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1. 发明授权

US5612383A Weakly basic anion exchangers, processes for their preparation by aminolysis and their use for removing sulphate ions from aqueous liquids 失效
标题翻译：弱碱性阴离子交换剂，其通过氨解制备的方法及其用于从含水液体中除去硫酸根离子的用途
公开(公告)号：US5612383A
公开(公告)日：1997-03-18
申请号：US443827
申请日：1995-05-18
申请人： Harold Heller , Franz-Rudolf Minz , Reinhold M. Klipper , Alfred Mitschker , Heiko Hoffmann
发明人： Harold Heller , Franz-Rudolf Minz , Reinhold M. Klipper , Alfred Mitschker , Heiko Hoffmann
IPC分类号： B01J41/04 , B01J41/14 , C01D3/16 , C02F1/42 , C08F8/32 , B01J41/12
CPC分类号： B01J41/046 , B01J41/14 , C08F8/32
摘要： Weakly basic anion exchangers of the poly(meth)acrylamide type which have been prepared by aminolysis of poly(meth)acrylonitrile or poly(meth)acrylate with polyamines of defined composition have an improved absorption capacity for sulphate ions and are suitable for selectively removing sulphate ions from aqueous liquids, in particular from sodium chloride brine and from waste waters.
摘要翻译：通过将聚（甲基）丙烯腈或聚（甲基）丙烯酸酯与多聚甲基丙烯酸酯分解而制得的聚（甲基）丙烯酰胺类型的弱碱性阴离子交换剂具有改进的硫酸根离子吸收能力，适用于选择性除去硫酸盐来自含水液体的离子，特别是氯化钠盐水和废水。

2. 发明授权

US5441646A Process of removing sulfate ions from water with a poly(meth)acrylamide exchange resin 失效
标题翻译：用聚（甲基）丙烯酰胺交换树脂从水中除去硫酸根离子的方法
公开(公告)号：US5441646A
公开(公告)日：1995-08-15
申请号：US277383
申请日：1994-07-19
申请人： Harold Heller , Franz-Rudolf Minz , Reinhold M. Klipper , Alfred Mitschker , Heiko Hoffmann
发明人： Harold Heller , Franz-Rudolf Minz , Reinhold M. Klipper , Alfred Mitschker , Heiko Hoffmann
IPC分类号： B01J41/04 , B01J41/14 , C01D3/16 , C02F1/42 , C08F8/32 , B01J41/12
CPC分类号： B01J41/046 , B01J41/14 , C08F8/32
摘要： Weakly basic anion exchangers of the poly(meth)acrylamide type which have been prepared by aminolysis of poly(meth)acrylonitrile or poly(meth)acrylate with polyamines of defined composition have an improved absorption capacity for sulphate ions and are suitable for selectively removing sulphate ions from aqueous liquids, in particular from sodium chloride brine and from waste waters.
摘要翻译：通过将聚（甲基）丙烯腈或聚（甲基）丙烯酸酯与多聚甲基丙烯酸酯分解而制得的聚（甲基）丙烯酰胺类型的弱碱性阴离子交换剂具有改进的硫酸根离子吸收能力，适用于选择性除去硫酸盐来自含水液体的离子，特别是氯化钠盐水和废水。

3. 发明授权

US5414020A Process for the preparation of anion exchange resins of the poly(meth)acrylamide type 失效
标题翻译：制备聚（甲基）丙烯酰胺型阴离子交换树脂的方法
公开(公告)号：US5414020A
公开(公告)日：1995-05-09
申请号：US160453
申请日：1993-12-01
申请人： Harold Heller , Friedrich Werner , Alfred Mitschker , Axel Ingendoh
发明人： Harold Heller , Friedrich Werner , Alfred Mitschker , Axel Ingendoh
IPC分类号： B01J41/14 , C08F8/00 , C08F8/32 , B01J41/08 , B01J41/12
CPC分类号： B01J41/14 , C08F8/32
摘要： According to the process according to the invention for the preparation of anion exchange resins of the poly(meth)acrylamide type by aminolysis of bead polymers of cross-linked poly(meth)acrylic acid esters with excess polyamine, subsequent separation of the anion exchange resins from the liquid phase containing the unreacted polyamine, washing the anion exchangers free of amine with water and recovering the polyamines from the washing waters, the liquid phase containing the unreacted polyamine and the polyamine-containing washing waters are immediately mixed with the bead polymer of cross-linked poly(meth)acrylic acid ester to be subjected to aminolysis, the amount of fresh polyamine necessary for the establishment of the desired polyamine excess is added to the mixture, the mixture thus obtained is distillatively dewatered until its water content has fallen to a value of
摘要翻译：根据本发明的制备聚（甲基）丙烯酰胺型阴离子交换树脂的方法，通过交联聚（甲基）丙烯酸酯与多余多胺的珠粒聚合物的分解，随后分离阴离子交换树脂从含有未反应的多胺的液相中，用水洗涤不含胺的阴离子交换剂并从洗涤水中回收多胺，将含有未反应的多胺和含多胺洗涤水的液相立即与交叉的珠聚合物连接的聚（甲基）丙烯酸酯进行氨解，将所需多胺过量所需的新鲜多胺的量加入混合物中，将得到的混合物进行蒸馏脱水，直到其含水量降至值为<7重量％，并且在该蒸馏脱水后残留的混合物在该溶液中进行氨解玛丽的样子

