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1. 发明授权

US08829084B2 Reinforced polyester resin composition 有权
标题翻译：增强聚酯树脂组合物
公开(公告)号：US08829084B2
公开(公告)日：2014-09-09
申请号：US13255787
申请日：2010-03-10
申请人： Tsuyoshi Urushihara , Yota Tsuneizumi
发明人： Tsuyoshi Urushihara , Yota Tsuneizumi
IPC分类号： C08K5/3415
CPC分类号： C08K5/47 , C08J5/043 , C08J2367/02 , C08K3/013 , C08K5/435 , C08L67/02 , C08L67/025 , C08L2666/18
摘要： The present invention provides a reinforced polyester resin composition, which comprises, with respect to 100 parts by mass of a polyester resin, 0.01 to 400 parts by mass of an inorganic filler as component (A) and 0.001 to 10 parts by mass of a metal salt of a sulfonamide compound as component (B), the metal salt of the sulfonamide compound having a structure represented by Formula (1): wherein R1 and R2 independently represent a hydrogen atom or the like; R1 and R2 are also optionally linked together to form a cyclic group; n represents number of 1 or 2; when n is 1, M represents an alkali metal atom or the like; when n is 2, the plural R1s and R2s are each optionally different; M represents a divalent metal atom or linking group; and when M is the linking group, either of R1 and R2 is an alkali metal.
摘要翻译：本发明提供一种增强聚酯树脂组合物，其包含相对于100质量份聚酯树脂，0.01〜400质量份作为组分（A）的无机填料和0.001至10质量份的金属作为组分（B）的磺酰胺化合物的盐，具有由式（1）表示的结构的磺酰胺化合物的金属盐：其中R1和R2独立地表示氢原子等; R1和R2也可任选地连接在一起形成环状基团; n表示1或2的数字; 当n为1时，M表示碱金属原子等; 当n为2时，多个R 1和R 2各自各自不同; M表示二价金属原子或连接基团; 当M是连接基团时，R1和R2中的任一个是碱金属。

2. 发明申请

US20120189793A1 POLYESTER RESIN COMPOSITION, POLYESTER FIBER, POLYESTER RESIN MOLDED ARTICLE, AND PROCESS FOR PRODUCTION OF NUCLEATING AGENT FOR POLYESTER RESIN 审中-公开
标题翻译：聚酯树脂组合物，聚酯纤维，聚酯树脂模制品以及用于生产聚酯树脂的核化剂的方法
公开(公告)号：US20120189793A1
公开(公告)日：2012-07-26
申请号：US13496959
申请日：2010-09-24
申请人： Yota Tsuneizumi , Tsuyoshi Urushihara , Naoshi Kawamoto
发明人： Yota Tsuneizumi , Tsuyoshi Urushihara , Naoshi Kawamoto
IPC分类号： C08K5/47 , B32B1/02 , B29C49/08 , B29C71/02 , B02C19/00
CPC分类号： C08K5/47 , C08K5/005 , C08K5/0083 , C08K5/435 , C08K5/49 , C08K5/529 , Y10T428/1352 , C08L67/02 , C08L67/00
摘要： Provided is a polyester resin composition comprising a sulfonamide compound as a nucleating agent, in which polyester resin composition coloring is inhibited.The polyester resin composition according to the present invention is a polyester resin composition comprising, with respect to 100 parts by mass of a polyester resin, 0.01 to 30 parts by mass of a phosphorus-based antioxidant (A) and 0.1 to 30 parts by mass of a sulfonamide compound metal salt (B), wherein the sulfonamide compound metal salt (B) has a water content of 0.1% to 20% based on the mass ratio with respect to the sulfonamide compound metal salt and not higher than 3% based on the mass ratio with respect to the polyester resin composition.
摘要翻译：提供一种聚酯树脂组合物，其包含作为成核剂的磺酰胺化合物，其中抑制聚酯树脂组合物着色。本发明的聚酯树脂组合物是聚酯树脂组合物，相对于100质量份聚酯树脂，含有0.01〜30质量份的磷系抗氧化剂（A）和0.1〜30质量份的磺酰胺化合物金属盐（B），其中磺胺化合物金属盐（B）的水含量相对于磺酰胺化合物金属盐的质量比为0.1〜20％，基于相对于磺酰胺化合物金属盐的质量比为3％以下相对于聚酯树脂组合物的质量比。

