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    • 10. 发明授权
    • Process for separating mixtures of hydrocarbon isomers in gas phase on molecular sieves
    • 在分子筛上分离气相中烃异构体的混合物的方法
    • US06924406B2
    • 2005-08-02
    • US09886994
    • 2001-06-25
    • Gianluca GirardiGianni PandolfiRenzo BignazziRenato Paludetto
    • Gianluca GirardiGianni PandolfiRenzo BignazziRenato Paludetto
    • C07C7/13C07C9/14C07C15/04C07C15/06C07C15/073C07C15/08C10G25/03C10G53/08C07C7/12
    • C07C7/13
    • A process for separating mixtures of hydrocarbon isomers on molecular sieves, including providing columns which include molecular sieves and function alternatively as secondary adsorption, primary adsorption, and desorption devices, feeding the mixtures of hydrocarbon isomers to a column functioning as the primary adsorption device for adsorbing isomers with greater selectivity towards the molecular sieves, feeding effluent of the mixtures from the column functioning as the primary adsorption device to a column functioning as the secondary adsorption device for adsorbing remaining isomers with greater selectivity, discharging isomers with a lower selectivity from the column functioning as the secondary adsorption device and a desorbing agent therein, feeding a desorbing agent to the column functioning as the desorption device, discharging isomers with a greater selectivity towards the molecular sieves and the desorbing agent in the column functioning as the desorption device.
    • 分子筛上分离烃异构体的混合物的方法,包括提供包括分子筛的色谱柱,或者作为二次吸附,主要吸附和解吸装置的功能,将烃异构体的混合物供给到用作吸附的主要吸附装置的塔 对分子筛具有更高选择性的异构体,将来自作为主要吸附装置的塔的混合物的流出物供给到用作用于以更高选择性吸附剩余的异构体的第二吸附装置的塔,从柱的功能以较低的选择性排出异构体 作为第二吸附装置和解吸剂,将脱附剂供给到用作解吸装置的塔中,以用作解吸装置的塔中的分子筛和解吸剂以更大的选择性排出异构体。