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1. 发明申请

US20220144869A1 HETEROLEPTIC CARBENE COMPLEXES AND THE USE THEREOF IN ORGANIC ELECTRONICS 有权
公开(公告)号：US20220144869A1
公开(公告)日：2022-05-12
申请号：US17526503
申请日：2021-11-15
申请人： BASF SE , OLEDWORKS GMBH , OSRAM OLEO GMBH
发明人： Evelyn FUCHS , Oliver MOLT , Korinna DORMANN , Thomas GESSNER , Nicolle LANGER , Ingo MUENSTER , JianQiang QU , Christian LENNARTZ , Christian SCHILDKNECHT , Soichi WATANABE , Gerhard WAGENBLAST , Guenter SCHMID , Herbert Friedrich BOERNER , Volker van ELSBERGEN
IPC分类号： C07F15/00 , H01L51/00
摘要： Heteroleptic carbene complexes and the use thereof in organic electronics The present invention relates to heteroleptic complexes comprising a phenylimidazole or phenyltriazole unit bonded via a carbene bond to a central metal atom, and phenylimidazole ligands attached via a nitrogen-metal bond to the central atom, to OLEDs which comprise such heteroleptic complexes, to light-emitting layers comprising at least one such heteroleptic complex, to a device selected from the group consisting of illuminating elements, stationary visual display units and mobile visual display units comprising such an OLED, to the use of such a heteroleptic complex in OLEDs, for example as emitter, matrix material, charge transport material and/or charge blocker.

2. 发明申请

US20200373503A1 HETEROLEPTIC CARBENE COMPLEXES AND THE USE THEREOF IN ORGANIC ELECTRONICS 审中-公开
公开(公告)号：US20200373503A1
公开(公告)日：2020-11-26
申请号：US16294403
申请日：2019-03-06
申请人： BASF SE , OLEDWORKS GMBH , OSRAM OLED GMBH
发明人： Evelyn FUCHS , Oliver MOLT , Korinna DORMANN , Thomas GESSNER , Nicolle LANGER , lngo MUENSTER , JianQiang Qu , Christian LENNARTZ , Christian SCHILDKNECHT , Soichi WATANABE , Gerhard WAGENBLAST , Guenter SCHMID , Herbert Friedrich BOERNER , Volker van ELSBERGEN
IPC分类号： H01L51/00 , C07F15/00
摘要： The present invention relates to heteroleptic complexes comprising a phenylimidazole or phenyltriazole unit bonded via a carbene bond to a central metal atom, and phenylimidazole ligands attached via a nitrogen-metal bond to the central atom, to OLEDs which comprise such heteroleptic complexes, to light-emitting layers comprising at least one such heteroleptic complex, to a device selected from the group consisting of illuminating elements, stationary visual display units and mobile visual display units comprising such an OLED, to the use of such a heteroleptic complex in OLEDs, for example as emitter, matrix material, charge transport material and/or charge blocker.

3. 发明申请

US20130178621A1 PROCESS FOR PREPARING TRANSITION METAL-CARBENE COMPLEXES 有权
公开(公告)号：US20130178621A1
公开(公告)日：2013-07-11
申请号：US13778262
申请日：2013-02-27
申请人： BASF SE
发明人： Oliver MOLT , Evelyn Fuchs , Martina Egen , Klaus Kahle , Christian Lennartz
IPC分类号： C07F15/00
CPC分类号： C07F15/0033 , B01J31/2265 , C07F15/0073 , C07F15/0086
摘要： Process for preparing cyclometallated transition metal-carbene complexes comprising at least one carbene ligand, which comprises reacting a ligand precursor with a base, an auxiliary reagent and a metal complex comprising at least one metal M1 (route A) or reacting the ligand precursor with a basic auxiliary reagent and a metal complex comprising at least one metal M1 (route B). The present invention further relates to the use of an auxiliary reagent selected from among salts comprising at least one metal selected from the group consisting of Ag, Hg, Sb, Mg, B and Al together with a base in a process for preparing cyclometallated metal complexes.

4. 发明申请

US20150353491A1 2,6-BIS-(AMINOMETHYL)PIPERIDINE DERIVATIVES 有权
标题翻译： 2,6-BIS-（氨基乙基）哌啶衍生物
公开(公告)号：US20150353491A1
公开(公告)日：2015-12-10
申请号：US14764010
申请日：2014-01-27
申请人： BASF SE
发明人： Stephanie JAEGLI , Thomas SCHMIDT , Alfred OFTRING , Alexander PANCHENKO , Kirsten DAHMEN , Oliver MOLT
IPC分类号： C07D211/26
CPC分类号： C07D211/26 , C07D211/60
摘要： The present invention relates to 2,6-bis(aminomethyl)piperidine derivatives as such (in the following text abbreviated to “2,6-BAMP derivatives”) which are defined by the general formula (I) shown in the following text. In addition, the present invention relates to a process for preparing such 2,6-BAMP derivatives by hydrogenation of the corresponding 2,6-dicyanopiperidine derivatives (hereinafter abbreviated to “2,6-DCP derivatives”) in the presence of a catalyst. The present invention further provides for the use of the 2,6-BAMP derivatives of the invention as hardeners for epoxy resins, as intermediate in the preparation of diisocyanates, which play an important role in the production of polyurethanes, as starters in the preparation of polyetherols and/or as monomers for polyamide production. The present invention further relates to the diisocyanates as such prepared from the 2,6-BAMP derivatives and also the corresponding preparative process.
摘要翻译：本发明涉及如下文所示的由通式（I）定义的2,6-二（氨基甲基）哌啶衍生物（以下简称为“2,6-BAMP衍生物”）。此外，本发明涉及通过在催化剂存在下氢化相应的2,6-二氰基哌啶衍生物（以下简称为“2,6-DCP衍生物”）制备这种2,6-BAMP衍生物的方法。本发明还提供了本发明的2,6-BAMP衍生物作为环氧树脂的硬化剂的用途，作为制备二异氰酸酯的中间体，其在聚氨酯的生产中起重要作用，作为起始剂在制备聚乙烯醇和/或作为聚酰胺生产的单体。本发明还涉及由2,6-BAMP衍生物制备的二异氰酸酯以及相应的制备方法。

5. 发明申请

US20150018544A1 PROCESS FOR PREPARING TRANSITION METAL-CARBENE COMPLEXES 审中-公开
公开(公告)号：US20150018544A1
公开(公告)日：2015-01-15
申请号：US14480973
申请日：2014-09-09
申请人： BASF SE
发明人： Oliver MOLT , Evelyn FUCHS , Martina EGEN , Klaus KAHLE , Christian LENNARTZ
IPC分类号： C07F15/00
CPC分类号： C07F15/0033 , B01J31/2265 , C07F15/0073 , C07F15/0086
摘要： Process for preparing cyclometallated transition metal-carbene complexes comprising at least one carbene ligand, which comprises reacting a ligand precursor with a base, an auxiliary reagent and a metal complex comprising at least one metal M1 (route A) or reacting the ligand precursor with a basic auxiliary reagent and a metal complex comprising at least one metal M1 (route B). The present invention further relates to the use of an auxiliary reagent selected from among salts comprising at least one metal selected from the group consisting of Ag, Hg, Sb, Mg, B and Al together with a base in a process for preparing cyclometallated metal complexes.

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