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1. 发明授权

US08084525B2 Use of organophosphorus compounds as creping aids 有权
标题翻译：有机磷化合物用作起绉助剂
公开(公告)号：US08084525B2
公开(公告)日：2011-12-27
申请号：US11369133
申请日：2006-03-06
申请人： Vladimir A. Grigoriev , Gary S. Furman , Sammy L. Archer
发明人： Vladimir A. Grigoriev , Gary S. Furman , Sammy L. Archer
IPC分类号： C08K5/00
CPC分类号： B31F1/12 , C08K5/521 , C09J11/06
摘要： A modified creping adhesive composition comprising at least one adhesive component and at least one modifier component, said modifier component comprising an organophosphorus compound is disclosed and claimed. A method of creping a paper web comprising: applying to a rotating creping cylinder an effective amount of a modified creping adhesive composition comprising at least one adhesive component and at least one modifier component, said modifier component comprising an organophosphorus compound; pressing a paper web against the creping cylinder to effect adhesion of the paper web to the creping cylinder; and dislodging the paper web from the creping cylinder with a doctor blade is also disclosed and claimed.
摘要翻译：一种改进的起皱粘合剂组合物，其包含至少一种粘合剂组分和至少一种改性剂组分，所述改性剂组分包含有机磷化合物。一种起皱纸幅的方法，包括：向旋转的起皱圆筒施加有效量的改性起皱粘合剂组合物，其包含至少一种粘合剂组分和至少一种改性剂组分，所述改性剂组分包含有机磷化合物; 将纸幅压靠在起皱圆筒上以使纸幅粘附到起皱圆筒上; 并且还公开并要求保护，并且用刮刀从起皱圆筒移除纸幅。

2. 发明授权

US08066847B2 Creping adhesives comprising blends of polyaminoamide epihalolhydrin resins and polyamides 有权
标题翻译：起皱粘合剂包括聚氨基酰胺表卤醇树脂和聚酰胺的共混物
公开(公告)号：US08066847B2
公开(公告)日：2011-11-29
申请号：US11321995
申请日：2005-12-29
申请人： Vladimir A. Grigoriev , Gary S. Furman , Sammy Lee Archer , Winston Su , Christopher D. Kaley , Mingli Wei
发明人： Vladimir A. Grigoriev , Gary S. Furman , Sammy Lee Archer , Winston Su , Christopher D. Kaley , Mingli Wei
IPC分类号： C08G69/48 , C08L77/06
CPC分类号： C08G73/0286 , C08L77/00 , C08L79/02 , C08L79/08 , D21H17/55 , C08L2666/20
摘要： A composition comprising one or more polyaminoaminde epihalohydrin resins and one or more polyamides in a ratio of about 1:99 to about 99:1 based on polymer actives and use of the composition for creping paper webs.
摘要翻译：一种组合物，其包含一种或多种聚氨基甲醛表卤代醇树脂和一种或多种基于聚合物活性剂的比例为约1:99至约99:1的聚酰胺和用于起皱纸幅的组合物的用途。

3. 发明申请

US20090133846A1 CREPING ADHESIVES COMPRISING BLENDS OF HIGH AND LOW MOLECULAR WEIGHT RESINS 有权
标题翻译：包含高分子量低分子量树脂的混合物的粘合剂
公开(公告)号：US20090133846A1
公开(公告)日：2009-05-28
申请号：US11946397
申请日：2007-11-28
申请人： Vladimir A. Grigoriev , Gary S. Furman
发明人： Vladimir A. Grigoriev , Gary S. Furman
IPC分类号： B31F1/14 , C08L33/24
CPC分类号： D21H21/146 , C08L33/26 , C08L79/02 , C08L2205/02 , C08L2666/04 , C09J129/04 , C09J179/02 , D21H17/36 , D21H17/56 , C08L2666/20
摘要： A composition comprising one or more high molecular weight resins and one or more low molecular weight resins in a ratio of about 1:99 to about 99:1 based on polymer actives, wherein said high molecular weight resins are selected from the group consisting of glyoxylated polyacrylamide, crosslinked polyaminoamide and polyaminoamide-epihalohydrin resins having a molecular weight of about 100,000 to about 5,000,000 Dalton and the low molecular weight resins are selected from the group consisting of glyoxylated polyacrylamide, crosslinked polyaminoamide and polyaminoamide-epihalohydrin resins having a molecular weight of less than about 100,000 Dalton and wherein the mole ratio of epihalohydrin to secondary nitrogen atoms in the high and low molecular weight polyaminoamide-epihalohydrin resins is less than about 0.5. and use of the composition for creping paper webs.
摘要翻译：一种包含一种或多种高分子量树脂和一种或多种基于聚合物活性物质的约1:99至约99:1的低分子量树脂的组合物，其中所述高分子量树脂选自乙氧基化聚丙烯酰胺，交联聚氨基酰胺和分子量为约100,000至约5,000,000道尔顿的聚氨基酰胺 - 表卤代醇树脂和低分子量树脂选自乙氧基化聚丙烯酰胺，交联聚氨基酰胺和分子量小于10的聚氨基酰胺 - 表卤代醇树脂约100,000道尔顿，其中高分子量和低分子量聚氨基酰胺 - 表卤代醇树脂中表卤代醇与次级氮原子的摩尔比小于约0.5。以及使用该组合物起皱纸幅。

