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1. 发明授权

US10562833B2 Method for obtaining alcohols from aldehydes III 有权
公开(公告)号：US10562833B2
公开(公告)日：2020-02-18
申请号：US16204263
申请日：2018-11-29
申请人： Evonik Degussa GmbH
发明人： Dirk Fridag , Robert Franke , Michael Grass , Florian Boeck , Corinna Hecht , Benedikt Dercks , Udo Lenz , Christoph Hiller , Christoph Ehlers , Stefan Münzner
IPC分类号： C07C29/141 , C07C29/17 , B01J31/18 , C07C45/82 , C07C45/74 , C07C29/82 , C07C29/80 , C07C45/50 , C07C31/12 , C07C31/125 , C07C47/02 , C07C47/21
摘要： The present invention relates to a method for preparing saturated Cn- and C2n-alcohols, wherein the ratio of Cn- to C2n-alcohols is controlled by a distillative separation of the aldehydes used.

2. 发明授权

US10519090B2 Process for Pd-catalyzed hydroxycarbonylation of diisobutene: acetic acid/diisobutene ratio 有权
公开(公告)号：US10519090B2
公开(公告)日：2019-12-31
申请号：US16216053
申请日：2018-12-11
申请人： EVONIK DEGUSSA GMBH
发明人： Rui Sang , Peter Kucmierczyk , Kaiwu Dong , Ralf Jackstell , Matthias Beller , Robert Franke
IPC分类号： C07C51/14 , C07C53/00 , B01J31/00 , B01J31/22 , B01J31/24 , B01J31/30 , C07C53/126
摘要： Process for Pd-catalyzed hydroxycarbonylation of diisobutene:acetic acid/diisobutene ratio.

3. 发明申请

US20190283004A1 OLIGOMERIZATION CATALYST AND PROCESS FOR THE PRODUCTION THEREOF 审中-公开
公开(公告)号：US20190283004A1
公开(公告)日：2019-09-19
申请号：US16293859
申请日：2019-03-06
申请人： Evonik Degussa GmbH
发明人： Fabian Nadolny , Stephan Peitz , Guido Stochniol , Robert Franke , Thomas Quandt
IPC分类号： B01J23/755 , B01J35/10 , C07C2/10 , B01J35/02
摘要： The invention relates to an oligomerization catalyst comprising nickel oxide and silica-alumina support material and to a process for oligomerization of C3- to C6-olefins using the oligomerization catalyst.

4. 发明授权

US10294191B2 Monophosphine compounds and palladium catalysts based thereon for the alkoxycarbonylation of ethylenically unsaturated compounds 有权
公开(公告)号：US10294191B2
公开(公告)日：2019-05-21
申请号：US15213449
申请日：2016-07-19
申请人： EVONIK DEGUSSA GMBH
发明人： Kaiwu Dong , Ralf Jackstell , Matthias Beller , Robert Franke , Dieter Hess , Katrin Marie Dyballa , Dirk Fridag , Frank Geilen
IPC分类号： C07F15/00 , C07F9/28 , B01J27/185 , C07C67/38 , C07F9/58 , C07F9/572 , C07F9/6506 , B01J31/24 , B01J31/22 , C07F9/655 , C07F9/6553 , C07F17/02
摘要： The invention relates to compounds of formula (I) where R1 is selected from —(C1-C12)-alkyl, —(C3-C12)-cycloalkyl, —(C3-C12)-heterocycloalkyl; R2 is selected from —(C3-C12)-heterocycloalkyl, —(C6-C20)-aryl, —(C3-C20)-heteroaryl; R3 is —(C3-C20)-heteroaryl; and R1, R2 and R3 may each independently be substituted by one or more substituents selected from —(C1-C12)-alkyl, —(C3-C12)-cycloalkyl, —(C3-C12)-heterocycloalkyl, —O—(C1-C12)-alkyl, —O—(C1-C12)-alkyl-(C6-C20)-aryl, —O—(C3-C12)-cycloalkyl, —S—(C1-C12)-alkyl, —S—(C3-C12)-cycloalkyl, —COO—(C1-C12)-alkyl, —COO—(C3-C12)-cycloalkyl, —CONH—(C1-C12)-alkyl, —CONH—(C3-C12)-cycloalkyl, —CO—(C1-C12)-alkyl, —COO—(C3-C12)-cycloalkyl, —N—[(C1-C12)-alkyl]2, —(C6-C20)-aryl, —(C6-C20)-aryl-(C1-C12)-alkyl, —(C6-C20)-aryl-O—(C1-C12)-alkyl, —(C3-C20)-heteroaryl, —(C3-C20)-heteroaryl-(C1-C12)-alkyl, —(C3-C20)-heteroaryl-O—(C1-C12)-alkyl, —COOH, —OH, —SO3H, —NH2, halogen. The invention further relates to Pd complexes comprising the compound according to the invention and to the use thereof in alkoxycarbonylation.

