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1. 发明授权

US08686212B2 Process for treatment of ethylene 有权
标题翻译：处理乙烯的方法
公开(公告)号：US08686212B2
公开(公告)日：2014-04-01
申请号：US13389387
申请日：2010-08-10
申请人： Leslie William Bolton , Benjamin Patrick Gracey , Michael Keith Lee
发明人： Leslie William Bolton , Benjamin Patrick Gracey , Michael Keith Lee
IPC分类号： C07C7/00
CPC分类号： C07C7/11 , C07C11/04
摘要： Process for removing water from an ethylene stream containing water, by introducing an ethylene stream containing water into, and circulating the ethylene stream through, a separation vessel. A liquid diethyl ether stream is introduced into, and circulated through, the separation vessel so that the liquid diethyl ether stream and the ethylene stream containing water are brought into contact, and an ethylene stream having a reduced water content is recovered from the separation vessel.
摘要翻译：通过将含有乙烯的乙烯流引入并使乙烯流循环通过分离容器，从含有乙烯的流中除去水分的方法。将液体二乙醚流引入分离容器中并循环通过分离容器，使得液态二乙醚流和含水的乙烯流接触，并且从分离容器回收具有降低的水含量的乙烯流。

2. 发明授权

US08552240B2 Process for producing propylene 有权
标题翻译：生产丙烯的方法
公开(公告)号：US08552240B2
公开(公告)日：2013-10-08
申请号：US12085704
申请日：2006-11-22
申请人： Craig Bailey , Leslie William Bolton , Benjamin Patrick Gracey , Michael Keith Lee , Stephen Roy Partington
发明人： Craig Bailey , Leslie William Bolton , Benjamin Patrick Gracey , Michael Keith Lee , Stephen Roy Partington
IPC分类号： C07C1/24
CPC分类号： C07C1/24 , C07C2521/08 , C07C2521/16 , C07C2527/173 , C07C2527/188 , C07C2527/19 , C07C2529/18 , Y02P20/582 , C07C11/06
摘要： Process for producing propylene from a propanol feedstock A2 by reacting the propanol feedstock A2 in a vapor phase dehydration reactor wherein the propanol is convened at a temperature comprised between 160 and 270° C. and at a pressure of above 0.1 MPa but less than 4.5 MPa, into a product stream B2 containing propylene, propyl ethers, water and unconverted and/or isomerized propanols, cooling the product stream B2, disengaging the cooled product stream B2 in a separation unit to give a first stream C2 containing propylene and propyl ethers, and a second product stream D2 containing water, propyl ethers and unconverted and/or isomerized propanols, feeding the product stream D2 to a dewatering unit wherein the water stream F2 is separated from the propyl ethers and unconverted and/or isomerised propanols stream E2, recycling the stream E2 into the dehydration reactor, cooling the product stream C2, feeding the cooled product stream C2 to a purification unit wherein the propyl ethers stream G2 is separated from the propylene stream H2, and optionally, recycling the propyl ethers stream G2 to either the dewatering unit or directly to dehydration reactor.
摘要翻译：通过丙醇原料A2在气相脱水反应器中反应生成丙烯的方法，其中丙醇在160-270℃的温度和高于0.1MPa但小于4.5MPa的压力下进行在含有丙烯，丙醚，水和未转化的和/或异构化的丙醇的产物流B2中，冷却产物流B2，使分离单元中的冷却的产物流B2脱离，得到含丙烯和丙醚的第一料流C2，将含有水，丙醚和未转化和/或异构化的丙醇的第二产物流D2，将产物流D2供给脱水单元，其中水流F2与丙醚和未转化的和/或异构化的丙醇流E2分离，将将流E2进入脱水反应器中，冷却产物流C2，将冷却的产物流C2进料到纯化单元，其中丙醚流G2与丙烯流H 2分离，并且任选地将丙醚流G2再循环到脱水单元或直接进入脱水反应器。

