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    • 5. 发明申请
    • Ink Composition, Recording Method Using the Same, and Recorded Matter
    • 油墨成分,使用它的记录方法和记录的物质
    • US20090220748A1
    • 2009-09-03
    • US11887173
    • 2006-03-28
    • Miharu KanayaTetsuya AoyamaMasahiro HanmuraTeruo Naito
    • Miharu KanayaTetsuya AoyamaMasahiro HanmuraTeruo Naito
    • B32B5/00C08L67/00B05D5/00
    • C09D11/30C01P2004/64C09C3/10C09D11/106C09D11/326Y10T428/24802
    • An object of the present invention is to provide an ink composition which can provide an image having excellent glossy texture to various recording media, particularly to a glossy recording medium, is decreased in bronzing phenomenon, and is also good in fixing property and scratch resistance such as gloss change. The invention relates to an ink composition containing at least a coloring agent coated with a water-insoluble polymer as a coloring material and a resin emulsion as an additive, wherein the weight average molecular weight of the water-insoluble polymer is from 50,000 to 150,000, and wherein the resin emulsion comprises a resin comprising a monomer component of the same kind as the monomer component constituting the water-insoluble polymer and having a weight average molecular weight of 1.5 to 4 times that of the water-insoluble polymer; and an ink composition containing at least a coloring agent coated with a water-insoluble polymer and resin particles, wherein the water-insoluble polymer is a polymer obtained by a solution polymerization process using at least a polymerizable unsaturated monomer and a polymerization initiator, wherein the coloring agent coated with the water-insoluble polymer is a coloring material obtained by a phase inversion emulsification process in which after the water-insoluble polymer is dissolved in an organic solvent, at least the coloring agent and water are added thereto, followed by mixing, and the organic solvent is removed to perform dispersion in an aqueous system, and wherein the resin particles are a polymer obtained by an emulsion polymerization process using at least a crosslinking agent.
    • 本发明的目的是提供一种油墨组合物,其可以为各种记录介质,特别是光泽记录介质提供具有优异光泽质地的图像,减少了烫金现象,并且还具有良好的定影性和耐擦伤性 作为光泽变化。 本发明涉及一种油墨组合物,其至少包含涂覆有作为着色材料的水不溶性聚合物的着色剂和作为添加剂的树脂乳液,其中所述水不溶性聚合物的重均分子量为50,000-150000, 并且其中所述树脂乳液包含包含与构成所述水不溶性聚合物的单体成分相同种类的单体组分并且重均分子量为所述水不溶性聚合物的1.5-4倍的树脂; 以及至少含有涂覆有水不溶性聚合物和树脂颗粒的着色剂的油墨组合物,其中所述水不溶性聚合物是通过使用至少一种可聚合不饱和单体和聚合引发剂的溶液聚合方法获得的聚合物,其中, 涂布有水不溶性聚合物的着色剂是通过相转化乳化法得到的着色剂,其中将水不溶性聚合物溶解在有机溶剂中后,至少加入着色剂和水,然后混合, 除去有机溶剂以在水性体系中进行分散,并且其中树脂颗粒是通过使用至少一种交联剂的乳液聚合方法获得的聚合物。
    • 6. 发明申请
    • Ink set, and recording method and recorded matter using the same
    • 墨水设定,记录方法和使用记录的物质
    • US20060256175A1
    • 2006-11-16
    • US11392985
    • 2006-03-29
    • Miharu Kanaya
    • Miharu Kanaya
    • B41J2/17C09D11/02
    • C09D11/40
    • The present invention provides an ink set comprising at least two or more pigment inks different in color, wherein differences in average particle size between the inks different in color are 30 nm or less, the inks each have a sedimentation rate, as indicated by equation (I), of 15% or less, and differences in the sedimentation rate between the inks different in color are 4% or less: Sedimentation rate (%)=(S0−S1)/S0×100   (I) wherein S0 represents an “initial ink concentration”, which is an absorbance at a wavelength of λ max (or at 500 nm when λ max is not detected) at the time when UV spectral characteristics are measured for a 1000-fold diluted solution of the ink; and S1 represents an “ink concentration after sedimentation”, which is an absorbance at a wavelength of λ max (or at 500 nm when λ max is not detected) at the time when UV spectral characteristics are measured for a 1000-fold diluted solution of a supernatant obtained by centrifuging the ink at 16500 G at 1.60×107 g·sec.
