
申请人： Mark David Fisher , Bizhong Zhu
发明人： Mark David Fisher , Bizhong Zhu
IPC分类号： C08K3/04 , B32B9/04 , C08J5/00 , B82Y30/00 , C08J5/18 , C08L83/04 , C09D183/04 , C08G77/12 , C08G77/20
CPC分类号： C08J5/005 , B82Y30/00 , C08G77/12 , C08G77/20 , C08J5/18 , C08J2383/04 , C08K3/04 , C08L83/04 , C09D183/04 , H01L31/0481 , Y02E10/50 , Y10T428/31663 , C08L83/00 , C08K3/046 , C08K5/56
摘要： A method of preparing a silicone resin film, the method comprising coating a release liner with a nanomaterial-filled silicone composition comprising a hydrosilylation-curable silicone composition and a carbon nanomaterial, and heating the coated release liner at a temperature sufficient to cure the silicone resin; a silicone resin film prepared according to the preceding method; and a nanomaterial-filled silicone composition.
摘要翻译：一种制备有机硅树脂膜的方法，该方法包括用包含氢化硅烷化可固化的硅氧烷组合物和碳纳米材料的纳米材料填充的硅氧烷组合物涂覆剥离衬垫，并在足以固化硅树脂的温度下加热涂覆的剥离衬垫 ; 根据前述方法制备的有机硅树脂膜; 和纳米材料填充的硅氧烷组合物。

3. 发明授权

US08840999B2 Silicone composition and a method for preparing the same 有权
标题翻译：硅酮组合物及其制备方法
公开(公告)号：US08840999B2
公开(公告)日：2014-09-23
申请号：US13129926
申请日：2009-11-18
申请人： Yukinari Harimoto , Bizhong Zhu
发明人： Yukinari Harimoto , Bizhong Zhu
IPC分类号： B32B17/10 , C08L83/04 , C08K3/22 , C08K9/08 , C09C1/30 , C09C3/12 , C09C1/36 , C09C1/00 , C09C1/40 , C08G77/00 , C08G77/12 , C08G77/20
CPC分类号： C09C1/00 , C01P2006/22 , C01P2006/60 , C08G77/12 , C08G77/20 , C08G77/70 , C08K9/08 , C08L83/04 , C09C1/3081 , C09C1/3684 , C09C1/407 , C09C3/12 , Y10T428/2852 , Y10T428/31612 , C08L2666/54
摘要： A silicone composition comprises (a) a curable silicone resin, (b) an inorganic particle having a polymeric surface coating formed thereon, and (c) a cross-linking compound. The (a) curable silicone resin comprises units having a functional group R1 selected from an aryl group, an alkyl group, an alkenyl group, and hydrogen. The polymeric surface coating comprises an organopolysiloxane. The organopolysiloxane comprises units selected from R23SiO1/2, R22SiO2/2, R2SiO3/2, and combinations thereof. R2 is selected from an aryl group, an alkyl group, an alkenyl group, hydrogen, and combinations thereof, and R1 equals R2. The (c) cross-linking compound is reactive with at least one of (a) and the polymeric surface coating.
摘要翻译：有机硅组合物包含（a）可固化有机硅树脂，（b）其上形成有聚合物表面涂层的无机颗粒，和（c）交联化合物。（a）可固化有机硅树脂包括具有选自芳基，烷基，烯基和氢的官能团R1的单元。聚合物表面涂层包含有机聚硅氧烷。有机聚硅氧烷包括选自R 23 SiO 1/2，R 22 SiO 2/2，R 2 SiO 3/2的单元及其组合。 R2选自芳基，烷基，烯基，氢及其组合，并且R 1等于R 2。（c）交联化合物与（a）和聚合物表面涂层中的至少一种具有反应性。

