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1. 发明授权

US08598271B2 Block copolymer composition, film, and method for producing block copolymer composition 有权
标题翻译：嵌段共聚物组合物，膜，以及嵌段共聚物组合物的制造方法
公开(公告)号：US08598271B2
公开(公告)日：2013-12-03
申请号：US13141950
申请日：2009-12-25
申请人： Ryouji Oda , Takeshi Ooishi
发明人： Ryouji Oda , Takeshi Ooishi
IPC分类号： C08L53/02 , C08F295/00
CPC分类号： C08L53/02 , C08F297/044 , C08J5/18 , C08J2353/02 , C08L2205/025
摘要： An object of the present invention is to provide a block copolymer composition containing an aromatic vinyl-conjugated diene-aromatic vinyl block copolymer, which is capable of achieving a high-level balance between a high elastic modulus and a small permanent set, and is capable of producing a highly isotropic molded product having uniform mechanical properties even when a molding method which is likely to cause molecular orientation, such as extrusion molding, is applied. The object is attained by providing a block copolymer composition comprising a block copolymer A represented by the following Formula (A) and a block copolymer B represented by the following Formula (B), wherein a weight ratio (A/B) between the block copolymer A and the block copolymer B is 36/64 to 85/15: Ar1a−Da−Ar2a (A) (Arb−Db)n−X (B), in the Formulae (A) and (B), Ar1a and Arb each represent an aromatic vinyl polymer block having a weight average molecular weight of 6,000 to 15,000; Ar2a represents an aromatic vinyl polymer block having a weight average molecular weight of 40,000 to 400,000; Wand Db each represent a conjugated diene polymer block having a vinyl bond content of 1 mol % to 20 mol %; X represents a residue of a coupling agent; and n represents an integer of 3 or greater.
摘要翻译：本发明的目的是提供一种含有芳族乙烯基 - 共轭二烯 - 芳族乙烯基嵌段共聚物的嵌段共聚物组合物，其能够实现高弹性模量与小永久变形体之间的高水平平衡，并且能够即使应用可能引起分子取向的成型方法，例如挤出成型，也可以制造具有均匀机械性能的高度各向同性的成型体。该目的通过提供一种嵌段共聚物组合物来实现，该嵌段共聚物组合物包含由下式（A）表示的嵌段共聚物A和由下式（B）表示的嵌段共聚物B，其中嵌段共聚物 A和嵌段共聚物B在式（A）和（B）中为36/64〜85/15：Ar1a-Da-Ar2a（A）（Arb-Db）nX（B），Ar1a和Arb分别表示重均分子量为6000〜15000的芳族乙烯基聚合物嵌段; Ar2a表示重均分子量为40,000〜400,000的芳族乙烯基聚合物嵌段; 禾谷Db各自表示乙烯基键含量为1摩尔％至20摩尔％的共轭二烯聚合物嵌段; X表示偶联剂的残基; n表示3以上的整数。

