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    • 3. 发明申请
    • Optically active compound and liquid crystal composition containing the compound
    • 含有该化合物的光学活性化合物和液晶组合物
    • US20050260358A1
    • 2005-11-24
    • US10614296
    • 2003-07-08
    • Yuki MotoyamaTakashi AokiMasahiro Johno
    • Yuki MotoyamaTakashi AokiMasahiro Johno
    • G02F1/13C07C69/76C07C69/82C07C69/94C09K19/54C09K19/58C09K19/30C09K19/12C09K19/32
    • C09K19/586C07C69/94Y10T428/10
    • An optically active compound of the general formula (1), wherein n is an integer of 4 to 8, X is -Ph-COO-Ph-Ph-, -Ph-Ph-COO-Ph-, -Ph-OC-Ph-Ph-, -Ph-Ph-OC-Ph-, -Ph-Ph-Ph-, -Cy-COO-Ph-Ph-, -Ph-Ph-OC-Cy-, -Ph-OC-Ph-COO-Ph-, -Ph-OC-Cy-COO-Ph-, -Ph-OC-Np-COO-Ph-, -Np-OC-Ph- or -Ph-COO-Np- in which -Ph- is a 1,4-phenylene group, -Cy- is a trans-1,4-cyclohexylene group and -Np- is a 2,6-naphthylene group, and C* is an asymmetric carbon, and a nematic liquid crystal composition containing the above optically active compound. According to the present invention, there is provided a nematic liquid crystal composition containing the optically active compound having a helical twisting power (HTP) of 10 or more and giving a chiral dopant for a nematic liquid crystal, which chiral dopant has a property that the pitch of its induced helix decreases in length with an increase in temperature.
    • 通式(1)的光学活性化合物,其中n为4〜8的整数,X为-Ph-COO-Ph-Ph-,-Ph-Ph-COO-Ph-,-Ph-OC-Ph -Ph-Ph-OC-Ph-,-Ph-Ph-Ph-,-Cy-COO-Ph-Ph-,-Ph-Ph-OC-Cy-,-Ph-OC-Ph-COO -Ph-,-Ph-OC-Cy-COO-Ph-,-Ph-OC-Np-COO-Ph-,-Np-OC-Ph-或-Ph-COO-Np-,其中-Ph-为 1,4-亚苯基,-Cy-是反-1,4-亚环己基,-Np-是2,6-亚萘基,C *是不对称碳,并且含有上述的向列型液晶组合物 光学活性化合物。 根据本发明,提供了一种向列型液晶组合物,其含有螺旋扭转力(HTP)为10以上的光学活性化合物,并赋予向列型液晶的手性掺杂剂,该手性掺杂剂具有以下性质: 其诱导螺旋的间距随着温度的升高而降低。
    • 4. 发明授权
    • Optically active compound and liquid crystal composition containing the compound
    • 含有该化合物的光学活性化合物和液晶组合物
    • US06677475B2
    • 2004-01-13
    • US10046902
    • 2002-01-17
    • Yasumasa NorisueTakakiyo MineMasahiro Johno
    • Yasumasa NorisueTakakiyo MineMasahiro Johno
    • C07C6976
    • C09K19/586C07C69/76Y10T428/10
    • Optically active compounds of the following general formula (1) useful as chiral dopant, wherein n is an integer of 0 to 5, provided that when n is 0, A is a single bond (—) and that when n is 1 to 5, A is a single bond (—), —O—, —COO—, —Cy— or —Cy—COO— in which —Cy— is a trans-1,4-cyclohexylene group, each of X and Y is independently a hydrogen atom or a fluorine atom, B is a single bond (—), —COO—, —COO—Ph— or —Ph—COO— in which —Ph— is a 1,4-phenylene group, and C* is an asymmetric carbon. The chiral dopant of the present invention have a high helical twisting power of at least 9 and suitably have a feature that the helical pitch induced by them decreases in length with an increase in temperature so that they are advantageous for use in a nematic liquid crystal composition.
    • 可用作手性掺杂剂的以下通式(1)的光学活性化合物,其中n为0至5的整数,条件是当n为0时,A为单键( - ),当n为1至5时, A是单键( - ),-O - , - COO - , - C y - 或-C y -COO-,其中-Cy-是反式-1,4-亚环己基,X和Y各自独立地为 氢原子或氟原子,B是单键( - ),-COO-,-COO-Ph-或-Ph-COO-,其中-Ph-是1,4-亚苯基,C *是 不对称碳。 本发明的手性掺杂剂具有至少9的高的螺旋扭转力,并且适当地具有由它们引起的螺旋桨距随温度升高而减小的特征,因此它们有利于用于向列型液晶组合物 。
    • 5. 发明授权
    • Phenyl triester compound and anti-ferroelectric liquid crystal composition containing the same
    • 苯基三酯化合物和含有它的反铁电液晶组合物
    • US06217954B1
    • 2001-04-17
    • US09413482
    • 1999-10-06
    • Yuki MotoyamaTakahiro MatsumotoMasahiro JohnoTomoyuki Yui
    • Yuki MotoyamaTakahiro MatsumotoMasahiro JohnoTomoyuki Yui
    • C09K1912
    • C09K19/0266C07C69/90C09K19/2021Y10T428/10
    • An anti-ferroelectric liquid crystal composition containing a phenyl triester compound of the formula (1), wherein R1 is a linear alkyl group having 6 to 12 carbon atoms, m is an integer of 0 to 3, n is an integer of 1 to 3, and X1 is a hydrogen atom or a fluorine atom, and an anti-ferroelectric liquid crystal compound of the formula (2),  wherein R2 is a linear alkyl group having 6 to 12 carbon atoms, X2 is a hydrogen atom or a fluorine atom, A is —CH3 or —CF3, r is 0 or 1 and C* is an asymmetric carbon, provided that when A is —CH3, r is 0 and p is an integer of 4 to 10, that when A is —CF3 and when r is 0, p is an integer of 6 to 8, and further than when A is —CF3 and when r is 1, q is an integer of 5 to 8 and p is 2 or 4. The phenyl triester compound and anti-ferroelectric liquid crystal compound composition is not only improved in response speed but also shows remarkably controlled layer rotation, and it can achieve a simple matrix liquid crystal display device which is free of a change in contrast and is highly reliable in use for a long period of time.
    • 一种含有式(1)的苯基三酯化合物的反铁电液晶组合物,其中,R 1为碳原子数6〜12的直链烷基,m为0〜3的整数,n为1〜3的整数。 ,X 1为氢原子或氟原子,式(2)的反铁电液晶化合物,其中,R2为碳原子数6〜12的直链烷基,X2为氢原子或氟原子 A为-CH 3或-CF 3,r为0或1,C *为不对称碳,条件是当A为-CH 3时,r为0,p为4至10的整数,当A为-CF 3和 当r为0时,p为6至8的整数,并且当A为-CF 3时,当r为1时,q为5至8的整数,p为2或4.苯基三酯化合物和抗 - 铁电液晶化合物组合物不仅提高了响应速度,而且显示出显着控制的层旋转,并且可以实现简单的矩阵液晶显示装置,其不含ch 相比之下,在长时间使用中是高度可靠的。