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1. 发明申请

US20120077080A1 Lithium super-battery with a chemically functionalized disordered carbon cathode 有权
标题翻译：具有化学官能化无序碳阴极的锂超级电池
公开(公告)号：US20120077080A1
公开(公告)日：2012-03-29
申请号：US12924211
申请日：2010-09-23
申请人： Chenguang Liu , Aruna Zhamu , David Neff , Bor Z. Jang
发明人： Chenguang Liu , Aruna Zhamu , David Neff , Bor Z. Jang
IPC分类号： H01M10/26
CPC分类号： H01M4/587 , H01G11/06 , H01G11/38 , H01G11/50 , H01M4/485 , H01M4/5825 , H01M10/0525 , H01M2004/021 , Y02E60/122 , Y02E60/13
摘要： An electrochemical energy storage device, lithium super-battery, comprising a positive electrode, a negative electrode, a porous separator disposed between the two electrodes, and a lithium-containing electrolyte in physical contact with the two electrodes, wherein the positive electrode comprises a disordered carbon material having a functional group that reversibly reacts with a lithium atom or ion. The disordered carbon material is selected from a soft carbon, hard carbon, polymeric carbon or carbonized resin, meso-phase carbon, coke, carbonized pitch, carbon black, activated carbon, or partially graphitized carbon. In a preferred embodiment, a lithium super-battery having a functionalized disordered carbon cathode and a Li4Ti5O12 anode exhibits a gravimetric energy ˜5-10 times higher than those of conventional supercapacitors and a power density ˜10-30 times higher than those of conventional lithium-ion batteries. This device has the best properties of both the lithium ion battery and the supercapacitor.
摘要翻译：一种电化学蓄电装置，锂超级电池，包括正极，负极，设置在两个电极之间的多孔隔板和与两个电极物理接触的含锂电解质，其中正极包括无序的具有与锂原子或离子可逆地反应的官能团的碳材料。无序碳材料选自软碳，硬碳，聚合碳或碳化树脂，中间相碳，焦炭，碳化沥青，炭黑，活性炭或部分石墨化碳。在优选实施例中，具有官能化无序碳阴极和Li 4 Ti 5 O 12阳极的锂超级电池显示比常规超级电容器高约5-10倍的重量能量，并且功率密度比传统锂电池高10〜30倍电池。该器件具有锂离子电池和超级电容器的最佳性能。

2. 发明授权

US08795899B2 Lithium super-battery with a functionalized nano graphene cathode 有权
标题翻译：具有功能化纳米石墨烯阴极的锂超级电池
公开(公告)号：US08795899B2
公开(公告)日：2014-08-05
申请号：US12806679
申请日：2010-08-19
申请人： Chenguang Liu , Aruna Zhamu , David Neff , Bor Z. Jang
发明人： Chenguang Liu , Aruna Zhamu , David Neff , Bor Z. Jang
IPC分类号： H01M4/02 , H01M4/13 , H01M4/58 , H01G11/50 , H01M10/0525 , H01G11/06 , H01G11/38 , H01M4/587
CPC分类号： H01M4/587 , H01G11/06 , H01G11/38 , H01G11/50 , H01M10/0525 , Y02E60/122 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
摘要： An electrochemical energy storage device, lithium super-battery, comprising a positive electrode, a negative electrode, a porous separator disposed between the two electrodes, and a lithium-containing electrolyte in physical contact with the two electrodes, wherein the positive electrode comprises a plurality of chemically functionalized nano graphene platelets (f-NGP) or exfoliated graphite having a functional group that reversibly reacts with a lithium atom or ion. In a preferred embodiment, a lithium super-battery having a f-NGP positive electrode and Li4Ti5O12 negative electrode exhibits a gravimetric energy ˜5 times higher than conventional supercapacitors and a power density ˜10 times higher than conventional lithium-ion batteries. This device has the best properties of both the lithium ion battery and the supercapacitor.
摘要翻译：一种锂电池，包括正极，负极，设置在两个电极之间的多孔隔板的锂电池，以及与两个电极物理接触的含锂电解质，其中正电极包括多个的化学官能化纳米石墨烯片（f-NGP）或具有与锂原子或离子可逆反应的官能团的剥离石墨。在一个优选实施例中，具有f-NGP正极和Li 4 Ti 5 O 12负极的锂超级电池表现出比传统超级电容器高约5倍的重量能量，并且功率密度比常规锂离子电池高约10倍。该器件具有锂离子电池和超级电容器的最佳性能。

