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    • 3. 发明申请
    • METHOD FOR RECYCLING WASTE WATER FROM A STAINLESS STEEL SLAG TREATMENT PROCESS
    • 从不锈钢渣处理工艺回收废水的方法
    • US20130206041A1
    • 2013-08-15
    • US13810625
    • 2011-07-18
    • Dirk Van MechelenIsabelle LecomieEvelyne Nguyen
    • Dirk Van MechelenIsabelle LecomieEvelyne Nguyen
    • C04B7/36
    • C04B7/364C04B18/142C04B22/0046C04B28/04Y02W30/91Y02W30/92Y02W30/94C04B18/08C04B18/141C04B18/0472C04B18/0418
    • The present invention relates to a method for recycling waste water from a stainless steel slag treatment process wherein stainless steel slag is brought into contact with water, in particular to neutralize the free lime contained therein, thereby producing said waste water. This waste water contains heavy metals, including at least chromium, and has a pH higher than or equal to 11. In accordance with the invention, it is used as production water for manufacturing mortar and/or concrete. In this way, the heavy metals, which are dissolved in the waste water and thus readily available, become bound in the newly formed cement phases so that they are prevented from leaching. Moreover, it has been found that the workability of the fresh mortar or concrete and also the quality of the final mortar or concrete materials is not negatively affected by the use of this alkaline waste water and that an accelerated setting could be achieved during the first hours.
    • 本发明涉及一种用于从不锈钢渣处理方法回收废水的方法,其中不锈钢渣与水接触,特别是中和其中所含的游离石灰,从而产生所述废水。 该废水含有重金属,至少包含铬,并具有高于或等于11的pH值。根据本发明,它被用作制造砂浆和/或混凝土的生产水。 以这种方式,溶解在废水中并因此容易获得的重金属被结合在新形成的水泥相中,使得它们被防止浸出。 此外,已经发现,新鲜的砂浆或混凝土的可加工性以及最终的砂浆或混凝土材料的质量不会受到使用这种碱性废水的不利影响,并且在第一小时内可以实现加速的凝固 。
    • 4. 发明申请
    • Process for Preparing a Filler for Asphalt or Concrete Starting From a Slag Material
    • 从渣料开始制备沥青或混凝土填料的工艺
    • US20100170421A1
    • 2010-07-08
    • US12602009
    • 2008-06-02
    • Evelyne NguyenDirk Van Mechelen
    • Evelyne NguyenDirk Van Mechelen
    • C04B7/14C09C1/02C09C1/22C09C1/34C09D195/00C08K3/34
    • C04B18/142C04B5/06C04B18/144C04B20/026C04B26/26C04B28/02C04B2111/00103C04B2111/0075Y02W30/94C04B22/0013
    • The present invention relates to a process for preparing, starting from a slag material, a filler for construction materials which contain bitumen or a hydraulic binding agent. The slag used to prepare the filler contains γ-dicalcium silicate. The process comprises the step of removing from the slag material a finer fraction formed by particles of a size between 0 and at least 0.75 mm so as to reduce the γ-dicalcium silicate content of the slag material; and the step of finely milling at least a portion of the remaining coarser fraction of the slag to obtain the filler. The invention also relates to the obtained filler, to the use thereof for preparing construction materials and to concrete or mortar compositions and asphalt compositions containing the filler. By removing the finer fraction from the slag material, a filler is obtained which has a considerably lower water content so that it becomes suitable for use in asphalt or concrete or mortar compositions, in particular in self-compacting concrete compositions.
