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1. 发明授权

US3882009A Electrodeposition of isothiouronium stabilized lyophobic colloids 失效
标题翻译：异硫脲稳定的疏液胶体的电沉积
公开(公告)号：US3882009A
公开(公告)日：1975-05-06
申请号：US39270073
申请日：1973-08-29
申请人： DOW CHEMICAL CO
发明人： WAGENER EARL H , WESSLING RITCHIE A , GIBBS DALE S
IPC分类号： C09D5/44 , B01K5/02
CPC分类号： C09D5/4407
摘要： A method for electrodeposition of an organic material on an electroconductive surface comprising placing the electroconductive surface to be coated in contact with an aqueous dispersion containing a water-insoluble, essentially electrically non-conductive, film-forming, organic polymer as cation-active particles wherein a substantial portion of the cation-activity is provided by isothiouronium cations and passing an electric current from an electrode through the latex to the electroconductive surface in such a direction that the electroconductive surface is negatively charged, i.e., becomes a cathode in an electrophoretic cell. By use of alternating current both electrodes become coated with the polymer.
摘要翻译：一种用于在导电表面上电沉积有机材料的方法，包括将待涂覆的导电表面放置在与包含不溶于水的基本上不导电的成膜有机聚合物的水性分散体接触，所述有机材料作为阳离子活性颗粒，其中阳离子活性的很大一部分由异硫脲阳离子提供，并将电流从电极通过胶乳传递到导电表面，使得导电表面带负电，即在电泳池中成为阴极。通过使用交流电，两个电极都被聚合物涂覆。

2. 发明授权

US3649483A Process for producing bisorganomercury compounds by the electroreduction of sulfonium compounds 失效
标题翻译：通过磺化合物的电解生产双酚甘油化合物的方法
公开(公告)号：US3649483A
公开(公告)日：1972-03-14
申请号：US3649483D
申请日：1969-12-02
申请人： DOW CHEMICAL CO
发明人： SETTINERI WILLIAM J , WESSLING RITCHIE A
IPC分类号： C07F3/10 , C07B29/06
CPC分类号： C07F3/106
摘要： BISORGANOMERCURY COMPOUNDS HAVING THE STRUCTURAL FORMULA

(((X)N-PHENYL)-CH2-)2-HG

WHEREIN N IS AN INTEGER OF FROM 0 TO 5 AND X IS AN INERT, SUBSTANTIALLY NON-INTERFERING SUBSTITUENT, ARE PREPARED BY SUBJECTING A BENZYLSULFONIUM SALT IN AN ELECTROLYSIS SOLVENT TO AN ELECTRICAL POTENTIAL SUFFICIENT TO REDUCE THE SULFONIUM SALT; THE SULFONIUM SALT HAS THE FORMULA

((X)N-PHENYL)-CH2-S(+)(-R1)-R2 A(-)

WHEREIN N AND X ARE AS DEFINED ABOVE, R1 AND R2 ARE ALKYL OR HYDROXYALKYL GROUPS AND A$ IS AN ELECTROLYTICALLY ACCEPTABLE ANION. THE REDUCTION OCCURS ON A MERCURY CATHODE, WHICH IS CONSUMED IN THE REACTION. THE PRODUCTS ARE USEFUL AS CATALYST FOR FREE RADICAL INITIATED POLYMERIZATIONS. IN EXAMPLE, DIBENZYLMERCURY WAS PREPARED BY SUBJECTING AN AQUEOUS SOLUTION OF BENZYLDIMETHYLSULFONIUM CHLORIDE TO A CATHODE POTENTIAL OF ABOUT -1.0 VOLTS VS. A SATURATED CALOMEL ELECTRODE.

3. 发明授权

US3480527A Process for producing p,p'-dinitrobibenzyl compounds by the electroreduction of sulfonium compounds 失效
标题翻译：通过磺化合物的电解制备P，P'-四苯甲基化合物的方法
公开(公告)号：US3480527A
公开(公告)日：1969-11-25
申请号：US3480527D
申请日：1967-06-22
申请人： DOW CHEMICAL CO
发明人： WESSLING RITCHIE A , SETTINERI WILLIAM J
IPC分类号： C25B3/04 , B01K1/00
CPC分类号： C25B3/04

4. 发明授权

US3404132A Novel polymer compositions and method 失效
标题翻译：新型聚合物组合物和方法
公开(公告)号：US3404132A
公开(公告)日：1968-10-01
申请号：US61783467
申请日：1967-02-23
申请人： DOW CHEMICAL CO
发明人： WESSLING RITCHIE A , ZIMMERMAN RAY G
IPC分类号： C08G61/02
CPC分类号： C08G61/02

