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    • 4. 发明授权
    • Polyamide blend molding compound
    • 聚酰胺共混物模塑料
    • US08932693B2
    • 2015-01-13
    • US12845797
    • 2010-07-29
    • Botho HoffmannRalph Kettl
    • Botho HoffmannRalph Kettl
    • B32B1/08C08L77/06C08L77/02F16L9/127B32B1/02C08L23/20
    • C08L77/06C08L23/20C08L77/02C08L2205/02C08L2205/035F16L9/127Y10T428/13Y10T428/1303Y10T428/1352Y10T428/1359Y10T428/139C08L2666/20C08L2666/06C08L2666/02
    • Polyamide blend molding compound, includes a polyamide blend content and at least one impact-resistant component, characterized in that the polyamide blend content includes the following polyamides: (A) 20 to 65% by weight of at least one semi-crystalline polyamide with an enthalpy of fusion >40 J/g and with an average of at least 8 C atoms per monomeric unit; (B) 8 to 25% by weight of at least one amorphous and/or microcrystalline polyamide, with the microcrystalline polyamide having an enthalpy of fusion in the range of 4 to 40 J/g, and (C) 1 to 20% by weight of at least one polyamide with an average of a maximum of 6 C atoms per monomeric unit. The impact-resistant component includes as follows: (D) 10 to 40% by weight of a polyamide elastomer which is composed of hard segments and soft segments, with the hard segments being based on lactams and/or amino-carboxylic acids, and (E) 0 to 35% by weight of a non-polyamide elastomer.
    • 聚酰胺共混物模塑料包括聚酰胺共混物含量和至少一种耐冲击组分,其特征在于所述聚酰胺共混物含量包括以下聚酰胺:(A)20至65重量%的至少一种半结晶聚酰胺,其具有 熔化焓> 40J / g,平均每个单体单元至少8个C原子; (B)8至25重量%的至少一种无定形和/或微晶聚酰胺,微晶聚酰胺的熔融焓在4至40J / g的范围内,(C)1至20重量% 的至少一种平均每个单体单元最多6个C原子的聚酰胺。 抗冲击组分包括如下:(D)10-40重量%的由硬链段和软链段组成的聚酰胺弹性体,硬链段基于内酰胺和/或氨基羧酸,和( E)0至35重量%的非聚酰胺弹性体。
    • 5. 发明申请
    • TRANSPARENT POLYAMIDE ELASTOMERS
    • 透明聚酰胺弹性体
    • US20140134371A1
    • 2014-05-15
    • US14065187
    • 2013-10-28
    • Botho HOFFMANNHeinz HOFF
    • Botho HOFFMANNHeinz HOFF
    • C08G69/26B29C45/00B29C39/00B29C47/00
    • C08G69/26B29C39/006B29C45/0001B29C48/022C08G69/08C08G69/265C08G69/36C08G69/40C08G69/44Y10T428/139Y10T428/1397
    • A transparent polyamide elastomer of the general structure (I), where R1 is a polyamide segment formed from a) 10-100 mol % of alkyl-substituted bis(aminocyclohexyl)methane or bis(aminocyclohexyl)propane and 0-90 mol % of other cycloaliphatic, aliphatic or aromatic C6-C36 diamines, based on the total amount of diamine in the polyamide segment, and b) aliphatic C4-C36 dicarboxylic acids, cycloaliphatic or aromatic C8-C36 dicarboxylic acids, and c) optionally lactams or aminocarboxylic acids C6-C12, R2 being selected from the group of the divalent radicals: linear or branched C2-C5 polyoxyalkylene, polyolefin, polysiloxane with a number-average molar mass in the range of 200-3000 g/mol, C2-C36 alkylene, C6-C36 cycloalkylene, C6-C20 aryl, polycaprolactone, polyesters based on aliphatic or cycloaliphatic dicarboxylic acids and diols, aliphatic polycarbonate, and also copolymers of or mixtures of these elements, and X1 and X2 independently of one another being amide (CONH) or ester (COO) bonds.