4. 发明授权

US07291695B2 Stable wet strength resin 有权
标题翻译：稳定的湿强度树脂
公开(公告)号：US07291695B2
公开(公告)日：2007-11-06
申请号：US10818269
申请日：2004-04-05
申请人： Mingli Wei , Vladimir A. Grigoriev , Gary S. Furman, Jr.
发明人： Mingli Wei , Vladimir A. Grigoriev , Gary S. Furman, Jr.
IPC分类号： C08F6/00
CPC分类号： C08G73/0293 , D21H17/55 , D21H21/20
摘要： A method of stabilizing an aqueous solution of polyaminoamide-epichlorohydrin resin comprising adjusting the pH of the solution to less than about 3 with strong acid and then adding to the solution a weak acid in a mole ratio of total protons available from the weak acid to total protons available from the strong acid of about 0.05 to about 2.
摘要翻译：稳定聚氨基酰胺 - 表氯醇树脂水溶液的方法，其包括用强酸将溶液的pH调节至小于约3，然后向溶液中加入弱酸，所述弱酸以从弱酸到总量的总质子的摩尔比强酸可获得约0.05至约2的质子。

5. 发明授权

US08444812B2 Creping adhesives with improved film properties 有权
标题翻译：起皱粘合剂具有改善的膜性能
公开(公告)号：US08444812B2
公开(公告)日：2013-05-21
申请号：US12273217
申请日：2008-11-18
申请人： Vladimir A. Grigoriev , Gary S. Furman, Jr. , Mingli Wei , Winston Su , Christopher D. Kaley , Bryan M. Schertzer
发明人： Vladimir A. Grigoriev , Gary S. Furman, Jr. , Mingli Wei , Winston Su , Christopher D. Kaley , Bryan M. Schertzer
IPC分类号： B31F1/12
CPC分类号： D21H21/146 , C08G73/028 , C08G73/0286 , C08L79/02 , C09J179/02
摘要： The invention provides a composition of matter used to produce very soft high grades of tissue paper. The composition of matter comprises a PAE resin acidified with a multifunctional acid. The multifunctional acid includes but is not limited to carboxyl and sulfonyl. The acid has a functional group selected from carboxyl and sulfonyl and a functional group selected from carboxyl, sulfonyl, hydroxyl, lactone, phenol, amine and heterocycle. The PAE resin facilitates the use of an adhesive in a Yankee Dryer apparatus that is durable when the adhesive is wet but remains soft when the adhesive becomes dry. These properties allow the adhesive to be strong and remain engaged to the dryer apparatus when wet but be easily removed by the creping blade when dry.
摘要翻译：本发明提供用于生产非常柔软的高等级的薄纸的物质组合物。物质组成包括用多官能酸酸化的PAE树脂。多官能酸包括但不限于羧基和磺酰基。酸具有选自羧基和磺酰基的官能团和选自羧基，磺酰基，羟基，内酯，苯酚，胺和杂环的官能团。 PAE树脂有助于在扬克烘干机设备中使用粘合剂，该粘合剂在粘合剂湿润时是耐用的，而当粘合剂变干时保持柔软。这些特性使得粘合剂坚固并且在湿润时保持与干燥设备接合，但是当干燥时易于被起皱刀片除去。

