会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 1. 发明申请
    • Polymerization method for acrylic latex without emulisifier
    • 不含乳化剂的丙烯酸乳胶聚合方法
    • US20120095163A1
    • 2012-04-19
    • US13067902
    • 2011-07-06
    • Der-Jang LIAWChih-Kuang HUChih-Wei CHANG
    • Der-Jang LIAWChih-Kuang HUChih-Wei CHANG
    • C08L33/10C08L33/12
    • C08F2/22C08F2/18
    • The present invention provides a polymerization method for acrylic latex without emulsifier, in which a reaction system is formed from 40˜60 wt % of pure water and 2˜9 wt % of carboxylic acid monomers with carbon-carbon double bond polymerizable functional groups (A), and 40˜50 wt % of methyl methacrylate or acrylate monomers (B), and 0.2˜2.0 wt % of inorganic alkaline solution is first used to adjust the pH value of the reaction system to within a pH range of 9.0˜13.0, then 0.2˜1.0 wt % of peroxide sulfates are used as initiators, and emulsification polymerization is carried out. At the end of the reaction, organic amine compounds are used to adjust the pH value of the obtained aqueous resin latex to within the pH range 7.0˜9.5. Particle diameters of the manufactured aqueous resin latex are approximately 100˜30 nm, uniformly distributed and have excellent outward appearance. Moreover, acid value is low at 3.5˜6.5 mgKOH/g, and Its specific gravity is approximately 1.07, slightly greater than that of water; storage stability is excellent, with good permeability that facilitates construction. Moreover, water resisting property as a dry film coating is good, tensile strength is excellent, and provides superior abrasion performance.
    • 本发明提供了一种不含乳化剂的丙烯酸胶乳的聚合方法,其中反应体系由40〜60重量%的纯水和2〜9重量%的具有碳 - 碳双键聚合官能团的羧酸单体(A ),40〜50重量%的甲基丙烯酸甲酯或丙烯酸酯单体(B)和0.2〜2.0重量%的无机碱性溶液首先用于将反应体系的pH值调节至9.0〜13.0的pH范围内, 然后使用0.2〜1.0重量%的过氧化物硫酸盐作为引发剂,进行乳化聚合。 在反应结束时,使用有机胺化合物将所得水性树脂胶乳的pH值调节至7.0〜9.5的pH范围。 制造的水性树脂胶乳的粒径为约100〜30nm,均匀分布,外观优异。 此外,酸值低于3.5〜6.5 mgKOH / g,比重约为1.07,略高于水; 储存稳定性好,渗透性好,便于施工。 此外,作为干膜涂膜的耐水性良好,拉伸强度优异,并且提供优异的耐磨性能。