    • 本发明涉及从炉渣材料制备含有沥青或液压粘合剂的建筑材料填料的方法。 用于制备填料的炉渣含有γ-硅酸二钙。 该方法包括从矿渣材料中除去由0至至少0.75mm之间的颗粒形成的更细的部分以减少炉渣材料的γ-二硅酸钙含量的步骤; 以及将渣的剩余较粗部分的至少一部分精细研磨以获得填料的步骤。 本发明还涉及所获得的填料,其用于制备建筑材料的用途以及含有填料的混凝土或砂浆组合物和沥青组合物。 通过从矿渣材料中除去更细的部分,获得了具有相当低的水含量的填料,使得其适合用于沥青或混凝土或砂浆组合物,特别是在自密实混凝土组合物中。
    • 5. 发明申请
    • Process for Producing a Granular Material
    • 生产颗粒材料的方法
    • US20110017101A1
    • 2011-01-27
    • US12812912
    • 2009-01-15
    • Evelyne NguyênDirk Van MechelenPhilippe Descamps
    • Evelyne NguyênDirk Van MechelenPhilippe Descamps
    • C04B7/19C04B14/04C09C1/62
    • C21B3/06C04B18/142C04B28/02C04B2111/00767C22B7/04Y02P10/212Y02P40/18Y02W30/543Y02W30/91Y02W30/94C04B40/0028C04B40/0071C04B40/0231C04B18/021
    • The present invention relates to a process for producing a granular material 26 for mixing with at least a hydraulic binding agent and with water to produce mortar or concrete. This process comprises at least an aggregation step and a carbonation step. In the aggregation step, steel slag particles from at least a fine fraction 24 of steel slag, in particular a fine fraction of steel slag containing a significant amount of γ-dicalcium silicate, are aggregated into larger grains so as to form a coarser granular material 25. In the carbonation step, said aggregated particles in said coarser granular material 25 are carbonated by means of carbon dioxide so as to produce a carbonated granular material 26. The present invention also relates to a carbonated granular material of aggregated steel slag particles containing a significant amount of γ-dicalcium silicate, in particular at least 3 wt. %, preferably at least 5 wt. % and more preferably at least 7 wt. %, and bound within each grain by a solid matrix containing at least calcium and/or magnesium carbonates.
    • 本发明涉及一种用于与至少水硬性粘合剂和水混合以制造砂浆或混凝土的颗粒材料26的制备方法。 该方法至少包括聚集步骤和碳酸化步骤。 在聚集步骤中,来自钢渣的至少细小部分24的钢渣颗粒,特别是含有大量γ-硅酸二钙的钢渣的细小部分被聚集成较大的颗粒,以形成较粗的颗粒材料 在碳酸化步骤中,所述较粗粒状材料25中的所述凝集颗粒通过二氧化碳进行碳酸化,以生产碳酸化颗粒材料26.本发明还涉及一种含有 显着量的γ-二硅酸钙,特别是至少3wt。 %,优选至少5wt。 %,更优选至少7wt。 %,并且通过含有至少钙和/或碳酸镁的固体基质在每个晶粒内结合。
    • 7. 发明申请
    • METHOD FOR PURIFYING WASTE WATER FROM A STAINLESS STEEL SLAG TREATMENT PROCESS
    • 从不锈钢渣处理工艺中净化废水的方法
    • US20140291252A1
    • 2014-10-02
    • US13882091
    • 2011-10-27
    • Evelyne NguyenDirk Van Mechelen
    • Evelyne NguyenDirk Van Mechelen
    • C02F1/52C02F1/70
    • C02F1/5245C02F1/5236C02F1/66C02F1/705C02F2101/20C02F2101/22C02F2103/16C02F2301/08
    • The present invention relates to a method for purifying highly alkaline waste water from a stainless steel slag treatment process. This waste water contains between 0.5 and 5 mg/l of trivalent chromium (Cr(III)) and between 0.5 and 1.0 mg/l of molybdenum. To reduce the chromium and molybdenum content a trivalent iron is added to the waste water in the form of a water soluble ferric salt and the trivalent iron is allowed to co-precipitate with said chromium and molybdenum by lowering the pH of the waste water. It was found that by performing the co-precipitation at a pH of 3.5 to 5.7, both the chromium and the molybdenum content could be effectively reduced to a level of less than 0.5 mg/l, and this without having to provide large amounts of trivalent iron in the waste water, without having to repeat the purification process for several times, without having to add sulphide to the waste water, and without having to lower and raise the pH of the waste water for more than one time.
