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1. 发明申请

US20180309170A1 BATTERY WITH ALUMINUM-CONTAINING CATHODE 审中-公开
公开(公告)号：US20180309170A1
公开(公告)日：2018-10-25
申请号：US15956630
申请日：2018-04-18
申请人： C. Austen Angell , Leigang Xue
发明人： C. Austen Angell , Leigang Xue
IPC分类号： H01M10/39 , H01M2/16 , H01M4/38
CPC分类号： H01M10/399 , H01M2/1646 , H01M2/1686 , H01M4/381 , H01M2300/0057
摘要： A battery includes an anode chamber configured to contain an anolyte and including an anode, a cathode chamber configured to contain a catholyte including a cathode, and a separator between the anode chamber and the cathode chamber. The anode includes sodium, and the cathode includes aluminum. The battery is configured to be operated above a melting point of the anolyte and the catholyte, such that the anolyte is a molten anolyte and the catholyte is a molten catholyte.

2. 发明授权

US10686224B2 Battery with aluminum-containing cathode 有权
公开(公告)号：US10686224B2
公开(公告)日：2020-06-16
申请号：US15956630
申请日：2018-04-18
申请人： C. Austen Angell , Leigang Xue
发明人： C. Austen Angell , Leigang Xue
IPC分类号： H01M10/39 , H01M2/16 , H01M4/38
摘要： A battery includes an anode chamber configured to contain an anolyte and including an anode, a cathode chamber configured to contain a catholyte including a cathode, and a separator between the anode chamber and the cathode chamber. The anode includes sodium, and the cathode includes aluminum. The battery is configured to be operated above a melting point of the anolyte and the catholyte, such that the anolyte is a molten anolyte and the catholyte is a molten catholyte.

3. 发明申请

US20160043431A1 INORGANIC PLASTIC CRYSTAL ELECTROLYTES 审中-公开
标题翻译：无机塑料晶体电解质
公开(公告)号：US20160043431A1
公开(公告)日：2016-02-11
申请号：US14775215
申请日：2014-03-14
申请人： C. Austen ANGELL , Iolanda Santana KLEIN , Telpriore Greg TUCKER
发明人： C. Austen Angell , Iolanda Santana Klein , Telpriore Greg Tucker
IPC分类号： H01M10/0562 , H01M10/0525
CPC分类号： H01M10/0562 , H01M10/0525 , H01M2300/0071 , H01M2300/0091
摘要： Inorganic plastic crystal electrolytes, also referred to herein as inorganic plastic crystal conductors or single ion conductors including [ABx-yCy]y−[M]y+, where A is a tetravalent to hexavalent atom; B is a monovalent ligand; C is an oxyanion; M is an alkali metal; x is 4 when A is tetravalent, x is 5 when A is pentavalent, and x is 6 when A is hexavalent; y is an integer from 1 to x−1 inclusive. [ABx-yCy]y−[M]y+ is rotationally disordered and electrically conductive.
摘要翻译：无机塑料晶体电解质，本文也称为无机塑料晶体导体或包含[ABx-yCy] y- [M] y +的单离子导体，其中A为四价至六价原子; B是一价配体; C是氧阴离子; M是碱金属; 当A为四价时x为4，A为五价时x为5，A为六价时x为6; y为1〜x-1的整数。 [ABx-yCy] y- [M] y +是旋转地无序并导电的。