3. 发明授权

US08900755B2 Lithium super-battery with a chemically functionalized disordered carbon cathode 有权
标题翻译：具有化学官能化无序碳阴极的锂超级电池
公开(公告)号：US08900755B2
公开(公告)日：2014-12-02
申请号：US12924211
申请日：2010-09-23
申请人： Chenguang Liu , Aruna Zhamu , David Neff , Bor Z. Jang
发明人： Chenguang Liu , Aruna Zhamu , David Neff , Bor Z. Jang
IPC分类号： H01M4/13 , H01M4/587 , H01G11/06 , H01G11/38 , H01G11/50 , H01M10/0525 , H01M4/485 , H01M4/58 , H01M4/02
CPC分类号： H01M4/587 , H01G11/06 , H01G11/38 , H01G11/50 , H01M4/485 , H01M4/5825 , H01M10/0525 , H01M2004/021 , Y02E60/122 , Y02E60/13
摘要： An electrochemical energy storage device, lithium super-battery, comprising a positive electrode, a negative electrode, a porous separator disposed between the two electrodes, and a lithium-containing electrolyte in physical contact with the two electrodes, wherein the positive electrode comprises a disordered carbon material having a functional group that reversibly reacts with a lithium atom or ion. The disordered carbon material is selected from a soft carbon, hard carbon, polymeric carbon or carbonized resin, meso-phase carbon, coke, carbonized pitch, carbon black, activated carbon, or partially graphitized carbon. In a preferred embodiment, a lithium super-battery having a functionalized disordered carbon cathode and a Li4Ti5O12 anode exhibits a gravimetric energy ˜5-10 times higher than those of conventional supercapacitors and a power density ˜10-30 times higher than those of conventional lithium-ion batteries. This device has the best properties of both the lithium ion battery and the supercapacitor.
摘要翻译：一种电化学蓄电装置，锂超级电池，包括正极，负极，设置在两个电极之间的多孔隔板和与两个电极物理接触的含锂电解质，其中正极包括无序的具有与锂原子或离子可逆地反应的官能团的碳材料。无序碳材料选自软碳，硬碳，聚合碳或碳化树脂，中间相碳，焦炭，碳化沥青，炭黑，活性炭或部分石墨化碳。在优选实施例中，具有官能化无序碳阴极和Li 4 Ti 5 O 12阳极的锂超级电池显示比常规超级电容器高约5-10倍的重量能量，并且功率密度比传统锂电池高10〜30倍电池。该器件具有锂离子电池和超级电容器的最佳性能。