5. 发明授权

US3873488A Latexes for cathodic electrocoating 失效
标题翻译：阴极电动机的使用寿命
公开(公告)号：US3873488A
公开(公告)日：1975-03-25
申请号：US43010574
申请日：1974-01-02
申请人： DOW CHEMICAL CO
发明人： GIBBS DALE S , WAGENER EARL H , WESSLING RITCHIE A
IPC分类号： C08F28/00 , C08F236/04 , C09D5/44 , C08D7/00 , C09D5/02
CPC分类号： C09D5/4407 , C08F28/00 , C08F236/04 , Y10S524/901
摘要： Aqueous dispersions particularly adapted for cationic electrodeposition are provided by copolymerizing a small portion of a water-soluble, polymerizable, ethylenically unsaturated sulfonium salt such as vinylbenzyl dimethyl sulfonium chloride with an ethylenically unsaturated essentially hydrophobic monomer, for example, n-butyl acrylate or a mixture of such monomers, for example, styrene and butadiene or n-butyl acrylate and methyl methacrylate. A small amount of a conventional cationic or non-ionic surfactant may be included.
摘要翻译：特别适用于阳离子电沉积的水性分散体是通过将一小部分水溶性，可聚合的烯属不饱和锍盐如乙烯基苄基二甲基氯化锍与烯属不饱和基本上疏水的单体，例如丙烯酸正丁酯或混合物的这种单体，例如苯乙烯和丁二烯或丙烯酸正丁酯和甲基丙烯酸甲酯。可以包括少量常规的阳离子或非离子表面活性剂。

6. 发明授权

US3706677A Polyxylylidene articles 失效
标题翻译：多晶硅胶制品
公开(公告)号：US3706677A
公开(公告)日：1972-12-19
申请号：US3706677D
申请日：1970-10-05
申请人： DOW CHEMICAL CO
发明人： WESSLING RITCHIE A , ZIMMERMAN RAY G
IPC分类号： C08G61/02 , C08J9/02 , C08J9/26 , C08F47/00
CPC分类号： C08J9/26 , C08G61/02 , C08J9/02 , C08J2365/00 , Y10T428/269 , Y10T428/2913 , Y10T428/31645 , Y10T428/31678 , Y10T428/31692 , Y10T428/31989 , Y10T428/31993
摘要： THE COMPOSITIONS ARE OF THE CLASS OF POLYXYLYLIDENE HAVING A HIGH DEGREE OF POLYMERIZATION IN THE FORM OF COATINGS, FILMS, FIBERS OR FOAMS. SUCH ARTICLES ARE PREPARED FROM POLYELECTROLYTES COMPRISING VISCOUS AQUEOUS SOLUTIONS OF P-PHENYLENE DIMETHYLENE BIS(DIALKYL SULFONIUM SALTS), OR THE ANALOGOUS HYDROXIDE, BY SHAPING SUCH VISCOUS AQUEOUS SOLUTIONS, FOR EXAMPLE BY CASTING A WET FILM OR EXTRUDING THE SOLUTION INTO A BASIC AQUEOUS BATH, THEN DRYING, SOMETIMES WITH HEATING, TO CONVERT THE SOLFONIUM POLYELECTROLYTE TO A POLYXYLYLIDENE IN THE FORM OF A FILM, COATING, FIBER OR FOAM.

7. 发明授权

US3697398A Process for electrolytically applying polymer coatings on electroconductive articles 失效
标题翻译：电聚合涂层在电极材料上的电化学工艺
公开(公告)号：US3697398A
公开(公告)日：1972-10-10
申请号：US3697398D
申请日：1971-07-06
申请人： DOW CHEMICAL CO
发明人： WESSLING RITCHIE A , SETTINERI WILLIAM J
IPC分类号： C09D5/44 , C23B5/00 , B01K1/00 , B01K5/00
CPC分类号： C09D5/4488
摘要： HYDROPHOBIC POLYMER COATINGS ARE APPLIED TO SOLID ELECTROCONDUCTIVE ARTICLES BY SUBJECTING A POLYSULFONIUM SALT IN SOLUTION IN AN ELECTROLYSIS SOLVENT TO AN ELECTRICAL POTENTIAL SUFFICIENT TO REDUCE THE SULFONIUM SALT. THE SOLID ELECTROCONDUCTIVE ARTICLES ARE USED AS THE CATHODE IN THE ELECTROLYSIS PROCESS. IN EXAMPLE, A LEAD ELECTRODE IS COATED WITH POLY(P-XYLYLENE) BY ELECTROLYZING AN AQUEOUS SOLUTION OF (P-PHENYLENEDIMETHYLENE)BIS(DIMETHYLSULFONIUM CHLORIDE).