3. 发明授权

US08299133B2 Process for the conversion of hydrocarbons to oxygenates 有权
标题翻译：将烃转化为含氧化合物的方法
公开(公告)号：US08299133B2
公开(公告)日：2012-10-30
申请号：US12311944
申请日：2007-10-17
申请人： Benjamin Patrick Gracey , Michael Keith Lee
发明人： Benjamin Patrick Gracey , Michael Keith Lee
IPC分类号： C07C27/00
CPC分类号： C07C29/1518 , C07C31/04 , C07C31/08 , C07C31/10 , C07C31/12
摘要： Process for converting a hydrocarbon feedstock into alcohol(s) wherein the hydrocarbons are first converted into syngas, which is converted into alcohols, by converting hydrocarbon feedstock in a steam reformer into stream A′ of carbon oxide(s), hydrogen and water, feeding stream A′ with hydrocarbon and oxygen feedstocks into an auto-thermal reformer to produce stream A, converting stream A in an oxygenate synthesis reactor into stream B containing methanol, ethanol, propanol(s), H2, C1-C3 alkanes, CO, CO2 and water, separating stream B, into stream C containing CO, C1-C3 alkanes, H2 and methanol, stream D containing CO2, recovering stream B containing the ethanol, propanol(s) and water, treating stream C to separate into a stream comprising CO and a stream comprising H2 and C1-C3 alkanes, reintroducing part of stream C with the stream comprising CO into the oxygenate synthesis reactor. At least part of stream D is reintroduced into the steam reformer.
摘要翻译：将烃原料转化为醇的方法，其中烃首先通过将蒸汽重整器中的烃原料转化成碳氧化物，氢和水的进料A'而转化成合成气，转化成醇流A'与烃和氧原料进入自热重整器以产生流A，将含氧化合物反应器中的料流A转化成含有甲醇，乙醇，丙醇，H 2，C 1 -C 3烷烃，CO，CO 2的流B 和水，将流B分离成包含CO，C 1 -C 3烷烃，H 2和甲醇的流C，含有CO 2的流D，回收含有乙醇，丙醇和水的流B，处理流C以分离成包含 CO和包含H 2和C 1 -C 3烷烃的物流，将包含CO的流的部分流C再次引入到含氧化合物合成反应器中。流D的至少一部分被重新引入蒸汽重整器。

4. 发明授权

US08299132B2 Process for the conversion of hydrocarbons to alcohols 有权
标题翻译：将烃转化为醇的方法
公开(公告)号：US08299132B2
公开(公告)日：2012-10-30
申请号：US12311941
申请日：2007-10-17
申请人： Benjamin Patrick Gracey , Michael Keith Lee
发明人： Benjamin Patrick Gracey , Michael Keith Lee
IPC分类号： C07C27/00
CPC分类号： C07C29/1518 , C07C31/04 , C07C31/08 , C07C31/10 , C07C31/12
摘要： Process for converting a hydrocarbon feedstock into alcohol(s), wherein the hydrocarbons are first converted into syngas, which is subsequently converted into alcohols. The process is carried out by performing the steps of (1) converting a hydrocarbon feedstock, together with an oxygen feedstock, in a auto-thermal reactor (ATR), into a stream A, containing a mixture of carbon oxide(s) and hydrogen, (2) converting at least part of stream A, in the presence of a catalyst in a oxygenate synthesis reactor under a temperature between 150 and 400° C. and a pressure of 20 to 200 bar, into an alcohols stream B containing methanol, ethanol, propanol, H2, C1-C3 alkanes, CO, CO2 and water, (3) separating stream B, into a stream C containing the CO, C1-C3 alkanes, H2 and methanol; a stream D containing the CO2; and recovering a stream E containing the ethanol, propanol(s) and water, (4) treating a fraction of stream C in order to separate the fraction into a stream containing CO, and a stream containing H2 and the C1-C3 alkanes, (5) reintroducing at least part of stream C together with the stream containing CO from step 4 into the oxygenate synthesis reactor of step 2, and (6) reintroducing at least part of stream D into the auto-thermal reactor of step (1).
摘要翻译：将烃原料转化为醇的方法，其中烃首先转化为合成气，其随后转化成醇。该方法通过以下步骤进行：（1）将烃原料与氧原料一起在自热反应器（ATR）中转化成含有碳氧化物和氢气混合物的料流A ，（2）在含氧化合物反应器中的催化剂存在下，在150-400℃和20-200巴之间的温度下将至少一部分流A转化成含有甲醇的醇流B，乙醇，丙醇，H 2，C 1 -C 3烷烃，CO，CO 2和水，（3）将料流B分离成含有CO，C 1 -C 3烷烃，H 2和甲醇的料流C; 含有二氧化碳的流D; 并回收含有乙醇，丙醇和水的流E，（4）处理流C的馏分以将馏分分离成含有CO的物流，以及含有H 2和C 1 -C 3烷烃的物流（ 5）将至少一部分流C与来自步骤4的含CO的物流一起重新引入到步骤2的含氧化合物合成反应器中，和（6）将至少一部分流D重新引入到步骤（1）的自热反应器中。