4. 发明申请

US20170237101A1 PHOSPHORIC ACID-BASED ELECTROLYTES AND APPLICATIONS THEREOF 有权
公开(公告)号：US20170237101A1
公开(公告)日：2017-08-17
申请号：US15587107
申请日：2017-05-04
申请人： C. Austen Angell , Younes Ansari , Telpriore Greg Tucker
发明人： C. Austen Angell , Younes Ansari , Telpriore Greg Tucker
IPC分类号： H01M8/086
CPC分类号： H01M8/086 , H01B1/06 , H01M8/0289 , H01M8/1016 , H01M8/1048 , H01M2300/0008 , H01M2300/0068 , H01M2300/0085 , H01M2300/0091
摘要： A liquid electrolyte formed by reacting phosphoric acid (H3PO4) in the liquid state with silicon tetrachloride (SiCl4), thereby forming a fluid suspension. The fluid suspension is heated to yield a liquid electrolyte including phosphoric acid (H3PO4), pyrophosphoric acid (H4P2O7), and a particulate solid comprising a silicophosphoric acid, wherein the silicophosphoric acid is an acidic molecular compound including silicon and phosphorus. A concentrated silicophosphoric acid composition prepared by removing most of the liquid from the liquid electrolyte is dissolved in water to yield a homogeneous solution. The homogeneous solution is dried to yield a solid electrolyte. In some cases, the homogenous solution is dried on a substrate to coat at least a portion of the substrate with a proton conductive solid electrolyte. A fuel cell may include the liquid electrolyte, the solid electrolyte, or the coated substrate.

5. 发明申请

US20150270568A1 PHOSPHORIC ACID-BASED ELECTROLYTES AND APPLICATIONS THEREOF 有权
标题翻译：基于磷酸的电解质及其应用
公开(公告)号：US20150270568A1
公开(公告)日：2015-09-24
申请号：US14621707
申请日：2015-02-13
申请人： C. Austen Angell , Younes Ansari , Telpriore Greg Tucker
发明人： C. Austen Angell , Younes Ansari , Telpriore Greg Tucker
IPC分类号： H01M8/10 , H01M8/02
CPC分类号： H01M8/086 , H01B1/06 , H01M8/0289 , H01M8/1016 , H01M8/1048 , H01M2300/0008 , H01M2300/0068 , H01M2300/0085 , H01M2300/0091
摘要： A liquid electrolyte formed by reacting phosphoric acid (H3PO4) in the liquid state with silicon tetrachloride (SiCl4), thereby forming a fluid suspension. The fluid suspension is heated to yield a liquid electrolyte including phosphoric acid (H3PO4), pyrophosphoric acid (H4P2O7), and a particulate solid comprising a silicophosphoric acid, wherein the silicophosphoric acid is an acidic molecular compound including silicon and phosphorus. A concentrated silicophosphoric acid composition prepared by removing most of the liquid from the liquid electrolyte is dissolved in water to yield a homogeneous solution. The homogeneous solution is dried to yield a solid electrolyte. In some cases, the homogenous solution is dried on a substrate to coat at least a portion of the substrate with a proton conductive solid electrolyte. A fuel cell may include the liquid electrolyte, the solid electrolyte, or the coated substrate.
摘要翻译：通过使液态磷酸（H 3 PO 4）与四氯化硅（SiCl 4）反应形成的液体电解质，从而形成流体悬浮液。将流体悬浮液加热以产生包括磷酸（H 3 PO 4），焦磷酸（H 4 P 2 O 7）和包含硅磷酸的颗粒固体的液体电解质，其中硅磷酸是包括硅和磷的酸性分子化合物。通过从液体电解质中除去大部分液体而制备的浓缩硅磷酸组合物溶于水中以得到均匀的溶液。将均匀溶液干燥以产生固体电解质。在一些情况下，将均匀的溶液在基材上干燥以用质子传导性固体电解质涂覆至少一部分基材。燃料电池可以包括液体电解质，固体电解质或涂覆的基底。