8. 发明授权

US3401152A Polyelectrolytes from bis sulfonium salts 失效
标题翻译：来自双锍盐的聚电解质
公开(公告)号：US3401152A
公开(公告)日：1968-09-10
申请号：US59170666
申请日：1966-11-03
申请人： DOW CHEMICAL CO
发明人： WESSLING RITCHIE A , ZIMMERMAN RAY G
IPC分类号： C08G61/02
CPC分类号： C08G61/02

9. 发明授权

US3917574A Process for preparing substantially linear water-soluble or water-dispersible interpolymeric interfacially spreading polyelectrolytes 失效
标题翻译：制备基本上线性的水溶性或水分散性共聚物界面扩散聚电解质的方法
公开(公告)号：US3917574A
公开(公告)日：1975-11-04
申请号：US35171473
申请日：1973-04-16
申请人： DOW CHEMICAL CO
发明人： GIBBS DALE S , SIMONS PAUL B , VANDELL ROBERT D , WESSLING RITCHIE A
IPC分类号： C08F2/06 , C08F2/22 , C08F2/26 , C08F1/13 , C08F7/04 , C08F15/00
CPC分类号： C08F2/06 , C08F2/26
摘要： A process for preparing a substantially linear water-soluble or water-dispersible interpolymeric interfacially spreading polyelectrolyte wherein 1. THE POLYELECTROLYTE IS COMPOSED OF A MIXTURE OF NONIONIC HYDROPHOBIC UNITS AND IONIC HYDROPHILIC UNITS WHEREIN THE NONIONIC HYDROPHOBIC UNITS ARE RANDOMLY DISTRIBUTED IN THE BACKBONE OF THE POLYELECTROLYTE AND 2. THE POLYELECTROLYTE WHEN INCORPORATED INTO A DISPERSION IS ADSORBED AT THE DISPERSE PHASE OF THE DISPERSION IN A SUBSTANTIALLY FLAT CONFIGURATION AND WHERE THE AREA OCCUPIED BY EACH IONIC HYDROPHILIC UNIT OF THE POLYELECTROLYTE AT THE DISPERSE PHASE SURFACE IS FROM ABOUT 60 TO 100 SQUARE Angstrom units per ionic hydrophilic unit, and wherein the polyelectrolyte has an adsorption constant equal to or greater than 1 at the point where the disperse phase is saturated with the polyelectrolyte, the process comprising: the homogeneous continuous monomer addition polymerization of at least one ionic hydrophilic monomer and at least one nonionic hydrophobic monomer in a polar mutual solvent therefore wherein the monomers are added to a polymerization reactor at a rate no greater than the rate of polymerization and in a ratio which is substantially equal to that desired in the resulting polymer phase.
摘要翻译：一种制备基本上线性的水溶性或水分散性共聚物界面扩散聚电解质的方法，其中1.聚电解质是由非离子性疏水单体和非离子性疏水单体组成的非离子疏水单体在聚电解质的背胶中随机分布和2.当分散在分散体中的聚电解质在主要平面配置的分散相中被分散，并且分散相表面上的聚电解质的每个离子水解单元所占据的面积从约60到100平方厘米单位每离子亲水单元，并且其中所述聚电解质在所述分散相被所述聚电解质饱和的点处具有等于或大于1的吸附常数，所述方法包括：至少一种离子亲水单体的均匀连续单体加成聚合和至少一个不在极性相互溶剂中的阴离子疏水单体，其中单体以不大于聚合速率的速率加入到聚合反应器中，并且其比例基本上等于所得聚合物相中所需的比例。

10. 发明授权

US3681419A Process for producing bisorganomercury compounds 失效
标题翻译：生产异烟肼化合物的方法
公开(公告)号：US3681419A
公开(公告)日：1972-08-01
申请号：US3681419D
申请日：1970-04-13
申请人： DOW CHEMICAL CO
发明人： SETTINERI WILLIAM J , WESSLING RITCHIE A
IPC分类号： C07F3/10 , C08F4/12 , C07F3/12
CPC分类号： C07F3/106 , C08F4/12
摘要： Bisorganomercury compounds having the formula

WHEREIN N IS AN INTEGER OF FROM 0 TO 5 AND X is an inert, substantially non-interfering substituent, are prepared by contacting an alkali metal amalgam with a sulfonium salt of the formula

WHEREIN X and n are as defined above, R1 and R2 are alkyl groups or R1 joins with R2 to form a cycloaliphatic group, or the corresponding hydroxy-substituted alkyl or cycloaliphatic groups, and A- is an anion. The reaction is preferably conducted in an aqueous solution. The bisorganomercury compounds are useful as catalysts for free-radical-initiated polymerizations and as fungicides, insecticides, and the like.
摘要翻译：通过使碱金属汞齐与式WHEREIN X和n如上定义的锍盐接触来制备具有下式的双有机汞化合物：其中N为0至5的整数，X为惰性的，基本上不干扰的取代基 R1和R2是烷基或R1与R2连接以形成脂环族基团，或相应的羟基取代的烷基或脂环族基团，并且A（ - ）是阴离子。反应优选在水溶液中进行。双有机汞化合物可用作自由基引发聚合的催化剂和杀真菌剂，杀虫剂等。

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