5. 发明授权

US10227278B2 Economical production of 2-propylheptanol 有权
公开(公告)号：US10227278B2
公开(公告)日：2019-03-12
申请号：US15773613
申请日：2016-08-02
申请人： Evonik Degussa GmbH
发明人： Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Markus Schwarz , Hermann-Josef Schulte-Althoff , Frank Geilen
IPC分类号： C07C45/50 , C07C47/02 , C07C29/17 , C07C29/14 , C07C47/21 , B01J31/02 , B01J31/18
摘要： The production of 2-propylheptanol described here is effected via Rh-catalyzed hydroformylation of C4-olefin to afford C5-aldehyde, aldol condensation to afford the C10-aldehyde and hydrogenation to afford the C10-alcohol. The emphasis is on the hydroformylation and the ligand employed therein. The problem addressed by the invention is that of reducing the costs of 2PH production. This problem is solved when a cheaper catalyst system which simultaneously achieves a better regioselectivity is employed in the hydroformylation. This catalyst system contains rhodium as the central atom and is complexed with the ligand (1):

6. 发明授权

US10202329B2 Ferrocene-based compounds and palladium catalysts based thereon for the alkoxycarbonylation of ethylenically unsaturated compounds 有权
公开(公告)号：US10202329B2
公开(公告)日：2019-02-12
申请号：US15213453
申请日：2016-07-19
申请人： EVONIK DEGUSSA GMBH
发明人： Kaiwu Dong , Helfried Neumann , Ralf Jackstell , Matthias Beller , Robert Franke , Dieter Hess , Katrin Marie Dyballa , Dirk Fridag , Frank Geilen
IPC分类号： C07F9/58 , C07C67/38 , C07F9/572 , C07F9/6506 , C07F15/00 , B01J31/24 , B01J31/22 , C07F9/655 , C07F9/6553 , C07F17/02
摘要： The invention relates to a compound of formula (I) where R1 and R3 are each a heteroaryl radical having five ring atoms, R2 and R4 are each independently selected from —(C1-C12)-alkyl, —(C3-C12)-cycloalkyl, —(C3-C12)-heterocycloalkyl, —(C6-C20)-aryl; R1 and R3 may each independently be substituted by one or more substituents selected from —(C1-C12)-alkyl, —(C3-C12)-cycloalkyl, —(C3-C12)-heterocycloalkyl, —O—(C1-C12)-alkyl, —O—(C1-C12)-alkyl-(C6-C20)-aryl, —O—(C3-C12)-cycloalkyl, —S—(C1-C12)-alkyl, —S—(C3-C12)-cycloalkyl, —COO—(C1-C12)-alkyl, —COO—(C3-C12)-cycloalkyl, —CONH—(C1-C12)-alkyl, —CONH—(C3-C12)-cycloalkyl, —CO—(C1-C12)-alkyl, —CO—(C3-C12)-cycloalkyl, —N—[(C1-C12)-alkyl]2, —(C6-C20)-aryl, —(C6-C20)-aryl-(C1-C12)-alkyl, —(C6-C20)-aryl-O—(C1-C12)-alkyl, —(C3-C20)-heteroaryl, —(C3-C20)-heteroaryl-(C1-C12)-alkyl, —(C3-C20)-heteroaryl-O—(C1-C12)-alkyl, —COOH, —OH, —SO3H, —NH2, halogen; and R2 and R4, if they are —(C1-C12)-alkyl, —(C3-C12)-cycloalkyl, —(C3-C12)-heterocycloalkyl or —(C6-C20)-aryl, may each independently be substituted by one or more substituents selected from —(C1-C12)-alkyl, —(C3-C12)-cycloalkyl, —(C3-C12)-heterocycloalkyl, —O—(C1-C12)-alkyl, —O—(C1-C12)-alkyl-(C6-C20)-aryl, —O—(C3-C12)-cycloalkyl, —S—(C1-C12)-alkyl, —S—(C3-C12)-cycloalkyl, —COO—(C1-C12)-alkyl, —COO—(C3-C12)-cycloalkyl, —CONH—(C1-C12)-alkyl, —CONH—(C3-C12)-cycloalkyl, —CO—(C1-C12)-alkyl, —CO—(C3-C12)-cycloalkyl, —N—[(C1-C12)-alkyl]2, —(C6-C20)-aryl, —(C6-C20)-aryl-(C1-C12)-alkyl, —(C6-C20)-aryl-O—(C1-C12)-alkyl, —(C3-C20)-heteroaryl, —(C3-C20)-heteroaryl-(C1-C12)-alkyl, —(C3-C20)-heteroaryl-O—(C1-C12)-alkyl, —COOH, —OH, —SO3H, —NH2, halogen; excluding the compounds of the formulae (1) and (2) The invention further relates to precursors for preparation of the compound according to the invention, to Pd complexes comprising the compound according to the invention and to the use thereof in alkoxycarbonylation.

