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    • 5. 发明申请
    • 2-OXO-1,3-DIOXOLANE-4-CARBOXAMIDE BUILDING BLOCKS, THEIR PREPARATION AND USE
    • 2-氧代-1,3-二氧杂环戊烷-4-羧酰胺大块块,其制备和使用
    • US20150353521A1
    • 2015-12-10
    • US14760834
    • 2014-01-30
    • CONSTRUCTION RESEARCH & TECHNOLOGY GMBH
    • Heimo WÖLFLEBurkhard WALTHERSophie PUTZIEN
    • C07D317/38
    • C07D317/38
    • The present invention suggests a 2-oxo-1,3-dioxolane-4-carboxamide of formula (I), wherein R is an n-valent radical, n is an integer from 2 to 4, preferably from 2 to 3, and x is an integer from 1 to n−1. The invention furthermore suggests a process for the preparation of the 2-oxo-1,3-dioxolane-4-carboxamide of formula (I) from 2-oxo-1,3-dioxolane-4-carboxylic acid of formula (II) with a polyisocyanate of the formula R(NCO)n, where R and n have the meanings given, the use of the 2-oxo-1,3-dioxolane-4-carboxamide of formula (I) for the preparation of a 2-oxo-1,3-dioxolane-4-carboxamide-substituted prepolymer, and the 2-oxo-1,3-dioxolane-4-carboxamide-substituted prepolymer thus obtainable.
    • 本发明提出式(I)的2-氧代-1,3-二氧戊环-4-甲酰胺,其中R为n价基团,n为2至4的整数,优选为2至3,x 是从1到n-1的整数。 本发明还提出了从式(II)的2-氧代-1,3-二氧戊环-4-羧酸制备式(I)的2-氧代-1,3-二氧戊环-4-甲酰胺的方法,其中 式R(NCO)n的多异氰酸酯,其中R和n具有给定的含义,式(I)的2-氧代-1,3-二氧戊环-4-甲酰胺用于制备2-氧代 -1,3-二氧戊环-4-甲酰胺取代的预聚物和由此获得的2-氧代-1,3-二氧戊环-4-甲酰胺取代的预聚物。
    • 8. 发明申请
    • 2-HYDROXYETHYL 2-OXO-1,3-DIOXOLANE-4-CARBOXYLATES, THEIR PREPARATION AND USE
    • 2-羟基乙氧基-2-氧代-1,3-二氧戊环-4-羧酸酯,其制备和使用
    • US20170008871A1
    • 2017-01-12
    • US15121098
    • 2015-02-20
    • CONSTRUCTION RESEARCH & TECHNOLOGY GMBH
    • Sophie PUTZIENBurkhard WALTHERMaximilian KOHLER
    • C07D317/38C08G71/04
    • C07D317/38C08G71/04
    • 2-hydroxyethyl 2-oxo-1,3-dioxolane-4-carboxylates of formula (I): wherein one of R1 and R2 can be hydrogen. R1 and R2, if not hydrogen, and in each case independently of one another, are selected from straight-chain, branched or cyclic C1-22-alkyl groups, preferably C1-12-alkyl groups, C6-12-aryl groups, C6-18-aralkyl groups and C6-18-alkaryl groups, wherein R1 and/or R2, in each case independently of one another, may comprise at least one additional functional group, selected from hydroxyl groups, ether groups, ester groups, epoxy groups, and double bonds, and wherein R2 may be substituted with up to 10, preferably with 1 to 5, and in particular with 1 or 2 further 2-hydroxyethyl 2-oxo-1,3-dioxolane-4-carboxylic groups. The 2-hydroxyethyl 2-oxo-1,3-dioxolane-4-carboxylates can be prepared by reacting 2-oxo-1,3-dioxolane-4-carboxylic acid with epoxides and can be used for the preparation of hydroxyurethanes through reaction with amines, such as amine hardeners. Moreover, they can also be used as end groups for the blocking of amines.
    • 其中R1和R2之一可以是氢。 R 1和R 2如果不是氢,并且在每种情况下彼此独立地选自直链,支链或环状的C 1-22烷基,优选C 1-12 - 烷基,C 6-12 - 芳基,C 6 -18-芳烷基和C 6-18烷芳基,其中R 1和/或R 2在每种情况下彼此独立地可以包含至少一个选自羟基,醚基,酯基,环氧基团的另外的官能团 和双键,并且其中R 2可以被至多10个,优选1至5个,特别是1或2个2-羟乙基2-氧代-1,3-二氧戊环-4-羧基取代。 2-氧代-1,3-二氧戊环-4-羧酸2-羟乙酯可以通过2-氧代-1,3-二氧戊环-4-羧酸与环氧化物反应来制备,可用于通过与 胺,如胺硬化剂。 此外,它们也可以用作封端胺的端基。