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1. 发明申请

US20090011210A1 Lightweight glass fiber reinforced thermoplastic material 审中-公开
标题翻译：轻质玻璃纤维增强热塑性材料
公开(公告)号：US20090011210A1
公开(公告)日：2009-01-08
申请号：US12070372
申请日：2008-02-15
申请人： Xiao Gao , Thomas Arnold Ebeling , Brian Hynes , Scott Davis , Thomas Wood , Josephus Theorodus Petrus Dictus , Thomas Arnold Ebeling
发明人： Xiao Gao , Thomas Arnold Ebeling , Brian Hynes , Scott Davis , Thomas Wood , Josephus Theorodus Petrus Dictus , Thomas Arnold Ebeling
IPC分类号： B32B5/00 , B32B37/00 , B32B38/00
CPC分类号： B32B37/206 , B29C70/504 , B29K2101/12 , B29K2105/0845 , B29K2105/128 , B29K2995/0077 , B32B17/04 , B32B27/12 , B32B37/185 , B32B2260/021 , B32B2260/046 , B32B2262/101 , B32B2305/08 , B32B2307/54 , B32B2307/546 , B32B2307/72 , B32B2309/105 , B32B2315/085 , B32B2398/20 , B32B2553/00 , B32B2605/003 , C08J5/043 , Y10T156/10
摘要： A glass fiber reinforced thermoplastic sheet material is provided in which certain properties, or combinations of properties, are improved relative to similar comparative sheet materials. The sheet material generally comprises a glass mat or glass fabric fiber reinforced thermoplastic resin in which the thermoplastic resin at least partially impregnates the glass mat or fabric. The thermoplastic sheet material contains about 15 wt. % to about 65 wt. % of the glass mat or fabric based on the weight of the thermoplastic sheet material and has a thickness in the range of about 0.4 mm to about 3.0 mm. By including glass mat or fabric and maintaining the sheet thickness in the aforementioned range, the present invention thermoplastic sheet material exhibits improved flexural and/or tensile strength and modulus properties at reduced basis weight compared to a comparative thermoplastic sheet materials. A method of providing the glass fiber reinforced thermoplastic sheet material having an improved combination of flexural strength and modulus and/or tensile strength and modulus properties is also described, in which a first layer of a first thermoplastic resin, a second layer of a second thermoplastic resin, and a layer of glass mat or glass fabric are provided; the first thermoplastic resin layer, the second thermoplastic resin layer and the glass mat or glass fabric layer are arranged such that the glass mat or glass fabric layer is interposed between the first and second thermoplastic resin layers; and heat and pressure are applied to substantially melt and compress the first thermoplastic resin and/or the second thermoplastic resin and to at least partially impregnate the glass mat or glass fabric layer with the molten first thermoplastic resin and/or the molten second thermoplastic resin.
摘要翻译：提供了一种玻璃纤维增强的热塑性片材材料，其中相对于类似的比较片材材料，某些特性或性能的组合得到改善。片材通常包括玻璃毡或玻璃纤维增强热塑性树脂，其中热塑性树脂至少部分地浸渍玻璃毡或织物。热塑性片材含有约15wt。％至约65wt。基于热塑性片材的重量的玻璃毡或织物的百分比，其厚度在约0.4mm至约3.0mm的范围内。通过包括玻璃毡或织物并将片材厚度保持在上述范围内，与对比的热塑性片材相比，本发明的热塑性片材具有降低的基重的抗弯强度和/或拉伸强度和模量特性。还描述了提供具有改进的弯曲强度和/或拉伸强度和模量特性的组合的玻璃纤维增强热塑性片材的方法，其中第一热塑性树脂第一层，第二热塑性树脂的第二层树脂和一层玻璃垫或玻璃织物; 第一热塑性树脂层，第二热塑性树脂层和玻璃毡或玻璃织物层被布置成使得玻璃毡或玻璃织物层插入在第一和第二热塑性树脂层之间; 并且施加热和压力以基本上熔化和压缩第一热塑性树脂和/或第二热塑性树脂并且至少部分地用熔融的第一热塑性树脂和/或熔融的第二热塑性树脂浸渍玻璃毡或玻璃织物层。