4. 发明申请

US20120045688A1 Lithium super-battery with a functionalized nano graphene cathode 有权
标题翻译：具有功能化纳米石墨烯阴极的锂超级电池
公开(公告)号：US20120045688A1
公开(公告)日：2012-02-23
申请号：US12806679
申请日：2010-08-19
申请人： Chenguang Liu , Aruna Zhamu , David Neff , Bor Z. Jang
发明人： Chenguang Liu , Aruna Zhamu , David Neff , Bor Z. Jang
IPC分类号： H01M10/052 , H01M10/0563
CPC分类号： H01M4/587 , H01G11/06 , H01G11/38 , H01G11/50 , H01M10/0525 , Y02E60/122 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
摘要： An electrochemical energy storage device, lithium super-battery, comprising a positive electrode, a negative electrode, a porous separator disposed between the two electrodes, and a lithium-containing electrolyte in physical contact with the two electrodes, wherein the positive electrode comprises a plurality of chemically functionalized nano graphene platelets (f-NGP) or exfoliated graphite having a functional group that reversibly reacts with a lithium atom or ion. In a preferred embodiment, a lithium super-battery having a f-NGP positive electrode and Li4Ti5O12 negative electrode exhibits a gravimetric energy ˜5 times higher than conventional supercapacitors and a power density ˜10 times higher than conventional lithium-ion batteries. This device has the best properties of both the lithium ion battery and the supercapacitor.
摘要翻译：一种锂电池，包括正极，负极，设置在两个电极之间的多孔隔板的锂电池，以及与两个电极物理接触的含锂电解质，其中正电极包括多个的化学官能化纳米石墨烯片（f-NGP）或具有与锂原子或离子可逆反应的官能团的剥离石墨。在一个优选实施例中，具有f-NGP正极和Li 4 Ti 5 O 12负极的锂超级电池表现出比传统超级电容器高约5倍的重量能量，并且功率密度比常规锂离子电池高约10倍。该器件具有锂离子电池和超级电容器的最佳性能。

5. 发明授权

US09166252B2 Surface-controlled lithium ion-exchanging energy storage device 有权
标题翻译：表面控制锂离子交换储能装置
公开(公告)号：US09166252B2
公开(公告)日：2015-10-20
申请号：US12928927
申请日：2010-12-23
申请人： Aruna Zhamu , ChenGuang Liu , David Neff , Bor Z. Jang
发明人： Aruna Zhamu , ChenGuang Liu , David Neff , Bor Z. Jang
IPC分类号： H01M4/131 , H01M4/133 , H01M4/134 , H01M4/137 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/583 , H01M4/60 , H01M10/0525 , H01M4/04 , H01M4/13 , H01M4/1399 , H01M4/38 , H01M4/40 , H01M4/587 , H01G11/50 , H01G11/56 , H01G11/36 , H01M10/0565 , H01M10/0566 , H01M4/02
CPC分类号： H01M10/0525 , H01G11/36 , H01G11/50 , H01G11/56 , H01M4/0445 , H01M4/13 , H01M4/131 , H01M4/133 , H01M4/134 , H01M4/137 , H01M4/1399 , H01M4/38 , H01M4/382 , H01M4/405 , H01M4/485 , H01M4/587 , H01M4/60 , H01M4/602 , H01M4/604 , H01M10/0565 , H01M10/0566 , H01M2004/021 , Y02E60/122 , Y02E60/13
摘要： A surface-controlled, lithium ion-exchanging battery device comprising: (a) A positive electrode (cathode) comprising a first functional material having a first lithium-capturing or lithium-storing surface; (b) A negative electrode (anode) comprising a second functional material having a second lithium-capturing or lithium-storing surface; (c) A porous separator disposed between the two electrodes, and (d) A lithium-containing electrolyte (preferably liquid or gel electrolyte) in physical contact with the two electrodes; wherein at least one of the two electrodes contains therein a lithium source (e.g., lithium foil, lithium powder, stabilized lithium particles, etc) prior to the first charge or the first discharge cycle of the battery device. This new generation of energy storage device exhibits the best properties of both the lithium ion battery and the supercapacitor.
摘要翻译：一种表面控制的锂离子交换电池装置，包括：（a）正极（阴极），包括具有第一锂捕获或锂储存表面的第一功能材料; （b）负极（阳极），包括具有第二锂捕获或锂储存表面的第二功能材料; （c）设置在两个电极之间的多孔隔板，和（d）与两个电极物理接触的含锂电解质（优选液体或凝胶电解质）; 其中所述两个电极中的至少一个在所述电池装置的第一次充电或第一次放电循环之前包含锂源（例如，锂箔，锂粉末，稳定的锂颗粒等）。这种新一代储能装置表现出锂离子电池和超级电容器的最佳性能。

