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    • 8. 发明申请
    • MODIFIED ANODE/ELECTROLYTE STRUCTURE FOR A SOLID OXIDE ELECTROCHEMICAL CELL AND A METHOD FOR MAKING SAID STRUCTURE
    • 一种固体氧化物电化学细胞的改性阳极/电解质结构及制备结构的方法
    • US20140287341A1
    • 2014-09-25
    • US14353583
    • 2012-10-23
    • Mohammed Hussain Abdul JabbarJens HøghEugen Stamate
    • Mohammed Hussain Abdul JabbarJens HøghEugen Stamate
    • C25B11/04H01M8/12
    • C25B11/0426C25B11/041H01M4/8621H01M4/8846H01M4/8885H01M4/9058H01M4/9066H01M8/1213H01M8/124H01M2008/1293Y02P70/56
    • A novel modified anode/electrolyte structure for a solid oxide electrochemical cell is an assembly comprising (a) an anode consisting of a backbone of electronically conductive perovskite oxides selected from the group of doped strontium titanates and mixtures thereof, (b) a scandia and yttria-stabilised zirconium oxide electrolyte and (c) a metallic and/or a ceramic electrocatalyst in the shape of interlayers incorporated in the interface between the anode and the electrolyte. This assembly is first sintered at a given temperature and then at a lower temperature in reducing gas mixtures. These heat treatments resulted in a distribution of the metallic and/or ceramic interlayers in the electrolyte/anode backbone junction taking place. The structure is prepared by (a) depositing a ceramic interlayer onto one side of the electrolyte, (b) optionally applying a metallic interlayer thereon, (c) repeating steps (a) and (b), (d) applying a layer of the selected anode backbone onto the electrolyte with applied interlayers, (e) sintering the raw assembly and (f) infiltrating the electrocatalyst precursor into the sintered assembly and heat treating the assembly to incorporate additional electrocatalyst into the anode backbone.
    • 用于固体氧化物电化学电池的新型改性阳极/电解质结构是一种组件,其包括(a)由选自掺杂的钛酸锶锶及其混合物的电子导电钙钛矿氧化物的主链组成的阳极,(b)钪和氧化钇 稳定的氧化锆电解质和(c)金属和/或陶瓷电催化剂,其形成为并入阳极和电解质之间的界面中的夹层。 该组件首先在给定温度下烧结,然后在较低温度下在还原性气体混合物中烧结。 这些热处理导致发生在电解质/阳极主链结中的金属和/或陶瓷夹层的分布。 通过(a)在电解质的一侧上沉积陶瓷中间层来制备该结构,(b)任选在其上施加金属中间层,(c)重复步骤(a)和(b),(d) (e)烧结原始组件和(f)将电催化剂前体渗透到烧结组件中并热处理该组件以将额外的电催化剂结合到阳极骨架中。