    • 一种通式(I)的透明聚酰胺弹性体,其中R1是由a)10-100摩尔%的烷基取代的双(氨基环己基)甲烷或双(氨基环己基)丙烷和0-90摩尔%的其它 脂族或芳族C 6 -C 36二胺,基于聚酰胺链段中二胺的总量,和b)脂族C 4 -C 36二羧酸,脂环族或芳族C 8 -C 36二羧酸,和c)任选的内酰胺或氨基羧酸C6 -C12,R2选自二价基团:直链或支链C 2 -C 5聚氧化烯,聚烯烃,数均摩尔质量在200-3000g / mol范围内的聚硅氧烷,C2-C36亚烷基,C6- C 36亚环烷基,C 6 -C 20芳基,聚己内酯,基于脂族或脂环族二羧酸和二醇的聚酯,脂族聚碳酸酯,以及这些元素的共聚物或这些元素的混合物,X 1和X 2彼此独立地为酰胺(CONH)或酯 首席运营官)博 nds。
    • 6. 发明授权
    • Semiaromatic moulding compositions and uses of these
    • 半芳族成型组合物及其用途
    • US08420221B2
    • 2013-04-16
    • US12949945
    • 2010-11-19
    • Manfred HewelBotho HoffmannAndreas Bayer
    • Manfred HewelBotho HoffmannAndreas Bayer
    • B32B27/08B32B27/34
    • C08G69/265B29C47/38C08L77/06Y10T428/13Y10T428/139Y10T428/31725C08L2666/02
    • A polyamide molding composition with the following constitution is described: (a) from 40 to 90% by weight of a copolyamide, where this is composed of (a1) 1,6-hexanediamine and 1,10-decanediamine and also (a2) terephthalic acid and at least one other polyamide-forming monomer selected from the group of: dicarboxylic acid having from 8 to 18 carbon atoms, laurolactam, aminolauric acid, and/or mixtures thereof; (b) from 10 to 40% by weight of macromolecular plasticizers, with the proviso that these can have been replaced to some extent by low-molecular-weight plasticizers; (c) from 0 to 20% by weight of additives and/or added substances. Uses of this type of molding composition are also described, in particular for the production of a fuel line, cooling line, oil line or urea line for the automobile sector, as also are production processes to give moldings.
    • 描述了具有以下结构的聚酰胺模塑组合物:(a)40-90重量%的共聚酰胺,其由(a1)1,6-己二胺和1,10-癸二胺组成,和(a2)对苯二甲酸 酸和至少一种其它选自以下的聚酰胺形成单体:具有8至18个碳原子的二羧酸,月桂内酰胺,氨基月桂酸和/或其混合物; (b)10〜40重量%的大分子增塑剂,条件是这些可以在一定程度上被低分子增塑剂代替; (c)0至20重量%的添加剂和/或添加物质。 还描述了这种类型的成型组合物的用途,特别是用于生产用于汽车部门的燃料管线,冷却管线,油管线或尿素管线,以及制造成型品的生产方法。
    • 7. 发明申请
    • BRAKE BOOSTER LINE
    • 刹车线
    • US20120000562A1
    • 2012-01-05
    • US13172378
    • 2011-06-29
    • Botho HOFFMANNRalph KETTLLuc SCHERRER
    • Botho HOFFMANNRalph KETTLLuc SCHERRER
    • F16L11/00
    • C08L77/02B60T17/043C08L9/02C08L23/16C08L23/18C08L23/20C08L77/06C08L2205/02C08L2205/03C08L2205/035F16L9/12
    • A partial vacuum brake booster line is produced from a polyamide blend molding compound having a polyamide blend component and an impact resistance component. The polyamide blend component of the polyamide blend molding compound comprises the following polyamides: (A) 25 to 65 wt.-% of at least one partially crystalline polyamide having a melt enthalpy of >40 J/g and having an average of at least 8 C atoms per monomer unit, selected from a group which consists of the polyamides PA 11, PA 610, PA 612, PA 1010, PA 106, PA 106/10T, PA 614, and PA 618; (B) 0 to 25 wt.-% of at least one amorphous and/or microcrystalline polyamide, the microcrystalline polyamide having a melt enthalpy in the range from 4 to 40 J/g; and (C) 1 to 55 wt.-% of at least one polyamide having an average of at most 6 C atoms per monomer unit. The impact resistance component is formed from: (D) 5 to 35 wt.-% of a non-polyamide elastomer or of a mixture of non-polyamide elastomers. All specifications in wt.-% relate to the total weight of the polyamide blend molding compound and add up, optionally supplemented by also added commercially available additives, to 100 wt.-%. In addition, the partial vacuum brake booster line according to the invention is implemented as a single-layer extruded pipe and has a modulus of elasticity of at least 50 MPa at +180° C. The average number of C atoms per monomer unit is calculated for the polyamides from the sum of the number of C atoms in the monomers used divided by the number of monomers used.
