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1. 发明授权

US08864893B2 Bio-based binders for insulation and non-woven mats 有权
标题翻译：用于绝缘和无纺布垫的生物基粘合剂
公开(公告)号：US08864893B2
公开(公告)日：2014-10-21
申请号：US12900540
申请日：2010-10-08
申请人： Christopher M. Hawkins , Jesus M. Hernandez-Torres , Liang Chen
发明人： Christopher M. Hawkins , Jesus M. Hernandez-Torres , Liang Chen
IPC分类号： C08G63/48 , C09J103/00 , C09D103/00 , C08L3/00 , C03C25/10 , C03C25/26 , C03C25/32 , C08J3/24 , C09J103/02 , C09J103/04 , C09J105/06 , D04H1/4218 , D04H1/587 , D04H1/64 , D04H13/00 , B32B17/02 , B32B17/04 , D04H5/00 , B32B27/04 , C08K3/00 , C08K5/00 , C08L3/02 , C08L3/04 , C08L5/06
CPC分类号： C08K7/14 , C03C25/002 , C03C25/1095 , C03C25/146 , C03C25/26 , C03C25/32 , C03C25/323 , C03C25/64 , C08J3/24 , C08K3/16 , C08K3/32 , C08K5/0025 , C08K5/053 , C08K5/06 , C08K5/098 , C08K5/11 , C08K5/17 , C08K5/544 , C08K5/56 , C08K2003/164 , C08K2003/329 , C08L3/02 , C08L3/04 , C08L5/00 , C08L5/02 , C08L5/06 , C08L33/02 , C08L2205/02 , C08L2205/06 , C09D103/04 , C09J103/02 , C09J103/04 , C09J105/06 , D04H1/4218 , D04H1/587 , D04H1/641 , D04H13/008 , Y10T428/249924 , Y10T428/24994 , Y10T442/2992 , Y10T442/60 , Y10T442/696 , C08K5/092 , C08K5/54
摘要： An aqueous binder composition is provided that includes a carbohydrate and a crosslinking agent. In exemplary embodiments, the carbohydrate-based binder composition may also include a catalyst, a coupling agent, a process aid, a crosslinking density enhancer, an extender, a moisture resistant agent, a dedusting oil, a colorant, a corrosion inhibitor, a surfactant, a pH adjuster, and combinations thereof. The carbohydrate may be natural in origin and derived from renewable resources. Additionally, the carbohydrate polymer may have a dextrose equivalent (DE) number from 2 to 20. In at least one exemplary embodiment, the carbohydrate is a water-soluble polysaccharide such as dextrin or maltodextrin and the crosslinking agent is citric acid. Advantageously, the carbohydrates have a low viscosity and cure at moderate temperatures. The environmentally friendly, formaldehyde-free binder may be used in the formation of insulation materials and non-woven chopped strand mats. A method of making fibrous insulation products is also provided.
摘要翻译：提供了包含碳水化合物和交联剂的水性粘合剂组合物。在示例性实施方案中，基于碳水化合物的粘合剂组合物还可以包括催化剂，偶联剂，加工助剂，交联密度增强剂，增量剂，防潮剂，除尘油，着色剂，腐蚀抑制剂，表面活性剂，pH调节剂及其组合。碳水化合物可能是天然的，源于可再生资源。另外，碳水化合物聚合物可以具有2至20的葡萄糖当量（DE）数。在至少一个示例性实施方案中，碳水化合物是水溶性多糖，例如糊精或麦芽糖糊精，交联剂是柠檬酸。有利地，碳水化合物具有低粘度并在适度的温度下固化。环保的无甲醛粘合剂可用于形成绝缘材料和无纺短切纤维垫。还提供了制造纤维绝缘产品的方法。

