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1. 发明授权

US5503934A Metallized plastic article 失效
标题翻译：金属化塑料制品
公开(公告)号：US5503934A
公开(公告)日：1996-04-02
申请号：US333709
申请日：1994-11-03
申请人： Christianus J. J. Maas , Luca P. Fontana , Robertus E. de Jong , Michael B. Grimm
发明人： Christianus J. J. Maas , Luca P. Fontana , Robertus E. de Jong , Michael B. Grimm
IPC分类号： B32B15/09 , B29C39/12 , C08G63/64 , C08G64/00 , C08G64/04 , C08L69/00 , C23C14/20 , B32B27/36 , G02B1/10
CPC分类号： C08G63/64 , C08L69/005 , C23C14/20 , B29K2033/04 , B29K2069/00 , Y10S264/78 , Y10T428/31507 , Y10T428/31681
摘要： It is possible to manufacture articles out of thermoplastic materials and to metallize the articles at their surface. In this way one can manufacture reflectors and similar articles. Most thermoplastic materials require extra processing steps prior to the metallization like application of primers, chemical etching and the like.The invention is based on the discovery that a certain type of materials can be metallized without any extra processing steps. The materials involved are polyestercarbonates or blends of polyestercarbonates and polycarbonate. This is quite surprising since polycarbonates can not be metallized in good quality without extra processing steps prior to the metallization step.
摘要翻译：可以从热塑性材料制造制品并在其表面上金属化制品。这样就可以制造反射镜和类似物品。大多数热塑性材料在金属化之前需要额外的加工步骤，如施加底漆，化学蚀刻等。本发明基于以下发现：某种类型的材料可以金属化而没有任何额外的加工步骤。所涉及的材料是聚酯碳酸酯或聚酯碳酸酯和聚碳酸酯的共混物。这是非常令人惊奇的，因为在金属化步骤之前没有额外的加工步骤，聚碳酸酯不能以良好的质量进行金属化。

2. 发明授权

US5115024A Method for the preparation of crosslinked polycarbonates 失效
标题翻译：交联聚碳酸酯的制备方法
公开(公告)号：US5115024A
公开(公告)日：1992-05-19
申请号：US654708
申请日：1991-02-13
申请人： Luca P. Fontana , Sterling B. Brown
发明人： Luca P. Fontana , Sterling B. Brown
IPC分类号： C08G64/30 , C08J5/24 , C08L69/00
CPC分类号： C08J5/24 , C08G64/30 , C08L69/00 , C08J2369/00
摘要： An improved method for the preparation of crosslinked polycarbonates comprises the reaction at elevated temperature of a composition containing cyclic polycarbonate oligomers with at least one polyglycidyl acrylate copolymer formed by the reaction of at least one olefinic compound with a glycidyl acrylate monomer. Further disclosed are network polycarbonates wherein the carbonate chains are linked to each other via polyglycidyl acrylate copolymer groups, and prepreg compositions which comprise a filler and a mixture of cyclic polycarbonate oligomers with a polyglycidyl acrylate copolymer.
摘要翻译：用于制备交联聚碳酸酯的改进方法包括在含有环状聚碳酸酯低聚物和至少一种通过至少一种烯属化合物与丙烯酸缩水甘油酯单体的反应形成的丙烯酸缩水甘油酯共聚物的组合物的高温下进行反应。还公开了网络聚碳酸酯，其中碳酸酯链通过聚丙烯酸缩水甘油酯共聚物基团彼此连接，以及预浸料组合物，其包含填料和环状聚碳酸酯低聚物与聚缩水甘油丙烯酸酯共聚物的混合物。

3. 发明授权

US5106904A Composition containing an aromatic copolyestercarbonate and an inert filler 失效
标题翻译：含有芳香族共聚碳酸酯和惰性填料的组合物
公开(公告)号：US5106904A
公开(公告)日：1992-04-21
申请号：US511683
申请日：1990-04-20
申请人： Luca P. Fontana , Masataka Morioka
发明人： Luca P. Fontana , Masataka Morioka
IPC分类号： C08G63/64 , C08K3/00 , C08K7/14 , C08L67/00 , C08L69/00
CPC分类号： C08L69/005 , C08K7/14
摘要： A composition comprisinga. an aromatic copolyestercarbonate comprising from about 2 to 30 mole percent ester content of an alpha omega aliphatic dicarboxylic acid ester having from about 8 to 20 carbon atoms, inclusive, admixed withb. an inert filler in sufficient quantities to increase the flexural modulus of copolyestercarbonate.