2. 发明授权

US10059079B2 Deep draw composites and methods of using them 有权
公开(公告)号：US10059079B2
公开(公告)日：2018-08-28
申请号：US13543808
申请日：2012-07-07
申请人： Kumar Kunal , Thomas Arnold Ebeling , Jesse Guy Hipwell , Erich James Vorenkamp
发明人： Kumar Kunal , Thomas Arnold Ebeling , Jesse Guy Hipwell , Erich James Vorenkamp
IPC分类号： B32B27/02 , B32B17/02 , B32B18/00 , B32B5/02 , B32B3/00 , B32B5/14 , B32B3/26 , B32B5/26 , B32B25/16 , B32B27/12 , B32B27/28 , B32B27/30 , B32B27/32 , B32B27/34 , B32B27/36 , B32B27/40 , B32B5/18 , B32B5/24
CPC分类号： B32B5/145 , B32B3/26 , B32B3/266 , B32B5/022 , B32B5/026 , B32B5/18 , B32B5/245 , B32B5/26 , B32B25/16 , B32B27/12 , B32B27/28 , B32B27/281 , B32B27/285 , B32B27/30 , B32B27/302 , B32B27/308 , B32B27/32 , B32B27/34 , B32B27/365 , B32B27/40 , B32B2250/40 , B32B2262/02 , B32B2262/101 , B32B2262/105 , B32B2262/106 , B32B2270/00 , B32B2274/00 , B32B2307/50 , B32B2307/54 , B32B2307/718 , B32B2605/00 , B32B2605/08 , Y02B10/30 , Y10T428/24 , Y10T428/249986 , Y10T428/269 , Y10T428/273 , Y10T442/674
摘要： Certain embodiments described herein are directed to composite materials effective for use in deep draw processes. In some examples, the composites can be used to provide vehicle panels such as, for example, vehicle underbody panels. In some configurations, the composite comprises a fiber reinforced polymer core and a skin material disposed on at least some portion of the fiber reinforced polymer core, in which the skin material comprises a basis weight of at least 65 g/m2 and an elongation at break of at least 20%.

3. 发明申请

US20130292076A1 FIBER REINFORCED THERMOPLASTIC SHEETS WITH SURFACE COVERINGS 审中-公开
公开(公告)号：US20130292076A1
公开(公告)日：2013-11-07
申请号：US13827866
申请日：2013-03-14
申请人： Venkat Krishna Raghavendran , Thomas Arnold Ebeling
发明人： Venkat Krishna Raghavendran , Thomas Arnold Ebeling
IPC分类号： D21H13/40
CPC分类号： B32B27/06 , B32B5/28 , B32B27/08 , B32B2260/021 , B32B2260/046 , B32B2307/3065 , B32B2419/00 , B32B2605/00 , D21H13/20 , D21H13/40 , Y10T428/31507 , Y10T428/31551 , Y10T428/31562 , Y10T428/31721 , Y10T428/31833
摘要： A composite sheet material in one embodiment includes a porous core layer. The porous core layer includes a thermoplastic polymer, about 20 weight percent to about 80 weight percent of reinforcing fibers based on a total weight of the porous core layer, and an effective amount of a flame retardant agent.

4. 发明申请

US20200031091A1 DEEP DRAW COMPOSITES AND METHODS OF USING THEM 审中-公开
公开(公告)号：US20200031091A1
公开(公告)日：2020-01-30
申请号：US16113616
申请日：2018-08-27
申请人： Kunar Kumal , Thomas Arnold Ebeling , Jesse Guy Hipwell , Erich James Vorenkamp
发明人： Kunar Kumal , Thomas Arnold Ebeling , Jesse Guy Hipwell , Erich James Vorenkamp
IPC分类号： B32B5/14 , B32B5/02 , B32B25/16 , B32B27/12 , B32B27/28 , B32B27/30 , B32B27/32 , B32B27/34 , B32B27/36 , B32B27/40 , B32B5/18 , B32B5/24 , B32B3/26 , B32B5/26
摘要： Certain embodiments described herein are directed to composite materials effective for use in deep draw processes. In some examples, the composites can be used to provide vehicle panels such as, for example, vehicle underbody panels. In some configurations, the composite comprises a fiber reinforced polymer core and a skin material disposed on at least some portion of the fiber reinforced polymer core, in which the skin material comprises a basis weight of at least 65 g/m2 and an elongation at break of at least 20%.