7. 发明授权

US10155200B2 Separation off of a homogeneous catalyst from a reaction mixture with the help of organophilic nanofiltration 有权
公开(公告)号：US10155200B2
公开(公告)日：2018-12-18
申请号：US15040058
申请日：2016-02-10
申请人： Evonik Degussa GmbH
发明人： Frank Geilen , Robert Franke , Bart Hamers
IPC分类号： B01D19/00 , B01D61/02 , B01D71/70 , B01D61/12 , B01J31/40 , G06F17/10 , G06F17/50
摘要： The invention deals with the separation of homogeneous catalysts from reaction mixtures with the help of organophilic nanofiltration. It is based on the object of indicating an option as to how organophilic nanofiltration can be used economically for separating off homogeneous catalysts from reaction mixtures if the separation-active material of the membrane satisfying the separation aim is not available in sufficiently large amounts or only at high cost. This object is achieved by taking into consideration a particular membrane performance indicator during the design and/or the execution of the corresponding membrane separation process.

8. 发明授权

US10106497B2 Coupling of two arenes with selenium dioxide to give a selenobiaryl ether 有权
公开(公告)号：US10106497B2
公开(公告)日：2018-10-23
申请号：US15157934
申请日：2016-05-18
申请人： EVONIK DEGUSSA GMBH
发明人： Katrin Marie Dyballa , Robert Franke , Siegfried R Waldvogel , Thomas Quell , Michael Mirion
IPC分类号： C07C391/02
摘要： The present invention relates to a method for coupling two arenes with selenium dioxide to give a selenobiaryl ether. The method of the present invention includes: adding a first arene to the reaction mixture, adding a second arene to the reaction mixture, adding selenium dioxide to the reaction mixture, adding an acid having a pKa in the range from 0 to 5 to the reaction mixture, and adjusting the reaction temperature of the reaction mixture such that the first arene and the second arene are converted to a selenobiaryl ether. The present invention also relates to novel selenobiaryl ethers.

9. 发明授权

US10000440B2 Influencing the viscosity of N-butene-based ester mixtures by controlled use of ethene in the preparation of the ester precursors 有权
公开(公告)号：US10000440B2
公开(公告)日：2018-06-19
申请号：US15356507
申请日：2016-11-18
申请人： Evonik Degussa GmbH
发明人： Helene Reeker , Guido Stochniol , Dietrich Maschmeyer , Horst-Werner Zanthoff , Jörg Schallenberg , Frank Geilen , Katrin Marie Dyballa , Dirk Fridag , Stephan Peitz , Lena Altmann , Robert Franke
IPC分类号： C07C67/08 , C07C2/24 , C07C29/141 , C07C45/50
CPC分类号： C07C67/08 , C07C2/24 , C07C29/141 , C07C45/50 , C07C45/505 , C07C2521/12 , C07C2523/755 , Y02P20/52 , C07C47/02 , C07C31/125 , C07C69/80 , C07C11/02
摘要： The invention relates to a process for preparing an ester mixture, in which an n-butene-containing feed mixture having a composition which changes over time is first oligomerized and then converted by hydroformylation, hydrogenation and esterification to an ester mixture. In this process, an approximation of the actual viscosity of the ester mixture is determined. The problem that it addresses is that of specifying a comparatively simple process which enables conversion of an n-butene with a variable composition over time to an ester mixture having a viscosity which can be kept very substantially constant over a long period even when an inconstant C4 source which delivers fluctuating qualities over this period is utilized. This is achieved through controlled use of a second raw material, namely ethene. It has been found that the viscosity of n-butene-based ester mixtures can be influenced by controlled use of ethene in the preparation of the ester precursors. Specifically, the invention proposes two measures by which the ethene can be used: either directly as C2 olefin or as C8 olefin after prior separate oligomerization.

10. 发明授权

US09751904B2 Method for reducing the chlorine content of organomonophosphites using dimethylaminobutane, triethylamine or triethanolamine 有权
公开(公告)号：US09751904B2
公开(公告)日：2017-09-05
申请号：US15312024
申请日：2015-04-29
申请人： EVONIK DEGUSSA GMBH
发明人： Katrin Marie Dyballa , Robert Franke
IPC分类号： C07F9/145
CPC分类号： C07F9/062 , C07F9/025 , C07F9/145 , C07F9/65742 , C07F9/65744
摘要： The invention relates to a universally applicable method for reducing the chlorine content of organomonophosphites using dimethylaminobutane or triethylamine.

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