2. 发明申请

US20110257336A1 BLOCK COPOLYMER COMPOSITION, FILM, AND METHOD FOR PRODUCING BLOCK COPOLYMER COMPOSITION 有权
标题翻译：嵌段共聚物组合物，薄膜和生产嵌段共聚物组合物的方法
公开(公告)号：US20110257336A1
公开(公告)日：2011-10-20
申请号：US13141950
申请日：2009-12-25
申请人： Ryouji Oda , Takeshi Ooishi
发明人： Ryouji Oda , Takeshi Ooishi
IPC分类号： C08L53/02
CPC分类号： C08L53/02 , C08F297/044 , C08J5/18 , C08J2353/02 , C08L2205/025
摘要： An object of the present invention is to provide a block copolymer composition containing an aromatic vinyl-conjugated diene-aromatic vinyl block copolymer, which is capable of achieving a high-level balance between a high elastic modulus and a small permanent set, and is capable of producing a highly isotropic molded product having uniform mechanical properties even when a molding method which is likely to cause molecular orientation, such as extrusion molding, is applied. The object is attained by providing a block copolymer composition comprising a block copolymer A represented by the following Formula (A) and a block copolymer B represented by the following Formula (B), wherein a weight ratio (A/B) between the block copolymer A and the block copolymer B is 36/64 to 85/15: Ar1a−Da−Ar2a (A) (Arb−Db)n−X (B), in the Formulae (A) and (B), Ar1a and Arb each represent an aromatic vinyl polymer block having a weight average molecular weight of 6,000 to 15,000; Ar2a represents an aromatic vinyl polymer block having a weight average molecular weight of 40,000 to 400,000; Wand Db each represent a conjugated diene polymer block having a vinyl bond content of 1 mol % to 20 mol %; X represents a residue of a coupling agent; and n represents an integer of 3 or greater.
摘要翻译：本发明的目的是提供一种含有芳族乙烯基 - 共轭二烯 - 芳族乙烯基嵌段共聚物的嵌段共聚物组合物，其能够实现高弹性模量与小永久变形体之间的高水平平衡，并且能够即使应用可能引起分子取向的成型方法，例如挤出成型，也可以制造具有均匀机械性能的高度各向同性的成型体。该目的通过提供一种嵌段共聚物组合物来实现，该嵌段共聚物组合物包含由下式（A）表示的嵌段共聚物A和由下式（B）表示的嵌段共聚物B，其中嵌段共聚物 A和嵌段共聚物B在式（A）和（B）中为36/64〜85/15:Ar1a-Da-Ar2a（A）（Arb-Db）n-X（B），Ar1a和Arb各自代表重均分子量为6,000至15,000的芳族乙烯基聚合物嵌段; Ar2a表示重均分子量为40,000〜400,000的芳族乙烯基聚合物嵌段; 禾谷Db各自表示乙烯基键含量为1摩尔％至20摩尔％的共轭二烯聚合物嵌段; X表示偶联剂的残基; n表示3以上的整数。

3. 发明授权

US5733235A Rubber covered roll, rubber composition, and image-forming apparatus 失效
标题翻译：橡胶覆盖辊，橡胶组合物和成像装置
公开(公告)号：US5733235A
公开(公告)日：1998-03-31
申请号：US561606
申请日：1995-11-21
申请人： Tetsuo Waku , Hiromitsu Kikuchi , Takeshi Ooishi , Michiharu Yogosawa
发明人： Tetsuo Waku , Hiromitsu Kikuchi , Takeshi Ooishi , Michiharu Yogosawa
IPC分类号： G03G15/02 , B29C35/02 , B29K21/00 , B29K105/24 , B29L31/32 , C08G65/14 , C08G65/24 , C08J5/00 , C08L9/02 , C08L71/02 , C08L71/03 , F16C13/00 , G03G15/08 , G03G15/06 , B32B25/04 , B44F1/10
CPC分类号： G03G15/0818 , C08G65/14 , C08L71/02 , C08L9/02 , F16C13/00 , G03G2215/0861 , Y10T428/31826
摘要： A rubber covered roll of a structure that a rubber layer is formed on the surface of a roll-like base is provided. The rubber layer is a layer formed of a vulcanizate of a rubber composition comprising 25-95 wt. % of copolymer rubber (A) obtained by copolymerizing 28-70 mol % of an alkylene oxide, 28-70 mol % of an epihalohydrin and 2-15 mol % of an ethylenically unsaturated epoxide, and 5-75 wt. % of unsaturated rubber (B). The rubber covered roll does not contaminate any photosensitive member, stably has a low electric resistance, and is low in dependence of electric resistance on environment and in hardness. An image-forming apparatus equipped with the rubber covered roll as a development roll or charging roll, and a rubber composition for the rubber covered roll are also provided.
摘要翻译：提供了在辊状基体的表面上形成橡胶层的结构的橡胶覆盖辊。橡胶层是由橡胶组合物的硫化橡胶制成的层，所述橡胶组合物包含25-95wt。通过共聚28-70摩尔环氧烷，28-70摩尔％表卤代醇和2-15摩尔％烯键式不饱和环氧化物得到的共聚物橡胶（A）的％，和5-75重量％％的不饱和橡胶（B）。橡胶覆盖辊不会污染任何感光构件，稳定地具有低电阻，并且在电阻对环境和硬度方面依赖性低。还提供了一种装有橡胶覆盖辊作为显影辊或充电辊的图像形成装置和用于橡胶覆盖辊的橡胶组合物。