4. 发明申请

US20130149520A1 PHOSPHOSILOXANE RESINS, AND CURABLE SILICONE COMPOSITIONS, FREE-STANDING FILMS, AND LAMINATES COMPRISING THE PHOSPHOSILOXANE RESINS 有权
标题翻译：磷硅氧烷树脂和可固化的硅氧烷组合物，自由表面膜和包含磷硅氧烷树脂的层压材料
公开(公告)号：US20130149520A1
公开(公告)日：2013-06-13
申请号：US13817647
申请日：2011-08-23
申请人： Bizhong Zhu
发明人： Bizhong Zhu
IPC分类号： C08G79/04 , B32B7/12 , B32B27/28
CPC分类号： C08G79/04 , B32B7/12 , B32B27/283 , C08G77/30 , C08G77/48 , C08L83/08 , Y10T428/31663
摘要： A phosphosiloxane resin comprises a plurality of covalently bonded monomer units selected from phosphosiloxane units SiR23—O—P(═O)(R1)(OR3)q(O1/2—)p, and organosiloxane units R2m(OR3)nSiO(4-m-n)/2. R1 and each R2 are independently selected from the group consisting of hydrogen, C1 to C10 hydrocarbyl, and C1 to C10 hydrocarbylene; each R3 is independently selected from the group consisting of hydrogen and C1 to C10 hydrocarbyl; p is 0 or 1; q=1−p; m is 0, 1, 2, 3, or 4; n is 0, 1, or 2; and m+n is 0, 1, 2, 3, or 4. Curable silicone compositions comprise a phosphosiloxane resin having greater than one silicon-bonded alkenyl group, an organosilicon compound having at least two silicon-bonded hydrogen atoms, and a hydrosilylation catalyst. Fiber-reinforced free-standing films may comprise fibers dispersed in a cured product of the silicone composition. Laminated substrates comprise at least one fiber-reinforced free-standing film.
摘要翻译：磷硅氧烷树脂包括选自磷硅氧烷单元SiR23-OP（= O）（R1）（OR3）q（O1 / 2-）p和有机硅氧烷单元R2m（OR3）nSiO（4-mn））的多个共价键合的单体单元， / 2。 R 1和R 2各自独立地选自氢，C 1至C 10烃基和C 1至C 10亚烃基; 每个R 3独立地选自氢和C 1至C 10烃基; p为0或1; q = 1-p; m是0,1,2,3或4; n为0,1或2; 并且m + n为0,1,2,3或4.可固化的硅氧烷组合物包含具有大于一个硅键合的烯基的磷硅氧烷树脂，具有至少两个与硅键合的氢原子的有机硅化合物和氢化硅烷化催化剂。纤维增强的自立膜可以包括分散在硅氧烷组合物的固化产物中的纤维。层压基材包括至少一种纤维增强的自立膜。

5. 发明授权

US08088449B2 Reinforced silicone resin film and method of preparing same 失效
标题翻译：增强硅树脂薄膜及其制备方法
公开(公告)号：US08088449B2
公开(公告)日：2012-01-03
申请号：US11794925
申请日：2006-02-01
申请人： Debbie Bailey , Dimitris Elias Katsoulis , Michitaka Suto , Bizhong Zhu
发明人： Debbie Bailey , Dimitris Elias Katsoulis , Michitaka Suto , Bizhong Zhu
IPC分类号： B05D3/02
CPC分类号： C08J5/04 , C08J2383/04 , C08L83/04 , C08L83/00
摘要： A method of preparing a reinforced silicone resin film, the method comprising the steps of impregnating a fiber reinforcement in a condensation-curable silicone composition comprising a silicone resin, and curing the silicone resin in the condensation-curable silicone composition of the impregnated fiber reinforcement; wherein the reinforced silicone resin film comprises from 10 to 99% (w/w) of the cured silicone resin and the film has a thickness of from 15 to 500 μm; and a reinforced silicone resin film prepared according to the method.
摘要翻译：一种制备增强有机硅树脂膜的方法，所述方法包括以下步骤：将纤维增强物浸渍在包含硅树脂的可缩合固化的硅氧烷组合物中，并使浸渍的纤维增强物的可缩合固化的硅氧烷组合物中的硅树脂固化; 其中所述增强硅树脂膜包含10至99％（w / w）的所述固化的有机硅树脂，并且所述膜具有15至500μm的厚度; 和根据该方法制备的增强硅树脂膜。

6. 发明申请

US20110240103A1 SOLAR CELL INCLUDING A SILICONE RESIN LAYER 审中-公开
标题翻译：太阳能电池，包括硅树脂层
公开(公告)号：US20110240103A1
公开(公告)日：2011-10-06
申请号：US12303311
申请日：2008-07-30
申请人： Bizhong Zhu , Dimitris E. Katsoulis
发明人： Bizhong Zhu , Dimitris E. Katsoulis
IPC分类号： H01L31/02 , H01L31/0256
CPC分类号： C09D183/04 , H01L31/0392 , H01L31/0481 , Y02E10/50
摘要： The present invention provides a solar cell having a silicone resin layer. The solar cell comprises a silicone resin film that is at least partially cured and a photovoltaic element formed adjacent the silicone resin film.
摘要翻译：本发明提供一种具有硅树脂层的太阳能电池。太阳能电池包括至少部分固化的硅树脂膜和邻近有机硅树脂膜形成的光电元件。

7. 发明申请

US20110014482A1 DUCTILE MULTILAYER SILICONE RESIN FILMS 审中-公开
标题翻译：多层多层硅树脂膜
公开(公告)号：US20110014482A1
公开(公告)日：2011-01-20
申请号：US12303330
申请日：2007-06-04
申请人： Bizhong Zhu , Dimitris E. Katsoulis , Manish Deopura , Andrew Satorius , Raymond L. Tabler , Richard Rabe , Gifford N. Shearer
发明人： Bizhong Zhu , Dimitris E. Katsoulis , Manish Deopura , Andrew Satorius , Raymond L. Tabler , Richard Rabe , Gifford N. Shearer
IPC分类号： B32B25/20 , B29C47/06 , B29C47/14
CPC分类号： B32B25/20 , B01F5/0641 , B29B7/325 , B29C48/05 , B29C48/08 , B29C48/19 , B29C48/21 , B29C48/22 , B29C48/255 , B29C48/285 , B29C48/286 , B29C48/2886 , B29C48/30 , B29C48/305 , B29C48/49 , B29C48/71 , B29C48/911 , B29C48/919 , B29C55/023 , B29C55/06 , B29K2083/00 , B29K2105/16 , B32B27/28 , B32B37/153 , B32B38/0008 , B32B2310/0481 , B32B2310/14 , Y10T428/31663
摘要： The present invention provides a method of forming ductile multilayer silicone resin films. The method may include forming a silicone resin film comprising at least two polymer layers, at least one of them being a silicone resin layer. The thickness of the silicone resin layer(s) is less than a corresponding ductile transition thickness.
摘要翻译：本发明提供一种形成延性多层硅树脂膜的方法。该方法可以包括形成包含至少两个聚合物层的有机硅树脂膜，其中至少一个是有机硅树脂层。有机硅树脂层的厚度小于对应的延性转变厚度。

