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    • 3. 发明授权
    • Epoxy resins which are glycidyl ethers of glycerine
    • 作为甘油缩水甘油醚的环氧树脂
    • US3878132A
    • 1975-04-15
    • US42855673
    • 1973-12-26
    • DOW CHEMICAL CO
    • BERTRAM JAMES LBOWEN DAVID O
    • C08G59/04C08G59/14C08G59/22C08G59/38C08G59/62C08G30/02
    • C08G59/04C08G59/145C08G59/226C08G59/38C08G59/62Y10T428/31511
    • Epoxy resins which are glycidyl ethers of glycerine having improved physical properties, when cured to a thermoset condition, are the dehydrohalogenated reaction products of A. a mixture comprising from 0 to 49 percent by weight of a polyhydroxyl containing compound, such as polyglycerol, and from about 51 to 100 percent by weight of glycerine with B. a mixture comprising (1) 0.05 to 0.65 epoxy equivalents per mole of A of a polyepoxide, such as the diglycidyl ether of bisphenol A, and (2) from 1.35 to 2.95 epoxy equivalents per mole of A of an epoxy alkyl halide such as epichlorohydrin. When such products are cured with a catalytic quantity of a tertiary amine, they exhibit improved physical properties such as tensile strength, elongation, or tensile modulus.
    • 当固化成热固性条件时,具有改善的物理性能的甘油缩水甘油醚的环氧树脂是A.含有0至49重量%的含多羟基化合物如聚甘油的混合物的脱卤化氢反应产物, 约51至100重量%的甘油与B.一种混合物,其包含(1)0.05至0.65环氧当量/摩尔A的聚环氧化物,例如双酚A的二缩水甘油醚,和(2)1.35至2.95环氧当量 每摩尔A的环氧烷基卤化物如表氯醇。 当这些产物用催化量的叔胺固化时,它们表现出改善的物理性能,例如拉伸强度,伸长率或拉伸模量。