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    • 1. 发明申请
    • LITHIUM MANGANESE SECONDARY BATTERY
    • 锂锰锰二次电池
    • US20070202411A1
    • 2007-08-30
    • US11676723
    • 2007-02-20
    • Sun Kyu KIMKyung Min JUNSeung Don CHOIHong Kyu PARK
    • Sun Kyu KIMKyung Min JUNSeung Don CHOIHong Kyu PARK
    • H01M4/62H01M4/58H01M4/50
    • H01M4/131H01M4/133H01M4/505H01M4/62H01M10/0525Y02T10/7011
    • Disclosed is a manganese-based lithium secondary battery comprising a cathode containing manganese-based lithium metal oxide, an anode, and an electrolyte, wherein the anode comprises an anode active material in which a Mn scavenger capable of reducing manganese ions on a surface by conducting or semiconducting properties is coated on part or all of anode active material particles. Through the use of the Mn scavenger, manganese ion dissolved from the manganese-based cathode active material into the electrolyte is preferentially deposited on the Mn scavenger coated on the surface of the anode active material particles, such that the dissolved manganese ion is inhibited from being deposited directly on the surface of the anode active material, and a decomposition of the electrolyte with the deposited manganese component is inhibited. Accordingly, the use of the Mn scavenger can provide a manganese-based lithium secondary battery having excellent storage performance.
    • 公开了一种锰基锂二次电池,其包含含有锰基锂金属氧化物的阴极,阳极和电解质,其中所述阳极包括负极活性材料,其中能够通过导电在表面上还原锰离子的Mn清除剂 或半导体性质涂覆在部分或全部阳极活性材料颗粒上。 通过使用Mn清除剂,将从锰系阴极活性物质溶解到电解质中的锰离子优先沉积在涂覆在负极活性物质粒子表面上的Mn清除剂上,使得溶解的锰离子被抑制 直接沉积在阳极活性材料的表面上,并且电解质与沉积的锰组分的分解被抑制。 因此,使用Mn清除剂可以提供具有优良储存性能的锰基锂二次电池。