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    • 2. 发明申请
    • PRESSURE-SENSITIVE ADHESIVE COMPOSITION WITH TRANSPARENCY CHARACTERISTICS
    • US20220169897A1
    • 2022-06-02
    • US17442410
    • 2020-03-20
    • 3M INNOVATIVE PROPERTIES COMPANY
    • Frank KuesterSilke D. MechernichKerstin UnverhauTom Opstal
    • C09J7/38C09J133/08C09J7/24
    • The present disclosure relates to a pressure sensitive adhesive composition comprising a blend of: a) a (meth)acrylate-based (co)polymer base component; and b) a (meth)acrylate-based copolymeric additive comprising the free-radical random copolymerization reaction product of a copolymerizable material comprising: i. C1-C32 acrylic acid ester monomer units; ii. greater than 10 wt. % of C1-C18 methacrylic acid ester monomer units, based on the total weight of the (meth)acrylate-based copolymeric additive; and iii. ethylenically unsaturated monomer units having a functional group, which are copolymerizable with monomer units (i) and/or (ii); wherein the (meth)acrylate-based copolymeric additive has a weight average molecular weight (Mw) greater than 10,000 Daltons and a Tg no greater than 50° C., as estimated by the Fox equation. According to another aspect, the present disclosure is directed to a multilayer pressure sensitive adhesive assembly comprising at least a first polymer layer and a second pressure sensitive adhesive layer adjacent to the first polymer layer, wherein the second pressure sensitive adhesive layer has a composition as described above. According to still another aspect of the present disclosure, it is provided a method for manufacturing a pressure sensitive adhesive composition as described above. In yet another aspect, the present disclosure relates to the use of a pressure sensitive adhesive composition or multilayer pressure sensitive adhesive assembly as described above for the bonding to a medium surface energy substrate or a high surface energy substrate.
    • 8. 发明申请
    • MULTILAYER PRESSURE-SENSITIVE ADHESIVE ASSEMBLY
    • US20220177739A1
    • 2022-06-09
    • US17270701
    • 2019-08-15
    • 3M INNOVATIVE PROPERTIES COMPANY
    • Kerstin UnverhauSilke D. MechernichFrank Kuester
    • C09J7/38C09J133/08
    • The present disclosure relates to a multilayer pressure sensitive adhesive assembly comprising at least a first pressure sensitive adhesive layer and a second pressure sensitive adhesive layer adjacent to the first pressure sensitive adhesive layer, wherein the first pressure sensitive adhesive layer and the second pressure sensitive adhesive layer comprise a polymer base material selected from the group of polyacrylates, wherein the second pressure sensitive adhesive layer has a thickness no greater than 250 micrometres and comprises silica nanoparticles having an average particle size no greater than 400 nm when measured by Dynamic Light Scattering (DLS) techniques according to the test method described in the experimental section, and wherein the first pressure sensitive adhesive layer has a thickness in a range from 250 to 5000 micrometres and is substantially free of particulate filler material. According to another aspect, the present disclosure is directed to an article comprising a medium surface energy substrate and a multilayer pressure sensitive adhesive assembly as described above adjacent to the medium surface energy substrate. In another aspect, the present disclosure relates to the use of a multilayer pressure sensitive adhesive assembly as described above for the bonding to a medium surface energy substrate or a high surface energy substrate.