6. 发明授权

US07683121B2 Stable wet strength resin 有权
标题翻译：稳定的湿强度树脂
公开(公告)号：US07683121B2
公开(公告)日：2010-03-23
申请号：US11091176
申请日：2005-03-28
申请人： Mingli Wei , Vladimir A. Grigoriev , Gary S. Furman, Jr. , William J. Ward
发明人： Mingli Wei , Vladimir A. Grigoriev , Gary S. Furman, Jr. , William J. Ward
IPC分类号： C08L77/06 , C08G69/48 , C08F6/00
CPC分类号： C08G73/0293 , D21H17/14 , D21H17/55 , D21H21/18 , D21H21/20
摘要： A method of stabilizing an aqueous solution of polyaminoamide-epichlorohydrin resin comprising sequentially adding to the solution about 0.1 to about 10 weight percent of one or more strong acids and about 0.1 to about 10 weight percent of one or more weak acids to prepare a stabilized solution having a pH of about 3-4.
摘要翻译：一种稳定聚氨基酰胺 - 表氯醇树脂水溶液的方法，包括依次向该溶液中加入约0.1至约10重量％的一种或多种强酸和约0.1至约10重量％的一种或多种弱酸以制备稳定溶液 pH约3-4。

7. 发明授权

US08753478B2 Creping adhesives comprising blends of high and low molecular weight resins 有权
标题翻译：起皱粘合剂包括高分子量和低分子量树脂的共混物
公开(公告)号：US08753478B2
公开(公告)日：2014-06-17
申请号：US11946397
申请日：2007-11-28
申请人： Vladimir A. Grigoriev , Gary S. Furman
发明人： Vladimir A. Grigoriev , Gary S. Furman
IPC分类号： B31F1/12 , D21H21/14 , D21H17/36 , D21H17/56 , C09J129/04 , C09J179/02 , C08L79/02
CPC分类号： D21H21/146 , C08L33/26 , C08L79/02 , C08L2205/02 , C08L2666/04 , C09J129/04 , C09J179/02 , D21H17/36 , D21H17/56 , C08L2666/20
摘要： A composition comprising one or more high molecular weight resins and one or more low molecular weight resins in a ratio of about 1:99 to about 99:1 based on polymer actives, wherein said high molecular weight resins are selected from the group consisting of glyoxylated polyacrylamide, crosslinked polyaminoamide and polyaminoamide-epihalohydrin resins having a molecular weight of about 100,000 to about 5,000,000 Dalton and the low molecular weight resins are selected from the group consisting of glyoxylated polyacrylamide, crosslinked polyaminoamide and polyaminoamide-epihalohydrin resins having a molecular weight of less than about 100,000 Dalton and wherein the mole ratio of epihalohydrin to secondary nitrogen atoms in the high and low molecular weight polyaminoamide-epihalohydrin resins is less than about 0.5. and use of the composition for creping paper webs.
摘要翻译：一种包含一种或多种高分子量树脂和一种或多种基于聚合物活性物质的约1:99至约99:1的低分子量树脂的组合物，其中所述高分子量树脂选自乙氧基化聚丙烯酰胺，交联聚氨基酰胺和分子量为约100,000至约5,000,000道尔顿的聚氨基酰胺 - 表卤代醇树脂和低分子量树脂选自乙氧基化聚丙烯酰胺，交联聚氨基酰胺和分子量小于10的聚氨基酰胺 - 表卤代醇树脂约100,000道尔顿，其中高分子量和低分子量聚氨基酰胺 - 表卤代醇树脂中表卤代醇与次级氮原子的摩尔比小于约0.5。以及使用该组合物起皱纸幅。

8. 发明授权

US08071667B2 Compositions comprising (poly) alpha olefins 有权
标题翻译：包含（多）α-烯烃的组合物
公开(公告)号：US08071667B2
公开(公告)日：2011-12-06
申请号：US11143418
申请日：2005-06-02
申请人： Gary S. Furman, Jr. , Vladimir A. Grigoriev
发明人： Gary S. Furman, Jr. , Vladimir A. Grigoriev
IPC分类号： C08K5/544 , C08K5/17 , C08K5/19 , D21H25/02 , D21H23/00
CPC分类号： D21H21/146 , C08K5/04 , C08L23/18
摘要： A release aid comprising one or more (poly)C5-C20 alpha olefins and one or more surfactants for use in releasing a paper web from the fabric in through air drying processes and/or from the Yankee dryer, compositions comprising the release aid and methods of using the release aid.
摘要翻译：包含一种或多种（多）C5-C20α烯烃和一种或多种用于通过空气干燥方法从织物释放纸幅的表面活性剂和/或来自扬克烘缸的释放助剂，包含释放助剂和方法使用释放助剂。