4. 发明授权

US5175193A Process for the preparation of weakly acid cation exchange resins 失效
标题翻译：弱酸阳离子交换树脂的制备方法
公开(公告)号：US5175193A
公开(公告)日：1992-12-29
申请号：US638465
申请日：1991-01-07
申请人： Harold Heller , Friedrich Werner , Alfred Mitschker , Herbert V. Diehl , Axel Schafer
发明人： Harold Heller , Friedrich Werner , Alfred Mitschker , Herbert V. Diehl , Axel Schafer
IPC分类号： B01J39/20 , C08F8/12
CPC分类号： B01J39/20 , C08F8/44 , C08F2800/20 , C08F2810/20
摘要： The invention relates to an environment-friendly process for the preparation of weakly acid cation exchange resins by hydrolysis of crosslinked acrylonitrile bead polymers with an alkaline hydrolizing agent at elevated temperature, according to which the bead polymer and alkaline hydrolizing agent are brought together at elevated temperature only.
摘要翻译：本发明涉及通过在高温下用碱性水解剂水解交联的丙烯腈珠聚合物来制备弱酸阳离子交换树脂的环境友好的方法，根据该方法，将珠粒聚合物和碱性水解剂在高温下只要。

5. 发明授权

US4988738A Process for the preparation of bifunctional anion exchange resins, new bifunctional anion exchange resins and use thereof 失效
标题翻译：双功能阴离子交换树脂的制备方法，新型双功能阴离子交换树脂及其用途
公开(公告)号：US4988738A
公开(公告)日：1991-01-29
申请号：US373836
申请日：1989-06-30
申请人： Alfred Mitschker , Peter M. Lange , Harold Heller , Friedrich Werner , Hans-Karl Soest , Gunter Siegers
发明人： Alfred Mitschker , Peter M. Lange , Harold Heller , Friedrich Werner , Hans-Karl Soest , Gunter Siegers
IPC分类号： C08F8/00 , B01J41/04 , B01J41/14 , C08F8/02
CPC分类号： B01J41/14 , B01J41/043
摘要： A process for the preparation of a bifunctional anion exchange resin by partial quaternization of a weakly basic anion exchanger containing tertiary amino groups which process comprises (a) partially loading the weakly basic anion exchanger with a strong acid and (b) quaternizing the partially loaded anion exchanger by means of a customary alkylating agent.
摘要翻译：通过含有叔氨基的弱碱性阴离子交换剂的部分季铵化制备双功能阴离子交换树脂的方法，该方法包括（a）用强酸部分负载弱碱性阴离子交换剂和（b）将部分负载的阴离子季铵化交换器通过常规的烷基化剂。

6. 发明授权

US4083712A Nitrogenous fertilizer compositions 失效
标题翻译：氮肥组合物
公开(公告)号：US4083712A
公开(公告)日：1978-04-11
申请号：US428264
申请日：1973-12-26
申请人： Herbert Corte , Harold Heller , Peter Michael Lange , Otto Netz
发明人： Herbert Corte , Harold Heller , Peter Michael Lange , Otto Netz
IPC分类号： C05C9/00 , C05C11/00 , C05D9/00
CPC分类号： C05C11/00 , C05C9/00 , C05D9/00
摘要： Nitrogenous fertilizer compositions comprising a cation exchanger in the form of a salt thereof with a basic carbonic acid derivative containing at least 2 nitrogen groupings, e.g., a salt formed by attaching to a cation exchange material, guanidine, diguanidine, guanylurea, biuretdicyanamide, urazone, melamine, guanine or ammeline, are outstandingly effective in providing gradually-acting, long-lasting fertilizing action.
摘要翻译：含氮肥料组合物包含其盐形式的阳离子交换剂和含有至少2个氮基团的碱性碳酸衍生物，例如通过连接到阳离子交换材料，胍，二胍，脒基脲，缩二脲二酰胺，尿嘧啶，三聚氰胺，鸟嘌呤或氨基磺酸，对提供逐步作用，持久的施肥作用是非常有效的。