5. 再颁专利

USRE44893E1 Fiber reinforced thermoplastic sheets with surface coverings 有权
标题翻译：具有表面覆盖层的纤维增强热塑性片材
公开(公告)号：USRE44893E1
公开(公告)日：2014-05-13
申请号：US13427131
申请日：2012-03-22
申请人： Venkat Krishna Raghavendran , Thomas Arnold Ebeling
发明人： Venkat Krishna Raghavendran , Thomas Arnold Ebeling
IPC分类号： B32B27/36 , B32B27/38
CPC分类号： D21H13/40 , B32B5/28 , C08G64/10 , C08J5/043 , D21H21/34 , Y10T428/31507 , C08K7/14 , C08L69/00
摘要： A composite sheet material in one embodiment includes a porous core layer. The porous core layer includes a thermoplastic polymer, about 20 weight percent to about 80 weight percent of reinforcing fibers based on a total weight of the porous core layer, and an effective amount of a flame retardant agent.
摘要翻译：在一个实施例中的复合片材包括多孔芯层。多孔芯层包括热塑性聚合物，基于多孔芯层的总重量为约20重量％至约80重量％的增强纤维和有效量的阻燃剂。

6. 发明申请

US20130101822A1 DEEP DRAW COMPOSITES AND METHODS OF USING THEM 审中-公开
标题翻译：深层复合材料及其使用方法
公开(公告)号：US20130101822A1
公开(公告)日：2013-04-25
申请号：US13543808
申请日：2012-07-07
申请人： Kumar Kunal , Thomas Arnold Ebeling , Jesse Guy Hipwell , Erich James Vorenkamp
发明人： Kumar Kunal , Thomas Arnold Ebeling , Jesse Guy Hipwell , Erich James Vorenkamp
IPC分类号： B32B3/26 , B32B27/04 , B32B27/02 , B32B17/02 , B32B18/00 , B32B15/02 , B32B5/02 , B32B3/00
CPC分类号： B32B5/145 , B32B3/26 , B32B3/266 , B32B5/022 , B32B5/026 , B32B5/18 , B32B5/245 , B32B5/26 , B32B25/16 , B32B27/12 , B32B27/28 , B32B27/281 , B32B27/285 , B32B27/30 , B32B27/302 , B32B27/308 , B32B27/32 , B32B27/34 , B32B27/365 , B32B27/40 , B32B2250/40 , B32B2262/02 , B32B2262/101 , B32B2262/105 , B32B2262/106 , B32B2270/00 , B32B2274/00 , B32B2307/50 , B32B2307/54 , B32B2307/718 , B32B2605/00 , B32B2605/08 , Y02B10/30 , Y10T428/24 , Y10T428/249986 , Y10T428/269 , Y10T428/273 , Y10T442/674
摘要： Certain embodiments described herein are directed to composite materials effective for use in deep draw processes. In some examples, the composites can be used to provide vehicle panels such as, for example, vehicle underbody panels. In some configurations, the composite comprises a fiber reinforced polymer core and a skin material disposed on at least some portion of the fiber reinforced polymer core, in which the skin material comprises a basis weight of at least 65 g/m2 and an elongation at break of at least 20%.
摘要翻译：本文描述的某些实施例涉及有效用于深拉伸工艺的复合材料。在一些示例中，复合材料可用于提供车辆面板，例如车辆底板。在一些构造中，复合材料包括纤维增强聚合物芯和设置在纤维增强聚合物芯的至少一部分上的表皮材料，其中表皮材料包含至少65g / m 2的基重和断裂伸长率至少20％。