2. 发明申请

US20110086567A1 BIO-BASED BINDERS FOR INSULATION AND NON-WOVEN MATS 有权
标题翻译：用于绝缘和非织造布的生物基础粘合剂
公开(公告)号：US20110086567A1
公开(公告)日：2011-04-14
申请号：US12900540
申请日：2010-10-08
申请人： Christopher M. Hawkins , Jesus M. Hernandez-Torres , Liang Chen
发明人： Christopher M. Hawkins , Jesus M. Hernandez-Torres , Liang Chen
IPC分类号： D04H13/00 , C09D103/02 , C09D103/04 , C09D105/06 , C09D105/00 , B05D3/02
CPC分类号： C08K7/14 , C03C25/002 , C03C25/1095 , C03C25/146 , C03C25/26 , C03C25/32 , C03C25/323 , C03C25/64 , C08J3/24 , C08K3/16 , C08K3/32 , C08K5/0025 , C08K5/053 , C08K5/06 , C08K5/098 , C08K5/11 , C08K5/17 , C08K5/544 , C08K5/56 , C08K2003/164 , C08K2003/329 , C08L3/02 , C08L3/04 , C08L5/00 , C08L5/02 , C08L5/06 , C08L33/02 , C08L2205/02 , C08L2205/06 , C09D103/04 , C09J103/02 , C09J103/04 , C09J105/06 , D04H1/4218 , D04H1/587 , D04H1/641 , D04H13/008 , Y10T428/249924 , Y10T428/24994 , Y10T442/2992 , Y10T442/60 , Y10T442/696 , C08K5/092 , C08K5/54
摘要： An aqueous binder composition is provided that includes a carbohydrate and a crosslinking agent. In exemplary embodiments, the carbohydrate-based binder composition may also include a catalyst, a coupling agent, a process aid, a crosslinking density enhancer, an extender, a moisture resistant agent, a dedusting oil, a colorant, a corrosion inhibitor, a surfactant, a pH adjuster, and combinations thereof. The carbohydrate may be natural in origin and derived from renewable resources. Additionally, the carbohydrate polymer may have a dextrose equivalent (DE) number from 2 to 20. In at least one exemplary embodiment, the carbohydrate is a water-soluble polysaccharide such as dextrin or maltodextrin and the crosslinking agent is citric acid. Advantageously, the carbohydrates have a low viscosity and cure at moderate temperatures. The environmentally friendly, formaldehyde-free binder may be used in the formation of insulation materials and non-woven chopped strand mats. A method of making fibrous insulation products is also provided.
摘要翻译：提供了包含碳水化合物和交联剂的水性粘合剂组合物。在示例性实施方案中，基于碳水化合物的粘合剂组合物还可以包括催化剂，偶联剂，加工助剂，交联密度增强剂，增量剂，防潮剂，除尘油，着色剂，腐蚀抑制剂，表面活性剂，pH调节剂及其组合。碳水化合物可能是天然的，源于可再生资源。另外，碳水化合物聚合物可以具有2至20的葡萄糖当量（DE）数。在至少一个示例性实施方案中，碳水化合物是水溶性多糖，例如糊精或麦芽糖糊精，交联剂是柠檬酸。有利地，碳水化合物具有低粘度并在适度的温度下固化。环保的无甲醛粘合剂可用于形成绝缘材料和无纺短切纤维垫。还提供了制造纤维绝缘产品的方法。

3. 发明申请

US20110021101A1 MODIFIED STARCH BASED BINDER 审中-公开
标题翻译：基于修改的基于STARCH的BINDER
公开(公告)号：US20110021101A1
公开(公告)日：2011-01-27
申请号：US12825375
申请日：2010-06-29
申请人： Christopher M. Hawkins , Liang Chen , Jesus M. Hernandez-Torres , William E. Downey
发明人： Christopher M. Hawkins , Liang Chen , Jesus M. Hernandez-Torres , William E. Downey
IPC分类号： C08F251/00 , C07K1/107 , D04H13/00
CPC分类号： C09J103/10 , C03C25/1095 , C03C25/26 , C03C25/321 , D04H1/4218 , D04H1/64 , D04H3/004 , D04H3/12 , Y10T442/60
摘要： An aqueous binder composition is provided that includes a modified starch and a silane coupling agent, and optionally, a crosslinking agent. The starch from which the modified starch is derived is natural in origin, biorenewable, and is derived from plant sources. The modified starch has been chemically modified from its natural form and may have a degree of polymerization from about 20 to about 4000. Additionally, the modified starches have a low viscosity and cure at moderate temperatures. Advantageously, the modified starches are water dispersible and have excellent resistance to water after curing. In addition, the binder has a light color after being cured. The crosslinking agent may be any compound suitable for crosslinking the starch based compound. In exemplary embodiments, the silane coupling agent is an aminosilane. The environmentally friendly, biorenewable binder may be used in the formation of insulation materials and non-woven chopped strand mats.
摘要翻译：提供了包含改性淀粉和硅烷偶联剂以及任选的交联剂的水性粘合剂组合物。衍生自改性淀粉的淀粉是天然的，生物可再生的，并且衍生自植物来源。改性淀粉已经从其天然形式进行了化学改性，并且可以具有约20至约4000的聚合度。此外，改性淀粉具有低粘度并在适度的温度下固化。有利地，改性淀粉是水分散性的，并且在固化后具有优异的耐水性。此外，粘合剂在固化后具有浅色。交联剂可以是适于交联淀粉基化合物的任何化合物。在示例性实施方案中，硅烷偶联剂是氨基硅烷。环保的生物可再生粘合剂可用于形成绝缘材料和无纺短切纤维垫。