3. 发明授权

US09447200B2 Method for producing stabilized polymer 有权
标题翻译：稳定化聚合物的制备方法
公开(公告)号：US09447200B2
公开(公告)日：2016-09-20
申请号：US13817400
申请日：2011-08-18
申请人： Naoshi Kawamoto , Tsuyoshi Urushihara , Kohei Okamoto , Tetsuya Seguchi
发明人： Naoshi Kawamoto , Tsuyoshi Urushihara , Kohei Okamoto , Tetsuya Seguchi
IPC分类号： C08F4/44 , C08F2/00 , C08F4/00 , C08G18/48 , C08K5/49 , C08K5/05 , C08F2/44 , C08K5/00 , C08K5/527 , C08F2/40 , C08K5/5357 , C08K5/5317
CPC分类号： C08F2/00 , C08F2/40 , C08F2/44 , C08K5/0091 , C08K5/527 , C08K5/5317 , C08K5/5357 , C08F110/06 , C08F2500/12 , C08F10/00
摘要： Provided is a method of producing a stabilized polymer in which inhibition of polymerization of a monomer having an ethylenically unsaturated bond is suppressed even when a specific phenolic antioxidant is added before or during the polymerization of the monomer.The method of producing a stabilized polymer is characterized by comprising the step of adding at least one phenolic antioxidant which is represented by the following Formula (I), (II) or (III) and masked with an organic aluminum to a catalyst system or a polymerization system before or during polymerization of a monomer having an ethylenically unsaturated bond:

4. 发明授权

US08980163B2 Process for producing plastic bottle 有权
标题翻译：生产塑料瓶的工艺
公开(公告)号：US08980163B2
公开(公告)日：2015-03-17
申请号：US13259171
申请日：2010-03-26
申请人： Takahiro Horikoshi , Tsuyoshi Urushihara , Yota Tsuneizumi
发明人： Takahiro Horikoshi , Tsuyoshi Urushihara , Yota Tsuneizumi
IPC分类号： B29C49/06 , B29C45/00 , C08J3/22 , C08K5/47
CPC分类号： B29C45/00 , C08J3/226 , C08J2367/02 , C08J2467/00 , C08K5/47 , C08L67/02
摘要： Provided in a method of producing a plastic bottle in which molding cycle is improved and a highly transparent plastic bottle rarely having a problem of discoloration such as whitening is produced. The method according to the present invention is a method of producing a plastic bottle comprising 0.005 to 0.025 parts by mass of a 1,2-benzisothiazol-3(2H)-one 1,1-dioxide compound with respect to 100 parts by mass of a polyester resin, the method comprising preparing a masterbatch containing 0.01 to 0.5 parts by mass of the above-described 1,2-benzisothiazol-3(2H)-one 1,1-dioxide compound with respect to 100 parts by mass of the polyester resin, subsequently mixing the masterbatch and polyester resin to produce a mixture, and molding the mixture into the shape of a bottle. Further, it is preferred that the above-described polyester resin be a polyethylene terephthalate resin.
摘要翻译：本发明提供一种塑料瓶的制造方法，其中成型循环得到改善，并且产生了很少具有白化等变色问题的高透明塑料瓶。根据本发明的方法是一种制造塑料瓶的方法，其包含相对于100质量份的1,2-苯并异噻唑-3（2H） - 酮1,1-二氧化物化合物，含有0.005〜0.025质量份的1,2-苯并异噻唑-3（2H）聚酯树脂，该方法包括相对于100质量份聚酯制备含有0.01至0.5质量份上述1,2-苯并异噻唑-3（2H） - 酮1,1-二氧化物化合物的母料树脂，随后将母料和聚酯树脂混合以产生混合物，并将混合物模塑成瓶的形状。此外，优选上述聚酯树脂是聚对苯二甲酸乙二醇酯树脂。