    • 由具有聚酰胺共混组分和耐冲击组分的聚酰胺共混物模塑料生产部分真空制动助力线。 聚酰胺共混物模塑料的聚酰胺共混物组分包括以下聚酰胺:(A)25至65重量%的至少一种熔体焓> 40J / g并且平均至少为8的部分结晶的聚酰胺 每个单体单元的C原子,选自由聚酰胺PA 11,PA 610,PA 612,PA 1010,PA 106,PA 106 / 10T,PA 614和PA 618组成的组。 (B)0至25重量%的至少一种无定形和/或微晶聚酰胺,所述微晶聚酰胺的熔体焓在4至40J / g的范围内; 和(C)1至55重量%的至少一种每单体单元平均具有至多6个C原子的聚酰胺。 耐冲击性成分由以下组成:(D)5-35重量%的非聚酰胺弹性体或非聚酰胺弹性体混合物。 所有重量百分比的规格都涉及聚酰胺共混物模塑料的总重量,并且加上任选地还加入市售的添加剂,添加到100重量%。 此外,根据本发明的部分真空制动增压管线被实施为单层挤出管,并且在+ 180℃下具有至少50MPa的弹性模量。计算每个单体单元的平均C原子数 对于聚酰胺,由所使用的单体中的C原子数的总和除以所使用的单体数。
    • 9. 发明申请
    • TRANSPARENT POLYAMIDE ELASTOMERS
    • 透明聚酰胺弹性体
    • US20100203275A1
    • 2010-08-12
    • US12670306
    • 2008-07-17
    • Botho HoffmannHeinz Hoff
    • Botho HoffmannHeinz Hoff
    • C08G69/08B32B1/08B29C45/00
    • C08G69/26B29C39/006B29C45/0001B29C48/022C08G69/08C08G69/265C08G69/36C08G69/40C08G69/44Y10T428/139Y10T428/1397
    • A description is given, together with preferred applications, of a transparent polyamide elastomer of the general structure (I), where R1 is a polyamide segment formed from (a) 10-100 mol % of alkyl-substituted bis(aminocyclohexyl)methane and/or bis(aminocyclohexyl)propane and 0-90 mol % of other cycloaliphatic C6-C36 diamines and/or aliphatic C2-C36 diamines and/or aromatic C6-C36 diamines, the concentration figures being based on the total amount of diamine in the polyamide segment, and (b) aliphatic C4-C36 dicarboxylic acids and/or cycloaliphatic C8-C36 dicarboxylic acids and/or aromatic C8-C36 dicarboxylic acids, and (c) optionally lactams and/or aminocarboxylic acids C6-C12, R2 being selected from the group of the divalent radicals: linear or branched C2-C5 polyoxyalkylene, polyolefin, polysiloxane with a number-average molar mass in the range of 200-3000 g/mol, linear or branched, substituted or unsubstituted C2-C36 alkylene, C6-C36 cycloalkylene, C6-C20 aryl, polycaprolactone, polyesters based on aliphatic or cycloaliphatic dicarboxylic acids and diols, aliphatic polycarbonate, and also copolymers of or mixtures of these elements, and X1 and X2 independently of one another being amide (CONH) or ester (COO) bonds.
    • 连同一般结构(I)的透明聚酰胺弹性体一起被描述,其中R1是由(a)10-100摩尔%的烷基取代的双(氨基环己基)甲烷形成的聚酰胺链段和/ 或二(氨基环己基)丙烷和0-90摩尔%的其它脂环族C 6 -C 36二胺和/或脂肪族C 2 -C 36二胺和/或芳族C 6 -C 36二胺,其浓度图基于聚酰胺中二胺的总量 和(b)脂族C 4 -C 36二羧酸和/或脂环族C 8 -C 36二羧酸和/或芳族C 8 -C 36二羧酸,和(c)任选的内酰胺和/或氨基羧酸C6-C12,R2选自 二价基团:直链或支链C 2 -C 5聚氧化烯,聚烯烃,数均摩尔质量在200-3000g / mol范围内的聚硅氧烷,直链或支链的取代或未取代的C 2 -C 36亚烷基, C36亚环烷基,C6-C20芳基,聚己内酯,p 基于脂族或脂环族二羧酸和二醇的脂肪族聚酯,脂肪族聚碳酸酯,以及这些元素的共聚物或这些元素的混合物,X 1和X 2彼此独立地为酰胺(CONH)或酯(COO)键。