4. 发明申请

US20130334726A1 Use of Surfactants To Improve Aged Properties of Fiberglass Insulation Products 审中-公开
标题翻译：使用表面活性剂改善玻璃纤维绝缘产品的老化性能
公开(公告)号：US20130334726A1
公开(公告)日：2013-12-19
申请号：US13495356
申请日：2012-06-13
申请人： Jesus M. Hernandez-Torres , Christopher M. Hawkins
发明人： Jesus M. Hernandez-Torres , Christopher M. Hawkins
IPC分类号： D04H1/64
CPC分类号： D04H1/64
摘要： Fibrous insulation products manufactured with surfactants and methods for making are disclosed. The surfactant may be neutral or charged and, if charged, may be anionic, cationic or zwitterionic, although neutral or non-ionic provide suitable results. The surfactant may be of any chemical structure class, although ethoxylated alcohols and ethoxylated ethers have been found most suitable. Surfactant may be sprayed onto mineral fibers as a separate dispersion or as part of a binder dispersion. The surfactant my optionally be used with an organo-silane coupling agent, such as an amino-silane.
摘要翻译：公开了用表面活性剂制造的纤维绝缘产品和制造方法。表面活性剂可以是中性的或带电荷的，并且如果带电，则可以是阴离子的，阳离子的或两性离子的，尽管中性或非离子提供适当的结果。表面活性剂可以是任何化学结构类别，尽管已经发现乙氧基化醇和乙氧基化醚最合适。表面活性剂可以作为单独的分散体或粘合剂分散体的一部分喷涂到矿物纤维上。表面活性剂我可以任选地与有机硅烷偶联剂一起使用，例如氨基硅烷。

5. 发明授权

US09718729B2 Biocides for bio-based binders, fibrous insulation products and wash water systems 有权
公开(公告)号：US09718729B2
公开(公告)日：2017-08-01
申请号：US13026415
申请日：2011-02-14
申请人： Jesus M. Hernandez-Torres , Liang Chen , William R. Cooper
发明人： Jesus M. Hernandez-Torres , Liang Chen , William R. Cooper
IPC分类号： C03C25/26 , A01N25/34 , C09J103/02 , A01N25/04 , C03C25/10 , C03C25/28 , C03C25/32 , C08K5/00 , C09J105/06 , C03C25/14
CPC分类号： C03C25/26 , A01N25/04 , A01N25/34 , C03C25/1095 , C03C25/146 , C03C25/285 , C03C25/321 , C08K5/0058 , C08L33/02 , C09J103/02 , C09J105/06 , Y10T428/249924 , C08K5/092 , A01N35/08 , A01N41/10 , A01N43/80 , A01N47/12 , A01N59/00
摘要： Biocides for bio-based binder compositions are disclosed. Bio-based binders include those having a nutrient source such as carbohydrate, protein or fat, which can serve as an energy source for organisms to grow in areas that contact binder. Principal areas that contact bio-based binder in a fiberglass insulation manufacturing process include the raw ingredients, the binder chemicals, the prepared binder dispersions, the forming hood and related equipment, the final insulation product and, importantly, the cleaning systems and washwater arising from cleaning the manufacturing equipment and/or forming the product. Frequently the washwater is stored until re-cycled for re-use. Storage may take place in tanks, towers, vats and even outdoor reservoirs, all of which may harbor the growth of unwanted organisms, for which a biocide is desirable.