8. 发明申请

US20100210159A1 FIBER STRUCTURE AND METHOD OF MAKING SAME 审中-公开
标题翻译：纤维结构及其制造方法
公开(公告)号：US20100210159A1
公开(公告)日：2010-08-19
申请号：US12670749
申请日：2008-07-24
申请人： Bizhong Zhu
发明人： Bizhong Zhu
IPC分类号： D03D25/00 , B32B37/15 , D02G3/36
CPC分类号： D01D5/0084 , C03C25/1095 , C04B35/6224 , C04B35/62849 , C04B35/62889 , C04B35/82 , C04B2235/5256 , C04B2235/5264 , D01D5/38 , D04H1/4374 , D04H1/728 , Y10T428/2933 , Y10T428/2964 , Y10T442/20
摘要： A fiber structure and method of making the same are provided. The fiber structure comprises a microfiber structure having a nanofiber thereon. The nanofiber is formed by electrospinning a precursor solution to form a precursor nanofiber. The electrospun precursor nanofiber is deposited on the microfiber structure and fused therewith. In one preferable embodiment, silica nanofibers are formed on and fused with a glass microfiber.
摘要翻译：提供了一种纤维结构及其制造方法。纤维结构体包括其上具有纳米纤维的微纤维结构。通过静电纺丝前体溶液形成前体纳米纤维形成纳米纤维。电纺丝前体纳米纤维沉积在超细纤维结构上并与其融合。在一个优选的实施方案中，二氧化硅纳米纤维在玻璃微纤维上形成并与其融合。

9. 发明申请

US20100209687A1 Reinforced Silicone Resin Film and Nanofiber-Filled Silicone Composition 审中-公开
标题翻译：增强硅树脂薄膜和纳米纤维填充硅酮组合物
公开(公告)号：US20100209687A1
公开(公告)日：2010-08-19
申请号：US12676465
申请日：2008-09-03
申请人： Bizhong Zhu
发明人： Bizhong Zhu
IPC分类号： B32B5/00 , C08K3/22 , B32B27/00 , B32B27/12
CPC分类号： C08J5/005 , B82Y30/00 , C08J5/18 , C08J2383/04 , C08K3/22 , C08K7/08 , C08K7/14 , C09D7/70 , C09D183/04 , Y10T428/269 , Y10T428/31663 , Y10T442/3854 , Y10T442/674 , C08L83/04 , C08L2666/54
摘要： A reinforced silicone resin film comprising at least one polymer layer, wherein at least one of the polymer layers comprises a cured product of at least one silicone resin, and at least one of the polymer layers comprises aluminum oxide nanofibers, wherein the nanofibers comprise at least one aluminum oxide selected from γ-AlO(OH) and γ-Al203; and a nanofiber-filled silicone composition comprising the aluminum oxide nanofibers.
摘要翻译：一种增强的有机硅树脂薄膜，包括至少一个聚合物层，其中至少一个聚合物层包括至少一种硅树脂的固化产物，并且至少一个聚合物层包含氧化铝纳米纤维，其中纳米纤维至少包含一种选自γ-AlO（OH）和γ-Al2O3的氧化铝; 以及包含所述氧化铝纳米纤维的纳米纤维填充的硅氧烷组合物。

10. 发明申请

US20100086760A1 Reinforced Silicone Resin Films 失效
标题翻译：增强硅树脂薄膜
公开(公告)号：US20100086760A1
公开(公告)日：2010-04-08
申请号：US12527585
申请日：2008-01-31
申请人： Bizhong Zhu
发明人： Bizhong Zhu
IPC分类号： B32B27/06 , B32B9/04
CPC分类号： B82Y30/00 , C08G77/12 , C08G77/20 , C09D183/04 , Y10T428/24967 , Y10T428/24975 , Y10T428/25 , Y10T428/31663 , C08L83/00
摘要： Reinforced silicone resin films comprising at least two polymer layers, wherein at least one of the polymer layers comprises a cured product of a at least one silicone resin having an average of at least two silicon-bonded alkenyl groups or silicon-bonded hydrogen atoms per molecule, and at least one of the polymer layers comprises a carbon nanomaterial.
摘要翻译：包含至少两个聚合物层的增强有机硅树脂膜，其中至少一个聚合物层包含至少一种有机硅树脂的固化产物，其平均具有至少两个硅键合的链烯基或每个分子硅键合的氢原子，并且至少一个聚合物层包含碳纳米材料。

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