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    • 6. 发明授权
    • Perfluorinated polyether release agent for fuser members
    • 用于定影器构件的全氟聚醚脱模剂
    • US07491435B2
    • 2009-02-17
    • US11444559
    • 2006-05-31
    • David J. GervasiBryan J. RoofSantokh S. Badesha
    • David J. GervasiBryan J. RoofSantokh S. Badesha
    • B32B1/08B32B25/14B32B25/20G03G15/20
    • G03G15/2057G03G2215/2051Y10T428/1393Y10T428/3154Y10T428/31663
    • A fuser member having a substrate; an outer layer containing a silicone or fluoropolymer; and a release agent material coating on the outer layer, wherein the release agent material coating includes a perfluorinated polyether having a skeleton of Formulas I or II or mixtures thereof: CF3—(CF2CF2)m—O—(R1R2O)—(R3R3O)n—(R3O)p—(CF2)q—CF3  Formula I wherein R1 is selected from the group consisting of CF2, CF—CF3 and —NR4R5; R2 is selected from the group consisting of CF2, CF—CF3, and —NR4R5; R3 is selected from the group consisting of CF2 and CF3; R4 is selected from the group consisting of hydrogen, alkyl group having from about 1 to about 18 carbon atoms, arylalkyl group having from about 7 to about 18 carbon atoms, mercapto, hydride and carbinol functional group; R5 is selected from the group consisting of alkyl having from about 1 to about 20 carbons, and a fluoroalkyl having from about 2 to about 10 carbons; m is a number of 0 or 1; n is a number of from about 0 to about 500; p is a number of from about 0 to about 100; q is a number of 0 or 1; and p+n is a number of from about 180 to about 500; and R1—(CF2CF2)m—O—(R2R2O)n—(R2O)p—(CF2)q—CF3—R1  Formula II wherein R1 is CF3; R2 is CF2, or CF—CF3; m is a number of 0 or 1; n is a number of from about 0 to about 500; p is a number of from about 0 to about 100; q is a number of 0 or 1; and p+n is a number of from about 180 to about 500.
    • 具有基板的定影器构件; 含有硅酮或含氟聚合物的外层; 以及在所述外层上涂覆的脱模剂材料,其中所述脱模剂材料涂层包括具有式I或II骨架的全氟化聚醚或其混合物:<?in-line-formula description =“In-line Formulas”end = “引线”→CF 3 - (CF 2 CF 2)mO-(R 1 R 2 O) - (R 3 R 3 O)n - (R 3 O)p - (CF 2)q -CF 3式I <βin-line-formula description =“In-line Formulas =“尾”→其中R1选自CF2,CF-CF3和-NR4R5; R2选自CF2,CF-CF3和-NR4R5; R3选自CF2和CF3; R 4选自氢,具有约1至约18个碳原子的烷基,具有约7至约18个碳原子的芳基烷基,巯基,氢化物和甲醇官能团; R5选自具有约1至约20个碳的烷基和具有约2至约10个碳的氟代烷基; m是0或1的数字; n为约0至约500的数; p是约0至约100的数; q是0或1的数字; 并且p + n为约180至约500的数; R 1 - (CF 2 CF 2)m O - (R 2 R 2 O)n - (R 2 O)p - (CF 2)q CF 3-R 1式II <?in-line-formula description =“In-line Formulas”end =“tail”?>其中R1是CF3; R2是CF2或CF-CF3; m是0或1的数字; n为约0至约500的数; p是约0至约100的数; q是0或1的数字; 而p + n为约180至约500的数。