5. 发明申请

US20130331515A1 PROCESS OF PRODUCING LAMINATE FILM AND RESIN COMPOSITION FOR COATING MEMBERS 审中-公开
标题翻译：生产层压膜的方法和涂料成员的树脂组合物
公开(公告)号：US20130331515A1
公开(公告)日：2013-12-12
申请号：US14002525
申请日：2012-02-08
申请人： Naoshi Kawamoto , Tsuyoshi Urushihara , Kohei Okamoto , Tetsuya Seguchi
发明人： Naoshi Kawamoto , Tsuyoshi Urushihara , Kohei Okamoto , Tetsuya Seguchi
IPC分类号： C08K5/20
CPC分类号： C08K5/20 , B32B7/12 , B32B27/08 , B32B27/32 , B32B27/36 , C08F2/44
摘要： Provided is a method of producing a laminate film by which a laminate film having excellent adhesion with a laminate base material, in which laminate film the amount of elution of an additive into a solvent is small, can be produced.The method of producing a laminate film is characterized by comprising the step of adding, before or during polymerization of a monomer having an ethylenically unsaturated bond, a phenolic antioxidant represented by the following Formula (1), which is masked with an organoaluminum compound, to at least one of a catalyst system, a polymerization system and a piping, such that the phenolic antioxidant is incorporated in an amount of 0.001 to 0.5 parts by mass with respect to 100 parts by mass of a polymer obtained by the polymerization: (wherein, R1 and R2 each independently represent a hydrogen atom, an alkyl group having 1 to 5 carbon atoms which is optionally branched, or the like; and R represents an alkyl group having 1 to 30 carbon atoms which is optionally branched, an alkenyl group having 2 to 30 carbon atoms which is optionally branched, or the like).
摘要翻译：提供一种层压膜的制造方法，通过该层叠膜，可以制造与叠层基材具有优异粘附性的层压膜，其中层压膜的添加剂溶解到溶剂中的量少。制造层压膜的方法的特征在于包括在具有烯键式不饱和键的单体聚合之前或期间，将由有机铝化合物掩蔽的由下式（1）表示的酚类抗氧化剂加入到催化剂体系，聚合体系和管道中的至少一种，相对于100质量份通过聚合得到的聚合物，酚类抗氧化剂的配合量为0.001〜0.5质量份（式中， R 1和R 2各自独立地表示氢原子，可以具有支链的碳原子数1〜5的烷基等，R表示任意支链的碳原子数为1〜30的烷基，具有2个至30个碳原子，其任选是支链的等）。

6. 发明申请

US20120149838A1 METHOD FOR RECYCLING OF PHENOLIC ANTIOXIDANT AGENT, PROCESS FOR PRODUCTION OF OLEFIN POLYMER, POLYOLEFIN POWDER, AND FIBERS 有权
标题翻译：苯酚抗氧化剂回收方法，烯烃聚合物，聚烯烃粉末和纤维的生产方法
公开(公告)号：US20120149838A1
公开(公告)日：2012-06-14
申请号：US13391078
申请日：2010-09-01
申请人： Naoshi Kawamoto , Takashi Ayabe , Tsuyoshi Urushihara , Kohei Okamoto , Tetsuya Seguchi
发明人： Naoshi Kawamoto , Takashi Ayabe , Tsuyoshi Urushihara , Kohei Okamoto , Tetsuya Seguchi
IPC分类号： C08K5/20 , C08F2/44 , C08K5/52 , C07C233/11 , C08L23/12
CPC分类号： C08K5/20 , C08F6/28 , C08F10/00 , C08F2410/01 , D01F6/06 , C08L23/10 , C08L23/00 , C08F2/44 , C08F4/6495
摘要： Provided are a recycling method for industrially, simply and effectively recycling a phenolic body from a phenolic antioxidant which is masked by an organoaluminum compound and contained in an olefin polymer obtained by supplying the masked phenolic antioxidant upon polymerization; and an olefin polymer obtained by this method.In a method for recycling a phenolic antioxidant wherein a phenolic antioxidant which is masked by an organoaluminum compound and contained in an olefin polymer obtained by supplying the masked phenolic antioxidant upon polymerization is recycled to a phenolic body, a nitrogen gas comprising water and/or a proton donor at a volume ratio of 1.0×10−6 to 2.5×10−2 with respect to 1 volume of nitrogen is brought into contact with the olefin polymer.
摘要翻译：提供了一种工业上简单有效地将苯酚体系从酚类抗氧化剂中回收的再循环方法，该酚类抗氧化剂被有机铝化合物掩蔽并包含在通过在聚合时提供被掩蔽的酚类抗氧化剂而获得的烯烃聚合物中; 和通过该方法得到的烯烃聚合物。在一种酚类抗氧化剂的再循环方法中，其中由有机铝化合物掩蔽并且包含在通过在聚合时供应掩蔽的酚类抗氧化剂而获得的烯烃聚合物中的酚类抗氧化剂被循环到酚醛体中，包含水和/或使质子供体相对于1体积氮体积比为1.0×10-6〜2.5×10-2与烯烃聚合物接触。