7. 发明申请

US20120232211A1 Thermoplastic composite material with improved smoke generation, heat release, and mechanical properties 审中-公开
标题翻译：具有改善烟雾产生，放热和机械性能的热塑性复合材料
公开(公告)号：US20120232211A1
公开(公告)日：2012-09-13
申请号：US13416617
申请日：2012-03-09
申请人： Sandra Fritz Vos , Thomas Arnold Ebeling
发明人： Sandra Fritz Vos , Thomas Arnold Ebeling
IPC分类号： C08L79/08 , C08K7/02 , C08L69/00
CPC分类号： B29C70/504 , B29B7/90 , B29C65/48 , B29C66/712 , B29K2079/085 , B29K2105/04 , B29K2105/06 , B29K2309/08 , B29L2009/00 , B32B5/022 , B32B5/024 , B32B5/028 , B32B5/08 , B32B5/26 , B32B17/04 , B32B27/08 , B32B27/12 , B32B27/18 , B32B27/281 , B32B27/283 , B32B27/285 , B32B27/286 , B32B27/30 , B32B27/32 , B32B27/34 , B32B27/365 , B32B27/40 , B32B37/04 , B32B37/10 , B32B2260/021 , B32B2260/046 , B32B2262/02 , B32B2262/0261 , B32B2262/0269 , B32B2262/0276 , B32B2262/10 , B32B2262/101 , B32B2262/103 , B32B2262/105 , B32B2262/106 , B32B2262/14 , B32B2264/02 , B32B2270/00 , B32B2305/026 , B32B2305/076 , B32B2305/08 , B32B2305/22 , B32B2305/38 , B32B2307/3065 , B32B2307/718 , B32B2307/72 , B32B2307/748 , B32B2315/085 , B32B2371/00 , B32B2379/08 , B32B2605/00 , B32B2607/00 , Y10T428/24998 , Y10T428/249986
摘要： A fiber-reinforced thermoplastic composite material comprising a fiber-reinforced thermoplastic core material is provided. In some embodiments, the thermoplastic core material has a maximum smoke density Ds (4 minutes) of less than 200 as measured in accordance with ASTM E662, a maximum heat release (5 minutes) of less than 65 kW/m2 as measured in accordance with FAA Heat release test FAR 25.853 (a) Appendix F, Part IV (OSU 65/65), and an average total heat release (2 minutes) of less than 65 kW/m2 as measured in accordance with FAA Heat release test FAR 25.853 (a) Appendix F, Part IV (OSU 65/65).
摘要翻译：提供了包含纤维增强热塑性芯材的纤维增强热塑性复合材料。在一些实施方案中，热塑性芯材料具有根据ASTM E662测量的小于200的最大烟雾浓度Ds（4分钟），根据ASTM E662测量的最大热释放（5分钟）小于65kW / m 2 FAA热释放试验FAR 25.853（a）附录F，第IV部分（OSU 65/65）和平均总放热量（2分钟）小于65 kW / m2，根据FAA热释放试验FAR 25.853（ a）附录F第四部分（OSU 65/65）。

8. 发明授权

US07682697B2 Fiber reinforced thermoplastic sheets with surface coverings 有权
标题翻译：具有表面覆盖层的纤维增强热塑性片材
公开(公告)号：US07682697B2
公开(公告)日：2010-03-23
申请号：US11441709
申请日：2006-05-26
申请人： Venkat Krishna Raghavendran , Thomas Arnold Ebeling
发明人： Venkat Krishna Raghavendran , Thomas Arnold Ebeling
IPC分类号： B32B27/26 , B32B9/04
CPC分类号： B32B33/00 , B32B5/02 , B32B5/28 , B32B2305/026 , B32B2305/08 , B32B2305/22 , B32B2307/3065 , Y10T428/249924 , Y10T428/249953 , Y10T428/31504 , Y10T428/31507 , Y10T428/31551 , Y10T428/31562
摘要： A composite sheet material in one embodiment includes a porous core layer. The porous core layer includes a thermoplastic polymer, about 20 weight percent to about 80 weight percent of reinforcing fibers based on a total weight of the porous core layer, and an effective amount of a flame retardant agent.
摘要翻译：在一个实施例中的复合片材包括多孔芯层。多孔芯层包括热塑性聚合物，基于多孔芯层的总重量为约20重量％至约80重量％的增强纤维和有效量的阻燃剂。