6. 发明授权

US08859143B2 Partially and fully surface-enabled metal ion-exchanging energy storage devices 有权
标题翻译：部分和完全表面使能的金属离子交换储能装置
公开(公告)号：US08859143B2
公开(公告)日：2014-10-14
申请号：US12930294
申请日：2011-01-03
申请人： Aruna Zhamu , ChenGuang Liu , David Neff , Bor Z. Jang , Zhenning Yu
发明人： Aruna Zhamu , ChenGuang Liu , David Neff , Bor Z. Jang , Zhenning Yu
IPC分类号： H01M4/60 , H01M4/583 , H01M10/05 , H01M4/36 , H01M10/0565 , B82Y30/00 , H01M10/0566 , B82Y40/00 , H01M10/054 , H01M4/13 , H01M4/02 , H01M4/38
CPC分类号： H01M10/054 , B82Y30/00 , B82Y40/00 , H01M4/13 , H01M4/364 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/583 , H01M4/60 , H01M4/602 , H01M10/05 , H01M10/0565 , H01M10/0566 , H01M2004/021 , H01M2300/0025 , H01M2300/0085 , Y02E60/122 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
摘要： A surface-enabled, metal ion-exchanging battery device comprising a cathode, an anode, a porous separator, and a metal ion-containing electrolyte, wherein the metal ion is selected from (A) non-Li alkali metals; (B) alkaline-earth metals; (C) transition metals; (D) other metals such as aluminum (Al); or (E) a combination thereof; and wherein at least one of the electrodes contains therein a metal ion source prior to the first charge or discharge cycle of the device and at least the cathode comprises a functional material or nano-structured material having a metal ion-capturing functional group or metal ion-storing surface in direct contact with said electrolyte, and wherein the operation of the battery device does not involve the introduction of oxygen from outside the device and does not involve the formation of a metal oxide, metal sulfide, metal selenide, metal telluride, metal hydroxide, or metal-halogen compound. This energy storage device has a power density significantly higher than that of a lithium-ion battery and an energy density dramatically higher than that of a supercapacitor.
摘要翻译：一种表面使能的金属离子交换电池装置，包括阴极，阳极，多孔隔膜和含金属离子的电解质，其中所述金属离子选自（A）非Li碱金属; （B）碱土金属; （C）过渡金属; （D）其他金属如铝（Al）; 或（E）其组合; 并且其中所述电极中的至少一个在所述器件的第一充电或放电循环之前包含金属离子源，并且至少所述阴极包括具有金属离子捕获官能团或金属离子的功能材料或纳米结构材料并且其中电池装置的操作不涉及从装置外部引入氧气，并且不涉及形成金属氧化物，金属硫化物，金属硒化物，金属碲化物，金属氢氧化物或金属卤素化合物。该能量存储装置的功率密度显着高于锂离子电池的功率密度，能量密度显着高于超级电容器。