4. 发明授权

US08492480B2 Block copolymer composition, method for producing the same, and film of the same 有权
标题翻译：嵌段共聚物组合物，其制造方法及其膜
公开(公告)号：US08492480B2
公开(公告)日：2013-07-23
申请号：US12935361
申请日：2009-03-30
申请人： Takeshi Ooishi , Ryouji Oda
发明人： Takeshi Ooishi , Ryouji Oda
IPC分类号： C08L53/02 , C08F297/04 , C08J5/18
CPC分类号： C08J5/18 , C08J2353/02 , C08L53/02 , C08L2205/02 , C08L2666/24 , C08L2666/02
摘要： A block copolymer composition comprising an aromatic vinyl-conjugated diene-aromatic vinyl block copolymer having a high-level balance between a high elastic modulus and a small elongation set is provided. The block copolymer composition comprises a block copolymer A represented by formula (A) and a block copolymer B represented by formula (B), where the weight ratio of the block copolymer A to the block copolymer B, A/B, is from 36/64 to 85/15 and the ratio of the aromatic vinyl monomer units relative to all polymer components in the block copolymer composition is 27-70 wt %. Ar1a-Da-Ar2a (A). Ar1b-Db-Ar2b (B). (In the formulae, Ar1a, Ar1b and Ar2b each represent an aromatic vinyl polymer block having a weight-average molecular weight of from 6,000 to 18,000; Ar2a represents an aromatic vinyl polymer block having a weight-average molecular weight of from 40,000 to 400,000; Da and Db each represent a conjugated diene polymer block having a vinyl bond content of from 1 to 20% by mol; and Db has a weight-average molecular weight of from 60,000 to 400,000).
摘要翻译：提供了包含在高弹性模量与小伸长率之间具有高水平平衡的芳族乙烯基 - 共轭二烯 - 芳族乙烯基嵌段共聚物的嵌段共聚物组合物。嵌段共聚物组合物包含由式（A）表示的嵌段共聚物A和由式（B）表示的嵌段共聚物B，其中嵌段共聚物A与嵌段共聚物B A / B的重量比为36 / 64至85/15，并且芳族乙烯基单体单元相对于嵌段共聚物组合物中所有聚合物组分的比例为27-70重量％。 Ar1a-Da-Ar2a（A）。 Ar1b-Db-Ar2b（B）。（式中，Ar1a，Ar1b，Ar2b表示重均分子量为6,000〜18,000的芳族乙烯基聚合物嵌段; Ar2a表示重均分子量为40,000〜400000的芳香族乙烯基聚合物嵌段; Da和Db各自表示乙烯基键含量为1〜20摩尔％的共轭二烯聚合物嵌段; Db的重均分子量为6万〜40万）。