9. 发明申请

US20100021718A1 Thermoplastic composite material with improved smoke generation, heat release, and mechanical properties 审中-公开
标题翻译：具有改善烟雾产生，放热和机械性能的热塑性复合材料
公开(公告)号：US20100021718A1
公开(公告)日：2010-01-28
申请号：US12220410
申请日：2008-07-23
申请人： Sandra Fritz Vos , Thomas Arnold Ebeling
发明人： Sandra Fritz Vos , Thomas Arnold Ebeling
IPC分类号： B32B17/10 , B32B7/00
CPC分类号： B29C70/504 , B29B7/90 , B29C65/48 , B29C66/712 , B29K2079/085 , B29K2105/04 , B29K2105/06 , B29K2309/08 , B29L2009/00 , B32B5/022 , B32B5/024 , B32B5/028 , B32B5/08 , B32B5/26 , B32B17/04 , B32B27/08 , B32B27/12 , B32B27/18 , B32B27/281 , B32B27/283 , B32B27/285 , B32B27/286 , B32B27/30 , B32B27/32 , B32B27/34 , B32B27/365 , B32B27/40 , B32B37/04 , B32B37/10 , B32B2260/021 , B32B2260/046 , B32B2262/02 , B32B2262/0261 , B32B2262/0269 , B32B2262/0276 , B32B2262/10 , B32B2262/101 , B32B2262/103 , B32B2262/105 , B32B2262/106 , B32B2262/14 , B32B2264/02 , B32B2270/00 , B32B2305/026 , B32B2305/076 , B32B2305/08 , B32B2305/22 , B32B2305/38 , B32B2307/3065 , B32B2307/718 , B32B2307/72 , B32B2307/748 , B32B2315/085 , B32B2371/00 , B32B2379/08 , B32B2605/00 , B32B2607/00 , Y10T428/24998 , Y10T428/249986
摘要： A fiber-reinforced thermoplastic composite material having an advantageous combination of smoke generation, heat release, and mechanical property characteristics. The composite generally comprises a fiber-reinforced thermoplastic core containing discontinuous reinforcing fibers bonded together with one or more thermoplastic resins. The core material may further comprise at least one first skin material applied to a first surface of the core and/or one or more second skin material applied to a second surface of the core material. The thermoplastic core material has a maximum smoke density Ds (4 minutes) of less than 200 as measured in accordance with ASTM E662, a maximum heat release (5 minutes) of less than 65 kW/m2 as measured in accordance with FAA Heat release test FAR 25.853 (a) Appendix F, Part IV (OSU 65/65), and an average total heat release (2 minutes) of less than 65 kW/m2 as measured in accordance with FAA Heat release test FAR 25.853 (a) Appendix F, Part IV (OSU 65/65). The invention is useful in the manufacture of articles for aircraft, automotive, railcar, locomotive, bus, marine, aerospace and construction in which the certain advantages may be provided over other materials utilized for such applications.
摘要翻译：一种纤维增强的热塑复合材料，其具有烟雾产生，放热和机械性能特征的有利组合。复合材料通常包括纤维增强的热塑性芯，其包含与一种或多种热塑性树脂粘合在一起的不连续增强纤维。芯材料还可以包括施加到芯的第一表面和/或施加到芯材的第二表面的一个或多个第二表皮材料的至少一个第一表皮材料。根据ASTM E662测量，热塑性芯材料具有小于200的最大烟密度Ds（4分钟），根据FAA热释放试验测量的最大热释放（5分钟）小于65kW / m 2 FAR 25.853（a）附录F第IV部分（OSU 65/65）和根据FAA热释放试验FAR 25.853（a）附录F测量的小于65 kW / m2的平均总放热量（2分钟），第四部分（OSU 65/65）。本发明在制造用于飞机，汽车，轨道车辆，机车，公共汽车，船舶，航空航天和建筑物的制品中是有用的，其中可以提供与用于这种应用的其它材料相比的某些优点。

10. 发明授权

US06613824B2 Flame retardant resinous compositions and method 有权
公开(公告)号：US06613824B2
公开(公告)日：2003-09-02
申请号：US10015053
申请日：2001-11-12
申请人： John Robert Campbell , Thomas Miebach , Monica Marugan , Thomas Arnold Ebeling
发明人： John Robert Campbell , Thomas Miebach , Monica Marugan , Thomas Arnold Ebeling
IPC分类号： C08L6900
CPC分类号： C08L55/02 , C08F265/04 , C08F265/06 , C08F279/02 , C08F279/04 , C08K5/0066 , C08K5/41 , C08K5/49 , C08L25/00 , C08L25/12 , C08L27/12 , C08L33/00 , C08L35/06 , C08L51/00 , C08L51/003 , C08L51/04 , C08L69/00 , C08L2666/02 , C08L2666/14 , C08L2666/24 , C08L2666/04
摘要： Disclosed are flame retardant resinous compositions comprising (i) at least one aromatic polycarbonate; (ii) at least one of a second polymer having structural units derived from one or more monomers selected from the group consisting of vinyl aromatic monomers, monoethylenically unsaturated nitrile monomers, and C1-C12 alkyl (meth)acrylate monomers; (iii) at least one rubber modified graft copolymer; (iv) at least one polymeric or non-polymeric organic phosphorus species; (v) at least one antidrip agent; and (vi) at least one perfluoroalkanesulfonate salt present in an amount in a range between about 0.01 wt % and about 0.25 wt %, based on the weight of the entire composition. Also disclosed are methods for making said compositions.

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