6. 发明申请

US20110091710A1 SOFT FIBER INSULATION PRODUCT 审中-公开
标题翻译：软纤维绝缘产品
公开(公告)号：US20110091710A1
公开(公告)日：2011-04-21
申请号：US12758910
申请日：2010-04-13
申请人： David R. Mirth , William M. Babbitt , Liang Chen , Jesus M. Hernandez-Torres
发明人： David R. Mirth , William M. Babbitt , Liang Chen , Jesus M. Hernandez-Torres
IPC分类号： D04H1/64 , B32B5/02 , C03B37/01 , C03B37/10 , C03C25/42 , E04B1/74
CPC分类号： E04B1/7662 , C03C25/255 , C03C25/26 , D04H1/4218 , D04H1/72 , D04H3/002 , Y10T428/249924 , Y10T428/24994
摘要： A rotary fibrous insulation product that is soft to the touch is provided. The fibrous insulation product is formed of glass fibers having an average fiber diameter less than about 5.5 microns. The low fiber diameter helps to impart a soft feel to the insulation product. Additionally, the insulation product contains an oil with a flashpoint of at least 580° F. in an amount up to 5% by weight of the insulation product. The insulation product may contain up to about 85% by weight recycled glass. In exemplary embodiments, the binder is a low-formaldehyde, polyacrylic based binder. The combination of the low fiber diameter, the binder, and the oil create a synergistic effect to produce an unexpectedly soft insulation product. The insulation product is useful in a variety of thermal applications, such as in basements, in attics, and in walls of residential dwellings.
摘要翻译：提供了一种柔软触感的旋转纤维绝缘产品。纤维绝缘产品由平均纤维直径小于约5.5微米的玻璃纤维形成。低纤维直径有助于赋予绝缘产品柔软的感觉。此外，绝缘产品含有闪蒸点至少为580°F的油，其量高达绝缘产品重量的5％。绝缘产品可能含有高达约85重量％的回收玻璃。在示例性实施方案中，粘合剂是低甲醛，基于聚丙烯酸的粘合剂。低纤维直径，粘合剂和油的组合产生协同效应，以产生出乎意料的软绝缘产品。绝缘产品可用于各种热应用，如地下室，阁楼和住宅墙壁。

7. 发明申请

US20110003522A1 BIO-BASED AQUEOUS BINDER FOR FIBERGLASS INSULATION MATERIALS AND NON-WOVEN MATS 审中-公开
标题翻译：用于纤维绝缘材料和非织造布的生物基水性粘合剂
公开(公告)号：US20110003522A1
公开(公告)日：2011-01-06
申请号：US12776703
申请日：2010-05-10
申请人： Liang Chen , William E. Downey , Jesus M. Hernandez-Torres
发明人： Liang Chen , William E. Downey , Jesus M. Hernandez-Torres
IPC分类号： E04B1/74 , C09K3/00 , D04H13/00
CPC分类号： D04H3/004 , C03C25/1095 , C03C25/146 , C03C25/26 , C09J189/00 , D04H1/4218 , D04H1/64 , Y10T442/20
摘要： An aqueous binder composition is provided that includes a protein-containing biomass and a pH adjuster. Optionally, a crosslinking agent and/or a moisture resistant agent may be included in the binder composition. The protein-containing biomass is natural in origin and may be derived from plant or animal sources. The pH adjuster is used to adjust the pH of the binder to a desired pH and lower the viscosity of the protein-based biomass. In addition, the pH adjuster may act as a crosslinking agent. The crosslinking agent may be any compound suitable for crosslinking the protein-containing biomass and reacting with the moisture resistant agent, when the moisture resistant agent is present in the binder. In addition, the binder has a light color after it has been cured. The environmentally friendly, formaldehyde-free binder may be used in the formation of insulation materials and non-woven chopped strand mats.
摘要翻译：提供了含有含蛋白质的生物质和pH调节剂的水性粘合剂组合物。任选地，交联剂和/或防潮剂可以包括在粘合剂组合物中。含蛋白质的生物质是天然的，可以来自植物或动物来源。 pH调节剂用于将粘合剂的pH调节到所需的pH并降低基于蛋白质的生物质的粘度。此外，pH调节剂可以用作交联剂。当防粘剂存在于粘合剂中时，交联剂可以是任何适于交联含蛋白质的生物质并与防潮剂反应的化合物。此外，粘合剂在固化后具有浅色。环保的无甲醛粘合剂可用于形成绝缘材料和无纺短切纤维垫。