7. 发明申请

US20120171574A1 Partially and fully surface-enabled metal ion-exchanging energy storage devices 有权
标题翻译：部分和完全表面使能的金属离子交换储能装置
公开(公告)号：US20120171574A1
公开(公告)日：2012-07-05
申请号：US12930294
申请日：2011-01-03
申请人： Aruna Zhamu , ChenGuang Liu , David Neff , Bor Z. Jang , Zhenning Yu
发明人： Aruna Zhamu , ChenGuang Liu , David Neff , Bor Z. Jang , Zhenning Yu
IPC分类号： H01M10/02 , H01M10/05 , B82Y30/00
CPC分类号： H01M10/054 , B82Y30/00 , B82Y40/00 , H01M4/13 , H01M4/364 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/583 , H01M4/60 , H01M4/602 , H01M10/05 , H01M10/0565 , H01M10/0566 , H01M2004/021 , H01M2300/0025 , H01M2300/0085 , Y02E60/122 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
摘要： A surface-enabled, metal ion-exchanging battery device comprising a cathode, an anode, a porous separator, and a metal ion-containing electrolyte, wherein the metal ion is selected from (A) non-Li alkali metals; (B) alkaline-earth metals; (C) transition metals; (D) other metals such as aluminum (Al); or (E) a combination thereof; and wherein at least one of the electrodes contains therein a metal ion source prior to the first charge or discharge cycle of the device and at least the cathode comprises a functional material or nano-structured material having a metal ion-capturing functional group or metal ion-storing surface in direct contact with said electrolyte, and wherein the operation of the battery device does not involve the introduction of oxygen from outside the device and does not involve the formation of a metal oxide, metal sulfide, metal selenide, metal telluride, metal hydroxide, or metal-halogen compound. This energy storage device has a power density significantly higher than that of a lithium-ion battery and an energy density dramatically higher than that of a supercapacitor.
摘要翻译：一种表面使能的金属离子交换电池装置，包括阴极，阳极，多孔隔膜和含金属离子的电解质，其中所述金属离子选自（A）非Li碱金属; （B）碱土金属; （C）过渡金属; （D）其他金属如铝（Al）; 或（E）其组合; 并且其中所述电极中的至少一个在所述器件的第一充电或放电循环之前包含金属离子源，并且至少所述阴极包括具有金属离子捕获官能团或金属离子的功能材料或纳米结构材料并且其中电池装置的操作不涉及从装置外部引入氧气，并且不涉及形成金属氧化物，金属硫化物，金属硒化物，金属碲化物，金属氢氧化物或金属卤素化合物。该能量存储装置的功率密度显着高于锂离子电池的功率密度，能量密度显着高于超级电容器。

8. 发明申请

US20120164539A1 Surface -controlled lithium ion-exchanging energy storage device 有权
标题翻译：表面控制的锂离子交换储能装置
公开(公告)号：US20120164539A1
公开(公告)日：2012-06-28
申请号：US12928927
申请日：2010-12-23
申请人： Aruna Zhamu , ChenGuang Liu , David Neff , Bor Z. Jang
发明人： Aruna Zhamu , ChenGuang Liu , David Neff , Bor Z. Jang
IPC分类号： H01M10/056 , H01M10/26
CPC分类号： H01M10/0525 , H01G11/36 , H01G11/50 , H01G11/56 , H01M4/0445 , H01M4/13 , H01M4/131 , H01M4/133 , H01M4/134 , H01M4/137 , H01M4/1399 , H01M4/38 , H01M4/382 , H01M4/405 , H01M4/485 , H01M4/587 , H01M4/60 , H01M4/602 , H01M4/604 , H01M10/0565 , H01M10/0566 , H01M2004/021 , Y02E60/122 , Y02E60/13
摘要： A surface-controlled, lithium ion-exchanging battery device comprising: (a) A positive electrode (cathode) comprising a first functional material having a first lithium-capturing or lithium-storing surface; (b) A negative electrode (anode) comprising a second functional material having a second lithium-capturing or lithium-storing surface; (c) A porous separator disposed between the two electrodes, and (d) A lithium-containing electrolyte (preferably liquid or gel electrolyte) in physical contact with the two electrodes; wherein at least one of the two electrodes contains therein a lithium source (e.g., lithium foil, lithium powder, stabilized lithium particles, etc) prior to the first charge or the first discharge cycle of the battery device. This new generation of energy storage device exhibits the best properties of both the lithium ion battery and the supercapacitor.
摘要翻译：一种表面控制的锂离子交换电池装置，包括：（a）正极（阴极），包括具有第一锂捕获或锂储存表面的第一功能材料; （b）负极（阳极），包括具有第二锂捕获或锂储存表面的第二功能材料; （c）设置在两个电极之间的多孔隔板，和（d）与两个电极物理接触的含锂电解质（优选液体或凝胶电解质）; 其中所述两个电极中的至少一个在所述电池装置的第一次充电或第一次放电循环之前包含锂源（例如，锂箔，锂粉末，稳定的锂颗粒等）。这种新一代储能装置表现出锂离子电池和超级电容器的最佳性能。