    • 本发明涉及一种从不锈钢渣处理工艺中净化高碱性废水的方法。 该废水含有0.5-5mg / l三价铬(Cr(III))和0.5-1.0mg / l的钼。 为了降低铬和钼含量,将三价铁以水溶性铁盐的形式加入到废水中,通过降低废水的pH使三价铁与所述铬和钼共沉淀。 发现通过在3.5〜5.7的pH下进行共沉淀,可以将铬和钼含量有效降低至小于0.5mg / l的水平,而不必提供大量的三价 铁,而不必多次重复净化过程,而不必向废水中加入硫化物,并且不必降低和提高废水的pH超过一次。
    • 9. 发明授权
    • Process for producing a granular material
    • 粒状材料的制造方法
    • US08623134B2
    • 2014-01-07
    • US12812912
    • 2009-01-15
    • Evelyne NguyênDirk Van MechelenPhilippe Descamps
    • Evelyne NguyênDirk Van MechelenPhilippe Descamps
    • C04B18/14
    • C21B3/06C04B18/142C04B28/02C04B2111/00767C22B7/04Y02P10/212Y02P40/18Y02W30/543Y02W30/91Y02W30/94C04B40/0028C04B40/0071C04B40/0231C04B18/021
    • The present invention relates to a process for producing a granular material 26 for mixing with at least a hydraulic binding agent and with water to produce mortar or concrete. This process comprises at least an aggregation step and a carbonation step. In the aggregation step, steel slag particles from at least a fine fraction 24 of steel slag, in particular a fine fraction of steel slag containing a significant amount of γ-dicalcium silicate, are aggregated into larger grains so as to form a coarser granular material 25. In the carbonation step, said aggregated particles in said coarser granular material 25 are carbonated by means of carbon dioxide so as to produce a carbonated granular material 26. The present invention also relates to a carbonated granular material of aggregated steel slag particles containing a significant amount of γ-dicalcium silicate, in particular at least 3 wt. %, preferably at least 5 wt. % and more preferably at least 7 wt. %, and bound within each grain by a solid matrix containing at least calcium and/or magnesium carbonates.
    • 本发明涉及一种用于与至少水硬性粘合剂和水混合以制造砂浆或混凝土的颗粒材料26的制备方法。 该方法至少包括聚集步骤和碳酸化步骤。 在聚集步骤中,来自钢渣的至少细小部分24的钢渣颗粒,特别是含有大量γ-硅酸二钙的钢渣的细小部分被聚集成较大的颗粒,以形成较粗颗粒材料 在碳酸化步骤中,所述较粗粒状材料25中的所述凝集颗粒通过二氧化碳进行碳酸化,以生产碳酸化颗粒材料26.本发明还涉及一种含有 显着量的γ-二硅酸钙,特别是至少3wt。 %,优选至少5wt。 %,更优选至少7wt。 %,并且通过含有至少钙和/或碳酸镁的固体基质在每个晶粒内结合。
    • 10. 发明授权
    • Method of treating an alkaline granular carbonatable material
    • 处理碱性颗粒状​​可碳化材料的方法
    • US08603419B2
    • 2013-12-10
    • US13391521
    • 2010-08-23
    • Philippe DescampsIsabelle LecomteEvelyne NguyenDirk Van Mechelen
    • Philippe DescampsIsabelle LecomteEvelyne NguyenDirk Van Mechelen
    • C04B18/00
    • C04B18/021B09B3/0033C04B2111/0075Y02P40/18Y02W30/91Y02W30/92C04B18/10C04B20/023C04B40/0231C04B18/0463
    • The invention concerns a method of treating an alkaline granular carbonatable material which contains aluminium metal and which has in particular a pH of at least 10. The method comprises an oxidation step wherein at least a portion of said aluminium metal is oxidized by contact with moisture. The aluminium should be oxidized to avoid swelling problems when using the granular material as aggregate. In the method according to the invention this oxidation is accelerated by providing at least one oxidizing agent in said moisture, which oxidizing agent has a higher redox potential than the water contained in said moisture. The method further comprises a carbonation step wherein the granular carbonatable material is at least partially carbonated to lower the pH thereof. In this way the formation of ettringite, which may also release aluminium ions which causing further swelling problems, can be avoided in the granular material or any ettringite present therein can be destabilized.
    • 本发明涉及一种处理含有铝金属的碱性颗粒状​​可碳化材料的方法,该方法特别具有至少10的pH值。该方法包括氧化步骤,其中所述铝金属的至少一部分与水分接触而被氧化。 当使用颗粒材料作为骨料时,铝应被氧化以避免溶胀问题。 在根据本发明的方法中,通过在所述水分中提供至少一种氧化剂来加速该氧化,该氧化剂具有比所述水分中含有的水更高的氧化还原电位。 该方法还包括碳酸化步骤,其中可颗粒状可碳化材料至少部分碳酸化以降低其pH。 以这种方式,可以避免在粒状材料中形成可能释放引起更多溶胀问题的铝离子的钙矾石,或者其中存在的任何钙矾石可能不稳定。