4. 发明授权

US5025081A Preparation of polyestercarbonate from aliphatic dicarboxylic acid 失效
标题翻译：从脂肪族二羧酸制备聚酯碳酸酯
公开(公告)号：US5025081A
公开(公告)日：1991-06-18
申请号：US476067
申请日：1990-01-30
申请人： Luca P. Fontana , Paul W. Buckley
发明人： Luca P. Fontana , Paul W. Buckley
IPC分类号： C08G63/79 , C08G63/64
CPC分类号： C08G63/64
摘要： A process for preparing a copolyestercarbonate which comprises reacting interfacially a dihydric phenol, a carbonate precursor, and a saturated aliphatic alpha omega dicarboxylic acid having from 9 to about 40 carbon atoms wherein the said diacid is from about 2 to about 20 mole percent based on the dihydric phenol reactant content and wherein the initial pH is from about 8 to about 9 for about 70 to about 95% of the carbonate precursor addition time period time period and is then raised to a final pH of from about 10 to 12 for the remainder of the carbonate precursor addition time period.

5. 发明授权

US4983706A Interfacial process comprising reacting a dihydric phenol, a carbonate precursor and an aliphatic alpha omega dicarboxylic salt 失效
标题翻译：界面方法包括使二元酚，碳酸酯前体和脂族αω二羧酸盐反应
公开(公告)号：US4983706A
公开(公告)日：1991-01-08
申请号：US476066
申请日：1990-01-30
申请人： Luca P. Fontana , Paul W. Buckley , Denise Y. Harris , Eugene P. Boden
发明人： Luca P. Fontana , Paul W. Buckley , Denise Y. Harris , Eugene P. Boden
IPC分类号： C08G64/22 , C08G63/64 , C08G64/20
CPC分类号： C08G63/64
摘要： A process which comprises reacting interfacially a dihydric phenol, a carbonate precursor and a prior prepared salt of an aliphatic alpha omega dicarboxylic acid having from 8 to about 20 carbon atoms thereby producing a copolyestercarbonate.

6. 发明授权

US5605980A Copolyestercarbonate and polycarbonate 失效
标题翻译：共聚酯碳酸酯和聚碳酸酯
公开(公告)号：US5605980A
公开(公告)日：1997-02-25
申请号：US601883
申请日：1996-02-15
申请人： Omar M. Boutni , Luca P. Fontana , Sarah E. Morgan
发明人： Omar M. Boutni , Luca P. Fontana , Sarah E. Morgan
IPC分类号： C08L67/00 , C08L69/00 , C08L67/02
CPC分类号： C08L69/00 , C08L69/005
摘要： A composition comprisinga. about 10 to 90 weight-percent of an aromatic polycarbonate in admixture withb. about 90 to 10 weight percent of copolyestercarbonate having repeating units of the structure ##STR1## wherein: R is independently selected from halogen, monovalent hydrocarbon, and monovalent hydrocarbonoxy radicals;R.sup.1 is independently selected from halogen, monovalent hydrocarbon, and monovalent hydrocarbonoxy radicals;W is selected from divalent hydrocarbon ##STR2## radicals, n and n.sup.1 are independently selected from integers having a value of from 0 to 4 inclusive;b is either zero or one;X is an alkylene group of about 6 to 18 carbon atoms, inclusive;d is from about 2 to 30 mole percent of the total units c+d; anda and b calculated as weight percent of a plus b.
摘要翻译：一种组合物，其包含a。约10至90重量％的芳族聚碳酸酯与b混合。约90至10重量％的具有重复单元结构的共聚酯碳酸酯，其中：R独立地选自卤素，一价烃和一价烃氧基; R1独立地选自卤素，一价烃和一价烃氧基; W选自二价碳氢化合物基团，n和n1独立地选自具有0至4的整数的整数; b是零或一; X是约6-18个碳原子的亚烷基，包括端值; d为总单位c + d的约2至30摩尔％; a和b以加号b的重量百分比计算。

7. 发明授权

US5605754A Coated polycarbonate articles 失效
标题翻译：涂层聚碳酸酯制品
公开(公告)号：US5605754A
公开(公告)日：1997-02-25
申请号：US565801
申请日：1995-11-30
申请人： Josef G. Berndsen , Luca P. Fontana
发明人： Josef G. Berndsen , Luca P. Fontana
IPC分类号： B32B27/18 , B29C47/06 , B32B27/36 , C08J7/04 , C08K5/3475 , C08L67/00 , C08L67/02 , C08L69/00 , C09D201/00 , C08K5/34 , C07D249/16 , C08F20/00
CPC分类号： C08J7/047 , C08K5/3475 , Y10T428/265 , Y10T428/269 , Y10T428/31507
摘要： A thermoplastic article having on the outer surface thereof a protective layer having in admixture a trihydricphenol-benzotriazole ultra violet light absorber and a thermoplastic resin preferably a polycarbonate. The protective layer may be coated on the thermoplastic substrate or it may be co-extruded with the thermoplastic substrate.
摘要翻译：一种热塑性制品，其外表面上具有三元酚 - 苯并三唑紫外线吸收剂和热塑性树脂，优选聚碳酸酯的保护层。保护层可以涂覆在热塑性基材上，或者可以与热塑性基材共挤出。