9. 发明申请

US20100122785A1 CREPING ADHESIVES WITH IMPROVED FILM PROPERTIES 有权
标题翻译：用改进的胶片特性来制造粘合剂
公开(公告)号：US20100122785A1
公开(公告)日：2010-05-20
申请号：US12273217
申请日：2008-11-18
申请人： Vladimir A. Grigoriev , Gary S. Furman, JR. , Mingli Wei , Winston Su , Christopher D. Kaley , Bryan M. Schertzer
发明人： Vladimir A. Grigoriev , Gary S. Furman, JR. , Mingli Wei , Winston Su , Christopher D. Kaley , Bryan M. Schertzer
IPC分类号： B31F1/12 , C08L77/06
CPC分类号： D21H21/146 , C08G73/028 , C08G73/0286 , C08L79/02 , C09J179/02
摘要： The invention provides a composition of matter used to produce very soft high grades of tissue paper. The composition of matter comprises a PAE resin acidified with a multifunctional acid. The multifunctional acid includes but is not limited to carboxyl and sulfonyl. The acid has a functional group selected from carboxyl and sulfonyl and a functional group selected from carboxyl, sulfonyl, hydroxyl, lactone, phenol, amine and heterocycle. The PAE resin facilitates the use of an adhesive in a Yankee Dryer apparatus that is durable when the adhesive is wet but remains soft when the adhesive becomes dry. These properties allow the adhesive to be strong and remain engaged to the dryer apparatus when wet but be easily removed by the creping blade when dry.
摘要翻译：本发明提供用于生产非常柔软的高等级的薄纸的物质组合物。物质组成包括用多官能酸酸化的PAE树脂。多官能酸包括但不限于羧基和磺酰基。酸具有选自羧基和磺酰基的官能团和选自羧基，磺酰基，羟基，内酯，苯酚，胺和杂环的官能团。 PAE树脂有助于在扬克烘干机设备中使用粘合剂，该粘合剂在粘合剂湿润时是耐用的，而当粘合剂变干时保持柔软。这些特性使得粘合剂坚固并且在湿润时保持与干燥设备接合，但是当干燥时易于被起皱刀片除去。

10. 发明授权

US4424318A Continuous production of polymer beads of controlled size 失效
标题翻译：连续生产受控尺寸的聚合物珠粒
公开(公告)号：US4424318A
公开(公告)日：1984-01-03
申请号：US305647
申请日：1981-09-18
申请人： Claude R. L. Vairetti , Michel R. L. Desnoyers , Jack Carbonel , Paul D. A. Grammont , Arkadyi B. Pachkov , Vladimir A. Grigoriev , Vladimir I. Firsov
发明人： Claude R. L. Vairetti , Michel R. L. Desnoyers , Jack Carbonel , Paul D. A. Grammont , Arkadyi B. Pachkov , Vladimir A. Grigoriev , Vladimir I. Firsov
IPC分类号： B01J19/00 , C08F2/00 , C08F2/18 , C08F2/20
CPC分类号： B01J19/0006 , C08F2/18
摘要： A process and apparatus for the continuous production of spherical polymer beads in a restricted size range. Monomer droplets are produced in said size range by subjecting a fine monomer dispersion containing a controlled amount of a surface protective agent to controlled coalescence during passage through a tube (11) under laminar flow conditions. The monomer droplets are delivered from the tube (11) to the top of a polymerizing column (12) of variable cross-section wherein they undergo suspension polymerization in a laminar liquid stream descending through the column. Further polymerization in a separate reactor (30a, 30b) provides the desired polymer beads.
摘要翻译： PCT No.PCT / EP81 / 00069 Sec。 371日期1981年9月18日 102（e）1981年9月18日PCT申请1981年6月10日PCT公布。公开号WO81 / 03659 日期为1981年12月24日。用于连续生产限制尺寸范围的球形聚合物珠粒的方法和装置。通过在层流条件下通过管（11）通过含有受控量的表面保护剂的精细单体分散体来控制聚结，在所述尺寸范围内产生单体液滴。单体液滴从管（11）输送到可变横截面的聚合塔（12）的顶部，其中它们在通过塔下降的层流液流中进行悬浮聚合。在单独的反应器（30a，30b）中进一步聚合提供所需的聚合物珠粒。

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