7. 发明申请

US20100240815A1 POLYOLEFIN RESIN COMPOSITION 有权
标题翻译：聚烯烃树脂组合物
公开(公告)号：US20100240815A1
公开(公告)日：2010-09-23
申请号：US12680398
申请日：2008-08-29
申请人： Tsuyoshi Urushihara , Naoto Ueda , Naoshi Kawamoto
发明人： Tsuyoshi Urushihara , Naoto Ueda , Naoshi Kawamoto
IPC分类号： C08K5/20
CPC分类号： C08K5/0083 , C08K5/20 , C08L23/02
摘要： A polyolefin resin composition having a high crystallization temperature and excellent transparency is provided.Disclosed is a polyolefin resin composition comprising 0.01 to 10 parts by mass of a methylenebisanilide compound with respect to 100 parts by mass of a polyolefin resin, which methylenebisanilide compound is represented by the following General Formula (1): (wherein each of X1, X2, X3, X4, X5, X6, X7 and X8 independently represents a hydrogen atom or C1-C10 alkyl which is optionally substituted or branched; and each of R1 and R2 independently represents a hydrogen atom, C1-C21 alkyl which is optionally substituted or branched, C3-C12 cycloalkyl which is optionally substituted, or C6-C20 aryl which is optionally substituted).
摘要翻译：提供了具有高结晶温度和优异透明度的聚烯烃树脂组合物。公开了一种聚烯烃树脂组合物，其相对于100质量份的聚烯烃树脂含有0.01〜10质量份的亚甲基双酰苯胺化合物，该亚甲基双苯赖德化合物由以下通式（1）表示：（其中X1，X2 X3，X4，X5，X6，X7和X8独立地表示氢原子或任选取代或支链的C 1 -C 10烷基; R 1和R 2各自独立地表示氢原子，任选取代的C 1 -C 21烷基或支链的，任选取代的C 3 -C 12环烷基或任选被取代的C 6 -C 20芳基）。

8. 发明授权

US08288462B2 Polyolefin resin composition 有权
标题翻译：聚烯烃树脂组合物
公开(公告)号：US08288462B2
公开(公告)日：2012-10-16
申请号：US13061012
申请日：2009-08-21
申请人： Tsuyoshi Urushihara , Kazukiyo Nomura , Naoto Ueda , Yota Tsuneizumi
发明人： Tsuyoshi Urushihara , Kazukiyo Nomura , Naoto Ueda , Yota Tsuneizumi
IPC分类号： C08K5/22 , C08K5/52
CPC分类号： C08K5/0083 , C08K5/16 , C08L23/02 , C08L23/10
摘要： The present invention provides a polyolefin-based resin composition containing a crystal nucleating agent having a specific structure, which polyolefin-based resin composition has a superior transparency and whose crystallization is facilitated. The polyolefin-based resin composition is characterized by comprising, with respect to 100 parts by mass of a polyolefin-based resin, 0.01 to 1 parts by mass of at least one crystal nucleating agent selected from the group consisting of crystal nucleating agents each having a structure represented by one of the following Formulas (1) to (6):
摘要翻译：本发明提供一种含有具有特定结构的结晶成核剂的聚烯烃系树脂组合物，该聚烯烃类树脂组合物具有优异的透明性并且其结晶化。聚烯烃类树脂组合物的特征在于，相对于100质量份的聚烯烃系树脂，含有0.01〜1质量份的选自以下的结晶成核剂：晶体成核剂，其各自具有由下列公式（1）至（6）之一表示的结构：