6. 发明授权

US07867658B2 Ionic liquids and ionic liquid acids with high temperature stability for fuel cell and other high temperature applications, method of making and cell employing same 有权
标题翻译：用于燃料电池和其他高温应用的离子液体和离子液体酸具有高温稳定性，制备方法和使用细胞的方法
公开(公告)号：US07867658B2
公开(公告)日：2011-01-11
申请号：US10555468
申请日：2004-05-03
申请人： C. Austen Angell , Wu Xu , Jean-Philippe Belieres , Masahiro Yoshizawa
发明人： C. Austen Angell , Wu Xu , Jean-Philippe Belieres , Masahiro Yoshizawa
IPC分类号： H01M8/00 , H01M8/08
CPC分类号： H01M8/144 , H01M8/1016 , H01M8/14 , H01M2300/0005 , H01M2300/0022 , H01M2300/0048 , H01M2300/0054 , H01M2300/0062 , H01M2300/0085 , H01M2300/0091 , Y02P70/56
摘要： Disclosed are developments in high temperature fuel cells including ionic liquids with high temperature stability and the storage of inorganic acids as di-anion salts of low volatility. The formation of ionically conducting liquids of this type having conductivities of unprecedented magnitude for non-aqueous systems is described. The stability of the di-anion configuration is shown to play a role in the high performance of the non-corrosive proton-transfer ionic liquids as high temperature fuel cell electrolytes. Performance of simple H2(g) electrolyte/O2(g) fuel cells with the new electrolytes is described. Superior performance both at ambient temperature and temperatures up to and above 200° C. are achieved. Both neutral proton transfer salts and the acid salts with HSO−4 anions, give good results, the bisulphate case being particularly good at low temperatures and very high temperatures. The performance of all electrolytes is improved by the addition of a small amount of involatile base of pKa value intermediate between those of the acid and base that make the bulk electrolyte. The preferred case is the imidazole-doped ethylammonium hydrogensulfate which yields behavior superior in all respects to that of the industry standard phosphoric acid electrolyte.
摘要翻译：公开了高温燃料电池的发展，包括具有高温稳定性的离子液体和无机酸作为低挥发性的二阴离子盐的储存。描述了具有前所未有的非水系统电导率的这种离子导电液体的形成。二阴离子配置的稳定性显示出在非腐蚀性质子转移离子液体作为高温燃料电池电解质的高性能中起作用。描述了具有新电解质的简单H 2（g）电解质/ O 2（g）燃料电池的性能。在环境温度和高于和高于200℃的温度下都能实现卓越的性能。两种中性质子转移盐和与HSO-4阴离子的酸式盐都具有良好的结果，硫酸氢盐的情况在低温和非常高的温度下特别好。所有电解质的性能通过在制造本体电解质的酸和碱之间添加少量pKa值的非挥发性碱而提高。优选的情况是咪唑掺杂的硫酸氢铵，其产生的行为在所有方面都优于工业标准磷酸电解质。

7. 发明授权

US5518970A Nitride glasses and methods of making same 失效
标题翻译：氮化玻璃及其制作方法
公开(公告)号：US5518970A
公开(公告)日：1996-05-21
申请号：US447534
申请日：1995-05-24
申请人： Paul F. McMillan , C. Austen Angell , Tor Grande , John R. Holloway
发明人： Paul F. McMillan , C. Austen Angell , Tor Grande , John R. Holloway
IPC分类号： C03B19/09 , C03C3/32 , C03C3/16
CPC分类号： C03B19/09 , C03C3/328 , C03B2201/70 , C03B2201/80 , Y10S501/901
摘要： The present invention relates generally to a novel and unique class of gly materials and methods of making such materials in which substantially all of the anions are nitride ions, in contrast to the oxide ions of conventional optical glasses, or the fluoride ions of the more recently discovered fluoride optical glasses. The chemical nature of these new glasses dispose the glassy materials to a remarkable combination of desirable properties, including, but not limited to, high hardness, high refractive index and high softening temperature.
摘要翻译：本发明一般涉及一种新颖而独特的玻璃质材料及其制造方法，其中基本上所有的阴离子都是氮化物离子，与传统的光学眼镜的氧化物离子相比，更近的是氟离子发现氟化物光学眼镜。这些新玻璃的化学性质将玻璃状材料配置成所需性能的显着组合，包括但不限于高硬度，高折射率和高软化温度。