8. 发明申请

US20110200814A1 BIOCIDES FOR BIO-BASED BINDERS, FIBROUS INSULATION PRODUCTS AND WASH WATER SYSTEMS 有权
标题翻译：用于生物基础粘合剂，纤维隔离产品和洗涤水系统的生物
公开(公告)号：US20110200814A1
公开(公告)日：2011-08-18
申请号：US13026415
申请日：2011-02-14
申请人： Jesus M. Hernandez-Torres , Liang Chen , William R. Cooper
发明人： Jesus M. Hernandez-Torres , Liang Chen , William R. Cooper
IPC分类号： B32B5/02 , C09D5/14 , E04B1/74
CPC分类号： C03C25/26 , A01N25/04 , A01N25/34 , C03C25/1095 , C03C25/146 , C03C25/285 , C03C25/321 , C08K5/0058 , C08L33/02 , C09J103/02 , C09J105/06 , Y10T428/249924 , C08K5/092 , A01N35/08 , A01N41/10 , A01N43/80 , A01N47/12 , A01N59/00
摘要： Biocides for bio-based binder compositions are disclosed. Bio-based binders include those having a nutrient source such as carbohydrate, protein or fat, which can serve as an energy source for organisms to grow in areas that contact binder. Principal areas that contact bio-based binder in a fiberglass insulation manufacturing process include the raw ingredients, the binder chemicals, the prepared binder dispersions, the forming hood and related equipment, the final insulation product and, importantly, the cleaning systems and washwater arising from cleaning the manufacturing equipment and/or forming the product. Frequently the washwater is stored until re-cycled for re-use. Storage may take place in tanks, towers, vats and even outdoor reservoirs, all of which may harbor the growth of unwanted organisms, for which a biocide is desirable.
摘要翻译：公开了用于生物基粘合剂组合物的杀生物剂。生物基粘合剂包括具有诸如碳水化合物，蛋白质或脂肪的营养源的那些，其可以用作生物体在接触粘合剂的区域中生长的能量来源。在玻璃纤维绝缘制造过程中与生物基粘合剂接触的主要领域包括原料，粘合剂化学品，制备的粘合剂分散体，成型罩和相关设备，最终的隔热产品，以及重要的是，清洁系统和洗涤水清洁制造设备和/或形成产品。洗涤水通常被储存直到重新循环再次使用。储存可能发生在坦克，塔，大桶甚至室外水库中，所有这些都可能存在不想要的生物体的生长，对此，生物杀伤剂是可取的。

9. 发明申请

US20120168054A1 USE OF SILICONES TO IMPROVE FIBERGLASS INSULATION PRODUCTS 审中-公开
标题翻译：使用硅胶改善纤维绝缘产品
公开(公告)号：US20120168054A1
公开(公告)日：2012-07-05
申请号：US13338316
申请日：2011-12-28
申请人： Liang Chen , William E. Downey , Jesus M. Hernandez-Torres , Ying Peng , Jonathan Davis
发明人： Liang Chen , William E. Downey , Jesus M. Hernandez-Torres , Ying Peng , Jonathan Davis
IPC分类号： B32B37/12 , B32B37/14 , B05D3/00 , B05D5/00 , B32B37/00
CPC分类号： C03C25/26 , B32B2607/00 , C03C25/40 , C08L83/00 , C09J103/02
摘要： Dispersions of reactive polysiloxanes are applied to fibrous products, such as construction panels to provide improved properties, like better resistance to staining and discoloration and better adhesion of facer layers The reactive polysiloxane may be applied directly to the fibrous product or mixed into binder compositions prior to application; and may be applied substantially uniformly or non-uniformly. The construction panels may form wall and/or ceiling panels. The reactive polysiloxane may include polysiloxanes functionalized with any of hydrogen, amino, hydroxyl or carboxyl reactive functionalities.
摘要翻译：反应性聚硅氧烷的分散体应用于纤维制品，例如建筑面板，以提供改进的性能，如更好的抗染色和变色性能以及更好的粘合层。反应性聚硅氧烷可以直接施加到纤维制品上，或者在应用; 并且可以基本均匀地或不均匀地施加。建筑面板可以形成墙壁和/或天花板面板。反应性聚硅氧烷可以包括用氢，氨基，羟基或羧基反应性官能团中的任何一种官能化的聚硅氧烷。

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