9. 发明申请

US20120026643A1 Supercapacitor with a meso-porous nano graphene electrode 有权
标题翻译：具有中孔多孔纳米石墨烯电极的超级电容器
公开(公告)号：US20120026643A1
公开(公告)日：2012-02-02
申请号：US12804911
申请日：2010-08-02
申请人： Zhenning Yu , David Neff , Chen-guang Liu , Bor Z. Jang , Aruna Zhamu
发明人： Zhenning Yu , David Neff , Chen-guang Liu , Bor Z. Jang , Aruna Zhamu
IPC分类号： H01G9/00
CPC分类号： H01G11/36 , H01G11/02 , H01G11/04 , H01G11/24 , H01G11/38 , H01G11/46 , Y02E60/13
摘要： A supercapacitor comprising a two electrodes, a porous separator disposed between the two electrodes, and an ionic liquid electrolyte in physical contact with the two electrodes, wherein at least one of the two electrodes comprises a meso-porous structure being formed of a plurality of nano graphene platelets and multiple pores having a pore size in the range of 2 nm and 25 nm, wherein the graphene platelets are not spacer-modified or surface-modified platelets. Preferably, the graphene platelets are curved, not flat-shaped. The pores are accessible to ionic liquid molecules, enabling the formation of large amounts of electric double layer charges in a supercapacitor, which exhibits an exceptionally high specific capacitance and high energy density.
摘要翻译：一种超级电容器，包括两个电极，设置在所述两个电极之间的多孔隔离体和与所述两个电极物理接触的离子液体电解质，其中所述两个电极中的至少一个包括由多个纳米颗粒形成的中孔多孔结构石墨烯血小板和孔径在2nm和25nm范围内的多个孔，其中石墨烯血小板不是间隔子改性的或表面改性的血小板。优选地，石墨烯片晶是弯曲的，不是平坦的。离子液体分子可以获得孔隙，使得能够在超级电容器中形成大量的双电层电荷，其表现出非常高的比电容和高能量密度。

10. 发明授权

US09053870B2 Supercapacitor with a meso-porous nano graphene electrode 有权
标题翻译：具有中孔多孔纳米石墨烯电极的超级电容器
公开(公告)号：US09053870B2
公开(公告)日：2015-06-09
申请号：US12804911
申请日：2010-08-02
申请人： Zhenning Yu , David Neff , Chen-guang Liu , Bor Z. Jang , Aruna Zhamu
发明人： Zhenning Yu , David Neff , Chen-guang Liu , Bor Z. Jang , Aruna Zhamu
IPC分类号： H01G11/36 , H01G11/02 , H01G11/04 , H01G11/46 , H01G11/38 , H01G11/24
CPC分类号： H01G11/36 , H01G11/02 , H01G11/04 , H01G11/24 , H01G11/38 , H01G11/46 , Y02E60/13
摘要： A supercapacitor comprising a two electrodes, a porous separator disposed between the two electrodes, and an ionic liquid electrolyte in physical contact with the two electrodes, wherein at least one of the two electrodes comprises a meso-porous structure being formed of a plurality of nano graphene platelets and multiple pores having a pore size in the range of 2 nm and 25 nm, wherein the graphene platelets are not spacer-modified or surface-modified platelets. Preferably, the graphene platelets are curved, not flat-shaped. The pores are accessible to ionic liquid molecules, enabling the formation of large amounts of electric double layer charges in a supercapacitor, which exhibits an exceptionally high specific capacitance and high energy density.
摘要翻译：一种超级电容器，包括两个电极，设置在所述两个电极之间的多孔隔离体和与所述两个电极物理接触的离子液体电解质，其中所述两个电极中的至少一个包括由多个纳米颗粒形成的中孔多孔结构石墨烯血小板和孔径在2nm和25nm范围内的多个孔，其中石墨烯血小板不是间隔子改性的或表面改性的血小板。优选地，石墨烯片晶是弯曲的，不是平坦的。离子液体分子可以获得孔隙，使得能够在超级电容器中形成大量的双电层电荷，其表现出非常高的比电容和高能量密度。

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