    • 本发明提供了一种包含至少两种或多种不同颜色的颜料油墨的油墨组,其中颜色不同的油墨之间的平均颗粒尺寸的差异为30nm以下,油墨各自具有沉降速率,如式 I)为15%以下,颜色不同的油墨之间的沉降速度差为4%以下:<?在线配方说明=“在线式”末端=“铅”→沉淀 速率(%)=(S 0 -S -S 1)/ S 0 x 100(I)<β在线公式描述=“ 其中S 表示“初始油墨浓度”,其为λmax波长处的吸光度(或当λmax不为500nm时) 在对1000倍稀释的油墨溶液测量UV光谱特性时,检测) 并且S 1表示“UV沉淀后的墨浓度”,其是测量紫外光谱特性时λ波长(或未检测到λmax时为500nm时)的吸光度 对于1000倍稀释的通过在16500G下以1.60×10 7毫秒离心油墨获得的上清液。
    • 8. 发明授权
    • Aqueous ink composition and method of recording using the same
    • 水性油墨组合物及其使用方法
    • US5704969A
    • 1998-01-06
    • US569245
    • 1996-04-16
    • Miharu KanayaAkio Owatari
    • Miharu KanayaAkio Owatari
    • C09B47/26C09D11/00C09D11/322C09D11/328C09D11/40C09D11/02
    • C09D11/328C09B47/26
    • A cyan ink comprising a phthalocyanine derivative represented by the following formula (I), excellent in color reproducibility, suitable for use in the ink jet recording method is disclosed. The combination use of this cyan ink comprising the phthalocyanine derivative with yellow and magenta inks, each comprising a specific dye, gives excellent color printing. ##STR1## wherein X represents an ion of a metal selected from Cu, Fe, Co and Ni, R.sup.1 represents H or an alyl group, Z represents --O, --COOH or NR.sup.2 R.sup.3 (where R.sup.2 represents H or an alkyl group, and R.sup.3 represents an alkyl group or phenyl group), n represents an integer of 1 to 15, k and l represent 0 or 1, and m represents an integer of 1 to 4, provided that k, l and m fulfill the inequality 2.ltoreq.k+1+m.ltoreq.4.
    • PCT No.PCT / JP95 / 00815 Sec。 371日期1996年04月16日 102(e)日期1996年4月16日PCT提交1995年4月25日PCT公布。 WO95 / 29208 PCT出版物 日期:1995年11月2日公开了一种包含由下式(I)表示的酞菁衍生物的青色油墨,其颜色再现性优异,适用于喷墨记录方法。 包含酞菁衍生物的这种青色油墨与黄色和品红色油墨的组合使用,每种都含有特定的染料,得到优异的彩色印刷。 (I)其中X表示选自Cu,Fe,Co和Ni的金属离子,R1表示H或烯丙基,Z表示-O,-COOH或NR2R3(其中R2表示H或烷基 ,R3表示烷基或苯基),n表示1至15的整数,k和l表示0或1,m表示1至4的整数,条件是k,l和m满足不等式2
    • 10. 发明授权
    • Ink set, and ink jet recording method using the ink set
    • 油墨组和使用油墨组的喷墨记录方法
    • US08142560B2
    • 2012-03-27
    • US12383429
    • 2009-03-24
    • Chie SaitoMiharu Kanaya
    • Chie SaitoMiharu Kanaya
    • C09D11/02
    • B41M5/0023C08K9/04
    • An ink set including two or more kinds of ink compositions including at least a black ink composition and a color ink composition, in which the black ink composition includes a self-dispersion type pigment having a hydrophilic group on the surface thereof, the color ink composition includes a self-dispersion type pigment having a hydrophilic group on the surface thereof with a phenyl group, and all the ink compositions include resin emulsion, is used in an ink jet recording method. Provision of an ink set for ink jet recording, which is capable of realizing a good image, in addition to high color developability, high ejection stability, high clogging recovering properties, and high fixability.
    • 一种油墨组,包括至少包含黑色油墨组合物和彩色油墨组合物的两种或更多种油墨组合物,其中黑色油墨组合物包括其表面上具有亲水基团的自分散型颜料,彩色油墨组合物 包括在其表面上具有苯基的亲水基团的自分散型颜料,并且所有的油墨组合物包括树脂乳液都用于喷墨记录方法。 除了高显色性,高喷射稳定性,高堵塞恢复性能和高定影性之外,还提供了能够实现良好图像的喷墨记录用油墨组。