9. 发明申请

US20120013049A1 PROCESS FOR PRODUCING PLASTIC BOTTLE 有权
标题翻译：生产塑料瓶的工艺
公开(公告)号：US20120013049A1
公开(公告)日：2012-01-19
申请号：US13259171
申请日：2010-03-26
申请人： Takahiro Horikoshi , Tsuyoshi Urushihara , Yota Tsuneizumi
发明人： Takahiro Horikoshi , Tsuyoshi Urushihara , Yota Tsuneizumi
IPC分类号： B29C49/06
CPC分类号： B29C45/00 , C08J3/226 , C08J2367/02 , C08J2467/00 , C08K5/47 , C08L67/02
摘要： Provided in a method of producing a plastic bottle in which molding cycle is improved and a highly transparent plastic bottle rarely having a problem of discoloration such as whitening is produced. The method according to the present invention is a method of producing a plastic bottle comprising 0.005 to 0.025 parts by mass of a 1,2-benzisothiazol-3(2H)-one 1,1-dioxide compound with respect to 100 parts by mass of a polyester resin, the method comprising preparing a masterbatch containing 0.01 to 0.5 parts by mass of the above-described 1,2-benzisothiazol-3(2H)-one 1,1-dioxide compound with respect to 100 parts by mass of the polyester resin, subsequently mixing the masterbatch and polyester resin to produce a mixture, and molding the mixture into the shape of a bottle. Further, it is preferred that the above-described polyester resin be a polyethylene terephthalate resin.
摘要翻译：本发明提供一种塑料瓶的制造方法，其中成型循环得到改善，并且产生了很少具有白化等变色问题的高透明塑料瓶。根据本发明的方法是一种制造塑料瓶的方法，其包含相对于100质量份的1,2-苯并异噻唑-3（2H） - 酮1,1-二氧化物化合物，含有0.005〜0.025质量份的1,2-苯并异噻唑-3（2H）聚酯树脂，该方法包括相对于100质量份聚酯制备含有0.01至0.5质量份上述1,2-苯并异噻唑-3（2H） - 酮1,1-二氧化物化合物的母料树脂，随后将母料和聚酯树脂混合以产生混合物，并将混合物模塑成瓶的形状。此外，优选上述聚酯树脂是聚对苯二甲酸乙二醇酯树脂。

10. 发明申请

US20120004363A1 REINFORCED POLYESTER RESIN COMPOSITION 有权
标题翻译：增强聚酯树脂组合物
公开(公告)号：US20120004363A1
公开(公告)日：2012-01-05
申请号：US13255787
申请日：2010-03-10
申请人： Tsuyoshi Urushihara , Yota Tsuneizumi
发明人： Tsuyoshi Urushihara , Yota Tsuneizumi
IPC分类号： C08L67/02 , C08K7/14
CPC分类号： C08K5/47 , C08J5/043 , C08J2367/02 , C08K3/013 , C08K5/435 , C08L67/02 , C08L67/025 , C08L2666/18
摘要： The present invention provides a reinforced polyester resin composition having a high crystallization rate and superior moldability, from which a molded article having low shrinkage anisotropy and superior surface properties can be obtained.The reinforced polyester resin composition according to the present invention comprises, with respect to 100 parts by mass of a polyester resin, 0.01 to 400 parts by mass of an inorganic filler as component (A) and 0.001 to 10 parts by mass of a metal salt of a sulfonamide compound as component (B), the metal salt of the sulfonamide compound having a structure represented by the following Formula (1): (wherein, R1 and R2 independently represent a hydrogen atom or the like; R1 and R2 are also optionally linked together to form a cyclic group; n represents number of 1 or 2; when n is 1, M represents an alkali metal atom or the like; when n is 2, the plural R1s and R2s are each optionally different; M represents a divalent metal atom or linking group; and when M is the linking group, either of R1 and R2 is an alkali metal).
摘要翻译：本发明提供了一种具有高结晶速率和优异成型性的增强聚酯树脂组合物，可以获得具有低收缩各向异性和优异表面性能的成型制品。本发明的增强聚酯树脂组合物相对于100质量份的聚酯树脂，包含0.01〜400质量份作为（A）成分的无机填料和0.001〜10质量份的金属盐的作为组分（B）的磺酰胺化合物，具有由下式（1）表示的结构的磺酰胺化合物的金属盐：（其中，R 1和R 2独立地表示氢原子等; R 1和R 2也可任选地连接在一起形成环状基团; n表示1或2的数;当n为1时，M表示碱金属原子等;当n为2时，多个R 1和R 2各自不同; M表示二价金属原子或连接基团;当M为连接基团时，R 1和R 2均为碱金属）。

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