5. 发明授权

US08470929B2 Composition for stretchable film 有权
标题翻译：可拉伸薄膜的成分
公开(公告)号：US08470929B2
公开(公告)日：2013-06-25
申请号：US13255354
申请日：2010-03-29
申请人： Takeshi Ooishi , Takurou Sakurai
发明人： Takeshi Ooishi , Takurou Sakurai
IPC分类号： C08L53/02 , C08F297/04 , C08J5/18
CPC分类号： C08J5/18 , C08J2353/02 , C08L53/02 , C08L2203/16 , C08L2205/02 , Y10T442/674 , C08L2666/24
摘要： Provided is a composition for a stretchable film, which achieves a high-level balance between a high elastic modulus and a small permanent set, and can be formed into a stretchable film with satisfactory formability. A composition for a stretchable film comprises a block copolymer composition containing a block copolymer A represented by the following general formula (A) and a block copolymer B represented by the following general formula (B), and a tackifier resin: Ar1a-Da-Ar2a (A) (Arb-Db)n-X (B), in the general formulas (A) and (B), Ar1a and Arb each represent an aromatic vinyl polymer block having a weight average molecular weight of 6,000 to 20,000; Ar2a represents an aromatic vinyl polymer block having a weight average molecular weight of 40,000 to 400,000; Da and Db each represent a conjugated diene polymer block having a vinyl bond content of 1 mol % to 20 mol %; X represents a single bond or a residue of a coupling agent; and n represents an integer of 2 or greater.
摘要翻译：本发明提供一种可伸缩性的组合物，其可实现高弹性模量与小永久变形之间的高水平平衡，并且可以形成具有令人满意的成形性的伸缩性薄膜。用于可拉伸膜的组合物包含含有由以下通式（A）表示的嵌段共聚物A和由以下通式（B）表示的嵌段共聚物B的嵌段共聚物组合物和增粘树脂：Ar1a-Da-Ar2a （A）（Arb-Db）nX（B），通式（A）和（B）中，Ar1a和Arb分别表示重均分子量为6000〜20000的芳族乙烯基聚合物嵌段; Ar2a表示重均分子量为40,000〜400,000的芳族乙烯基聚合物嵌段; Da和Db各自表示乙烯基键含量为1mol％至20mol％的共轭二烯聚合物嵌段; X表示单键或偶联剂的残基; n表示2以上的整数。

6. 发明申请

US20110318987A1 COMPOSITION FOR STRECHABLE FILM 有权
标题翻译：可组合胶片的组合物
公开(公告)号：US20110318987A1
公开(公告)日：2011-12-29
申请号：US13255354
申请日：2010-03-29
申请人： Takeshi Ooishi , Takurou Sakurai
发明人： Takeshi Ooishi , Takurou Sakurai
IPC分类号： B32B27/12 , B32B37/14 , B29C70/00 , C08L53/02 , B29C47/00
CPC分类号： C08J5/18 , C08J2353/02 , C08L53/02 , C08L2203/16 , C08L2205/02 , Y10T442/674 , C08L2666/24
摘要： Provided is a composition for a stretchable film, which achieves a high-level balance between a high elastic modulus and a small permanent set, and can be formed into a stretchable film with satisfactory formability. A composition for a stretchable film comprises a block copolymer composition containing a block copolymer A represented by the following general formula (A) and a block copolymer B represented by the following general formula (B), and a tackifier resin: Ar1a-Da-Ar2a (A) (Arb-Db)n-X (B), in the general formulas (A) and (B), Ar1a and Arb each represent an aromatic vinyl polymer block having a weight average molecular weight of 6,000 to 20,000; Ar2a represents an aromatic vinyl polymer block having a weight average molecular weight of 40,000 to 400,000; Da and Db each represent a conjugated diene polymer block having a vinyl bond content of 1 mol % to 20 mol %; X represents a single bond or a residue of a coupling agent; and n represents an integer of 2 or greater.
摘要翻译：本发明提供一种可伸缩性的组合物，其可实现高弹性模量与小永久变形之间的高水平平衡，并且可以形成具有令人满意的成形性的伸缩性薄膜。用于可拉伸膜的组合物包含含有由以下通式（A）表示的嵌段共聚物A和由以下通式（B）表示的嵌段共聚物B的嵌段共聚物组合物和增粘树脂：Ar1a-Da-Ar2a （A）（Arb-Db）nX（B），通式（A）和（B）中，Ar1a和Arb分别表示重均分子量为6000〜20000的芳族乙烯基聚合物嵌段; Ar2a表示重均分子量为40,000〜400,000的芳族乙烯基聚合物嵌段; Da和Db各自表示乙烯基键含量为1mol％至20mol％的共轭二烯聚合物嵌段; X表示单键或偶联剂的残基; n表示2以上的整数。

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