5. 发明申请

US20100069514A1 PROCESS FOR THE CONVERSION OF HYDROCARBONS TO OXYGENATES 有权
标题翻译：将烃转化为氧化剂的方法
公开(公告)号：US20100069514A1
公开(公告)日：2010-03-18
申请号：US12311944
申请日：2007-10-17
申请人： Benjamin Patrick Gracey , Michael Keith Lee
发明人： Benjamin Patrick Gracey , Michael Keith Lee
IPC分类号： C07C29/151
CPC分类号： C07C29/1518 , C07C31/04 , C07C31/08 , C07C31/10 , C07C31/12
摘要： The present invention provides a process, that has a reduced level of CO2 emissions, for the conversion of hydrocarbons into alcohol(s) in the presence of a catalyst.
摘要翻译：本发明提供了一种在催化剂存在下将烃转化成醇的方法，其具有降低的CO 2排放水平。

6. 发明申请

US20090281362A1 Process for Producing Propylene 有权
标题翻译：生产丙烯的方法
公开(公告)号：US20090281362A1
公开(公告)日：2009-11-12
申请号：US12085704
申请日：2006-11-22
申请人： Craig Bailey , Leslie William Bolton , Benjamin Patrick Gracey , Michael Keith Lee , Stephen Roy Partington
发明人： Craig Bailey , Leslie William Bolton , Benjamin Patrick Gracey , Michael Keith Lee , Stephen Roy Partington
IPC分类号： C07C1/24 , C07C11/06 , C07C1/00
CPC分类号： C07C1/24 , C07C2521/08 , C07C2521/16 , C07C2527/173 , C07C2527/188 , C07C2527/19 , C07C2529/18 , Y02P20/582 , C07C11/06
摘要： The present invention relates to a process for the production of propylene from a feedstock comprising propanol.
摘要翻译：本发明涉及从包含丙醇的原料生产丙烯的方法。

7. 发明申请

US20090048354A1 Process for the Conversion of Synthesis Gas to Oxygenates Containing C2+ Alcohols 有权
标题翻译：将合成气转化为含有C2 +醇的含氧物的方法
公开(公告)号：US20090048354A1
公开(公告)日：2009-02-19
申请号：US11988211
申请日：2006-06-29
申请人： Peter Simpson Bell , Leslie William Bolton , Benjamin Patrick Gracey , Michael Keith Lee
发明人： Peter Simpson Bell , Leslie William Bolton , Benjamin Patrick Gracey , Michael Keith Lee
IPC分类号： C07C27/10
CPC分类号： C07C29/1518 , C07C29/1516 , C07C31/04 , C07C31/08 , C07C31/10
摘要： The present invention provides a process for the conversion of carbon oxide(s) and hydrogen containing feedstocks into alcohols in the presence of a particulate catalyst.
摘要翻译：本发明提供了在颗粒催化剂存在下将碳氧化物和含氢原料转化成醇的方法。

8. 发明授权

US08426664B2 Process for producing ethylene 有权
标题翻译：生产乙烯的方法
公开(公告)号：US08426664B2
公开(公告)日：2013-04-23
申请号：US12085703
申请日：2006-11-22
申请人： Craig Bailey , Leslie William Bolton , Benjamin Patrick Gracey , Michael Keith Lee , Stephen Roy Partington
发明人： Craig Bailey , Leslie William Bolton , Benjamin Patrick Gracey , Michael Keith Lee , Stephen Roy Partington
IPC分类号： C07C1/24
CPC分类号： C07C1/24 , C07C2521/08 , C07C2521/16 , C07C2527/188 , C07C2527/19 , C07C2529/18 , Y02P20/582 , C07C11/04
摘要： Process for producing ethylene from an ethanol feedstock A by (1) reacting the ethanol feedstock A in a vapor phase reactor wherein the ethanol is converted at a temperature between 160 and 270° C. and at a pressure of above 0.1 MPa but less than 4.5 MPa, into a product stream B containing ethylene, diethyl ethers, water and unconverted ethanol, (2) cooling the product stream B, (3) disengaging the cooled product stream B in a separation unit to give a first stream C containing ethylene and diethyl ethers, and a second product stream D containing water, diethyl ethers and unconverted ethanol, (4) feeding the product stream D to a dewatering unit wherein the water stream F is separated from the diethyl ethers and unconverted ethanol stream E, (5) recycling the stream E into the dehydration reactor of step 1, (6) cooling the product stream C, and (7) feeding the cooled product stream C to a purification unit wherein the diethyl ethers stream G is separated from the ethylene stream H. Optionally, the ethyl ethers stream G is recycled to either the dewatering unit of step (4) or directly to dehydration reactor of step (1).
摘要翻译：通过（1）使乙醇原料A在气相反应器中反应，其中乙醇在160-270℃之间的温度和在0.1MPa以上但小于4.5的压力下进行转化，从乙醇原料A生产乙烯的方法 MPa，加入含有乙烯，二乙醚，水和未转化乙醇的产物流B中，（2）冷却产物流B，（3）在分离单元中使冷却的产物流B脱离，得到含有乙烯和二乙基醚和含有水，二乙醚和未转化乙醇的第二产物流D，（4）将产物流D供给脱水单元，其中水流F与二乙醚和未转化的乙醇流E分离，（5）回收将流E进入步骤1的脱水反应器，（6）冷却产物流C，和（7）将冷却的产物流C供给到纯化单元，其中二乙醚流G与乙烯流H分离。乙醚流G被再循环到步骤（4）的脱水单元或直接转移到步骤（1）的脱水反应器中。