8. 发明授权

US5556936A Aromatic polycarbonates having polyfunctional UV screening units, method for making and use 失效
标题翻译：具有多官能UV筛选单元的芳族聚碳酸酯，制备和使用方法
公开(公告)号：US5556936A
公开(公告)日：1996-09-17
申请号：US341240
申请日：1994-11-17
申请人： Joseph A. King, Jr. , Patrick J. McCloskey , Alice M. Colley , David M. Dardaris , Luca P. Fontana , Josef G. Berndsen
发明人： Joseph A. King, Jr. , Patrick J. McCloskey , Alice M. Colley , David M. Dardaris , Luca P. Fontana , Josef G. Berndsen
IPC分类号： C08G64/12 , C08G64/00
CPC分类号： C08G64/12 , Y10T428/31507
摘要： UV stabilized polycarbonates are provided having chemically combined polyhydric phenol benzotriazole carbonate units, such as 1,1-bis(4-hydroxyphenyl)-1-[4-hydroxy-3-(N-2-benzotriazole)phenyl]ethane carbonate units and methods for making. Incorporation of the polyhydric phenol benzotriazole functional units into the polycarbonate backbone can be achieved by redistribution or transesterification under melt polymerization conditions.
摘要翻译：提供具有化学结合的多元酚苯并三唑碳酸酯单元如1,1-双（4-羟基苯基）-1- [4-羟基-3-（N-2-苯并三唑）苯基]乙烷碳酸酯单元和方法的紫外线稳定化聚碳酸酯制作。通过在熔融聚合条件下的再分配或酯交换可以将多羟基苯并三唑功能单元并入聚碳酸酯骨架中。

9. 发明授权

US5510182A Copolyestercarbonate composition derived from dihydric phenol, carbonate precursor and an alpha omega dicarboxylic acid 失效
标题翻译：衍生自二元酚，碳酸酯前体和αω二羧酸的共聚酯碳酸酯组合物
公开(公告)号：US5510182A
公开(公告)日：1996-04-23
申请号：US219128
申请日：1994-03-29
申请人： Luca P. Fontana , Kenneth F. Miller , Adrianus A. Claesen , Peter W. van Es , Theodorus O. N. de Vroomen , Clayton B. Quinn , Richard W. Campbell
发明人： Luca P. Fontana , Kenneth F. Miller , Adrianus A. Claesen , Peter W. van Es , Theodorus O. N. de Vroomen , Clayton B. Quinn , Richard W. Campbell
IPC分类号： C08G63/64 , C08G63/79
CPC分类号： C08G63/64 , C08G63/79 , Y10T428/1352 , Y10T428/2913 , Y10T428/31507
摘要： A composition comprising a copolyestercarbonate derived from a dihydric phenol, a carbonate precursor, and an aliphatic alpha omega dicarboxylic acid or ester precursor wherein the dicarboxylic acid or ester precursor has from 10 to about 20 carbon atoms, inclusive, and is present in the copolyestercarbonate in quantities of from about 2 to 30 mole percent of the dihydric phenol.
摘要翻译：一种组合物，其包含衍生自二元酚的共聚酯碳酸酯，碳酸酯前体和脂族αω二羧酸或酯前体，其中二羧酸或酯前体具有10至约20个碳原子，并且存在于共聚酯碳酸酯中量为约2至30摩尔％的二元酚。

10. 发明授权

US5455323A Reduced TG copolyestercarbonate 失效
标题翻译：降低TG共聚酯碳酸酯
公开(公告)号：US5455323A
公开(公告)日：1995-10-03
申请号：US154242
申请日：1993-11-18
申请人： Luca P. Fontana , Randall A. Reed
发明人： Luca P. Fontana , Randall A. Reed
IPC分类号： C08G63/64 , C08G64/00
CPC分类号： C08G63/64
摘要： A reduced glass transition temperature copolyester-carbonate which displays non-Newtonian melt behavior was synthesized by using bisphenol-A, a dicarboxylic acid and a trisphenol. The branched copolymer was obtained by interfacial phosgenation. One of the compositions described displays a Tg of about 127.degree. C. and twice the melt flow index of a branched polycarbonate of corresponding molecular weight or intrinsic viscosity.
摘要翻译：通过使用双酚A，二羧酸和三酚合成了显示非牛顿熔体特性的缩合玻璃化转变温度共聚酯 - 碳酸酯。通过界面光气化获得支化共聚物。所述组合物之一显示出约127℃的Tg和相应分子量或特性粘度的支化聚碳酸酯的熔体流动指数的两倍。

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