8. 发明授权

US5455211A Methods of making nitride glasses 失效
标题翻译：制造氮化玻璃的方法
公开(公告)号：US5455211A
公开(公告)日：1995-10-03
申请号：US229656
申请日：1994-04-19
申请人： Paul F. McMillan , C. Austen Angell , Tor Grande , John R. Holloway
发明人： Paul F. McMillan , C. Austen Angell , Tor Grande , John R. Holloway
IPC分类号： C03B19/09 , C03C3/32 , C03C3/11
CPC分类号： C03B19/09 , C03C3/328 , C03B2201/70 , C03B2201/80 , Y10S501/901
摘要： The present invention relates generally to a novel and unique class of gly materials and methods of making such materials in which substantially all of the anions are nitride ions, in contrast to the oxide ions of conventional optical glasses, or the fluoride ions of the more recently discovered fluoride optical glasses. The chemical nature of these new glasses dispose the glassy materials to a remarkable combination of desirable properties, including, but not limited to, high hardness, high refractive index and high softening temperature.
摘要翻译：本发明一般涉及一种新颖而独特的玻璃质材料及其制造方法，其中基本上所有的阴离子都是氮化物离子，与传统的光学眼镜的氧化物离子相比，更近的是氟离子发现氟化物光学眼镜。这些新玻璃的化学性质将玻璃状材料配置成所需性能的显着组合，包括但不限于高硬度，高折射率和高软化温度。

9. 发明授权

US09768462B2 Phosphoric acid-based electrolytes and applications thereof 有权
公开(公告)号：US09768462B2
公开(公告)日：2017-09-19
申请号：US15587107
申请日：2017-05-04
申请人： C. Austen Angell , Younes Ansari , Telpriore Greg Tucker
发明人： C. Austen Angell , Younes Ansari , Telpriore Greg Tucker
IPC分类号： H01M8/08 , H01M8/086
CPC分类号： H01M8/086 , H01B1/06 , H01M8/0289 , H01M8/1016 , H01M8/1048 , H01M2300/0008 , H01M2300/0068 , H01M2300/0085 , H01M2300/0091
摘要： A liquid electrolyte formed by reacting phosphoric acid (H3PO4) in the liquid state with silicon tetrachloride (SiCl4), thereby forming a fluid suspension. The fluid suspension is heated to yield a liquid electrolyte including phosphoric acid (H3PO4), pyrophosphoric acid (H4P2O7), and a particulate solid comprising a silicophosphoric acid, wherein the silicophosphoric acid is an acidic molecular compound including silicon and phosphorus. A concentrated silicophosphoric acid composition prepared by removing most of the liquid from the liquid electrolyte is dissolved in water to yield a homogeneous solution. The homogeneous solution is dried to yield a solid electrolyte. In some cases, the homogenous solution is dried on a substrate to coat at least a portion of the substrate with a proton conductive solid electrolyte. A fuel cell may include the liquid electrolyte, the solid electrolyte, or the coated substrate.

10. 发明授权

US09647288B2 Phosphoric acid-based electrolytes and applications thereof 有权
公开(公告)号：US09647288B2
公开(公告)日：2017-05-09
申请号：US14621707
申请日：2015-02-13
申请人： C. Austen Angell , Younes Ansari , Telpriore Greg Tucker
发明人： C. Austen Angell , Younes Ansari , Telpriore Greg Tucker
IPC分类号： H01M8/10 , H01M8/02 , H01M8/1016 , H01B1/06 , H01M8/0289 , H01M8/1048
CPC分类号： H01M8/086 , H01B1/06 , H01M8/0289 , H01M8/1016 , H01M8/1048 , H01M2300/0008 , H01M2300/0068 , H01M2300/0085 , H01M2300/0091
摘要： A liquid electrolyte formed by reacting phosphoric acid (H3PO4) in the liquid state with silicon tetrachloride (SiCl4), thereby forming a fluid suspension. The fluid suspension is heated to yield a liquid electrolyte including phosphoric acid (H3PO4), pyrophosphoric acid (H4P2O7), and a particulate solid comprising a silicophosphoric acid, wherein the silicophosphoric acid is an acidic molecular compound including silicon and phosphorus. A concentrated silicophosphoric acid composition prepared by removing most of the liquid from the liquid electrolyte is dissolved in water to yield a homogeneous solution. The homogeneous solution is dried to yield a solid electrolyte. In some cases, the homogenous solution is dried on a substrate to coat at least a portion of the substrate with a proton conductive solid electrolyte. A fuel cell may include the liquid electrolyte, the solid electrolyte, or the coated substrate.

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