9. 发明授权

US08440873B2 Process for producing olefins 有权
标题翻译：烯烃生产方法
公开(公告)号：US08440873B2
公开(公告)日：2013-05-14
申请号：US12085635
申请日：2006-11-22
申请人： Craig Bailey , Leslie William Bolton , Benjamin Patrick Gracey , Michael Keith Lee , Stephen Roy Partington
发明人： Craig Bailey , Leslie William Bolton , Benjamin Patrick Gracey , Michael Keith Lee , Stephen Roy Partington
IPC分类号： C07C1/24
CPC分类号： C07C1/24 , C07C1/20 , Y02P20/582 , Y02P30/42 , C07C11/02
摘要： Process for producing mono-olefins(s) from a feedstock A containing ethanol and propanol, wherein ethanol and propanol are dehydrated into the corresponding same carbon number olefins. The process is performed by 1. reacting feedstock A in a vapor phase dehydration reactor wherein the ethanol and propanol alcohols are converted into a product stream B comprising ethylene, propylene, ethers, water and unconverted alcohols, 2. cooling the product stream B, 3. disengaging the cooled product stream B in a separation unit to give a first stream C containing ethylene, propylene and ethers, and a second product stream D containing water, ethers and unconverted alcohols, 4. feeding the product stream D to a dewatering column wherein the water stream F is separated from the ethers and unconverted alcohols stream E, 5. recycling the stream E into the dehydration reactor of step 1, and 6. cooling the product stream C. In a step 7, the cooled product stream C is fed to a purification unit wherein the ethers stream G is separated from the ethylene and propylene stream H, and in an optional step 8, the ethers stream G is recycled to either the dewatering column of step 4 and/or directly to dehydration reactor of step 1.
摘要翻译：从含有乙醇和丙醇的原料A生产单烯烃的方法，其中乙醇和丙醇被脱水成相应的相同碳数的烯烃。该方法通过以下方式进行：1.将原料A在气相脱水反应器中反应，其中乙醇和丙醇醇转化成包含乙烯，丙烯，醚，水和未转化的醇的产物流B. 2.冷却产物流B，3 使分离单元中的冷却的产物流B脱离，得到含有乙烯，丙烯和醚的第一流C，以及含有水，醚和未转化的醇的第二产物流D.将产物流D送入脱水塔，将水流F与醚和未转化的醇流E，5分离，将流E再循环到步骤1的脱水反应器中，和6.冷却产物流C.在步骤7中，将冷却的产物流C 涉及一种净化单元，其中醚流G与乙烯和丙烯料流H分离，并且在任选的步骤8中，将醚流G再循环至步骤4的脱水塔和/或二直接进入步骤1的脱水反应器。

10. 发明申请

US20100016454A1 PROCESS FOR THE CONVERSION OF HYDROCARBONS TO ALCOHOLS 有权
标题翻译：将烃转化为醇的方法
公开(公告)号：US20100016454A1
公开(公告)日：2010-01-21
申请号：US12311941
申请日：2007-10-17
申请人： Benjamin Patrick Gracey , Michael Keith Lee
发明人： Benjamin Patrick Gracey , Michael Keith Lee
IPC分类号： C07C29/151
CPC分类号： C07C29/1518 , C07C31/04 , C07C31/08 , C07C31/10 , C07C31/12
摘要： The present invention provides a process, that has a reduced level of CO2 emissions, for the conversion of hydrocarbons into alcohol(s) in the presence of a catalyst.
摘要翻译：本发明提供了一种在催化剂存在下将烃转化成醇的方法，其具有降低的CO 2排放水平。

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