7. 发明授权

US4025705A Insoluble adsorber resin suitable for treating drinking water and sewage 失效
标题翻译：不溶性吸附树脂适用于饮用水和污水处理
公开(公告)号：US4025705A
公开(公告)日：1977-05-24
申请号：US623785
申请日：1975-10-20
申请人： Herbert Corte , Harold Heller , Michael Lange , Otto Netz
发明人： Herbert Corte , Harold Heller , Michael Lange , Otto Netz
IPC分类号： B01J20/22 , C02F1/28 , C08F212/00
CPC分类号： C08J9/286 , B01J20/22 , C02F1/285 , C08J2325/00 , Y10S210/916
摘要： The invention relates to a process for removing oleophilic odor- and tasteproducing substances from water by treating the water with an insoluble, macroporous adsorber resin comprising a matrix based on a crosslinked organic polymer containing aromatic nuclei, the polymer containing chloromethyl groups as substituents; some of the chlorine atoms in the chlormethyl groups can be reacted with ammonia or amines; furthermore, the invention relates to the adsorber resins to be used in the claimed process.
摘要翻译：本发明涉及一种通过用不溶性大孔吸附剂树脂处理水来除去亲油性气味和引诱物质的方法，所述不溶性大孔吸附剂树脂包括基于含有芳族核的交联有机聚合物的基质，所述聚合物含有氯甲基作为取代基; 氯甲基中的一些氯原子可以与氨或胺反应; 此外，本发明涉及要在所要求保护的方法中使用的吸附树脂。

8. 发明授权

US3994719A Resins for separating heavy metals consisting of thiourea-group-containing macroporous vinyl aromatic crosslinked matrixes 失效
标题翻译：用于分离由含硫脲基的大孔乙烯基芳族交联基质组成的重金属的树脂
公开(公告)号：US3994719A
公开(公告)日：1976-11-30
申请号：US452938
申请日：1974-03-20
申请人： Herbert Corte , Harold Heller , Michael Lange , Otto Netz
发明人： Herbert Corte , Harold Heller , Michael Lange , Otto Netz
IPC分类号： C08F8/00 , B01J20/22 , B01J20/26 , C08F8/34 , C08F212/00 , C08G18/00 , C08G18/62 , C08G85/00 , C08J7/12 , C08F27/02
CPC分类号： B01J20/26 , B01J20/22 , C08F8/34 , C08F2800/20
摘要： The invention concerns new, crosslinked, macroporous, vinyl-aromatic plastic materials containing thiourea groups, to processes for their production and to their use for adsorbing metal compounds, especially noble metal and mercury compounds.
摘要翻译：本发明涉及含有硫脲基团的新的，交联的，大孔的，乙烯基芳族塑料材料，其制备方法及其用于吸附金属化合物，特别是贵金属和汞化合物的用途。

9. 发明授权

US4469502A Ion exchanger fertilizers and a process for supplying plants with nutrients uniformly and over a long period of time 失效
标题翻译：离子交换肥料，以及长期供应植物营养的过程
公开(公告)号：US4469502A
公开(公告)日：1984-09-04
申请号：US492511
申请日：1983-05-06
申请人： Harold Heller , Dietmar Schapel
发明人： Harold Heller , Dietmar Schapel
IPC分类号： C05D3/00 , C05C13/00 , C05D9/02 , C05D11/00 , C05G3/00 , C05G1/00
CPC分类号： C05G3/0047 , C05D9/02
摘要： A process for supplying plants with nutrients uniformly and over a long period of time by the addition of nutrient-charged synthetic resin ion exchangers and mineral fertilizers to the culture medium, according to which the nutrient-charged synthetic resin ion exchangers are employed together with those mineral fertilizers with particle size
摘要翻译：通过向培养基中加入营养充足的合成树脂离子交换剂和矿物肥料，向植物均匀和长时间地供应营养物的方法，根据该方法，营养充电的合成树脂离子交换剂与那些颗粒尺寸<500μm的矿物肥料已经涂覆有具有特定吸水能力的块状聚氨酯，其特别适用于矿物肥料的水溶性; 此外，含有营养物质的合成树脂离子交换剂的肥料和涂覆有具有特定吸水能力的块状聚氨酯的矿物肥料。

10. 发明授权

US4402725A Fertilizers 失效
标题翻译：肥料
公开(公告)号：US4402725A
公开(公告)日：1983-09-06
申请号：US241325
申请日：1981-03-06
申请人： Harold Heller , Dietmar Schapel , Claus Hentschel , Manfred Dahm
发明人： Harold Heller , Dietmar Schapel , Claus Hentschel , Manfred Dahm
IPC分类号： C05G3/00 , C05D9/00
CPC分类号： C05D9/00 , Y10S71/02 , Y10S71/903 , Y10S71/904
摘要： A fertilizer for the long term and uniform supply of plants with nutrient ions comprising a covalently crosslinked hydrogel in which are embedded ion exchangers which are laden with plant nutrients; furthermore a process for the long term and uniform supply of plants with nutrient ions wherein a covalently crosslinked hydrogel in which are embedded ion exchangers which are laden with plant nutrients is applied to the plants or their environment.
摘要翻译：一种肥料，长期和均匀供应具有营养离子的植物，包括共价交联的水凝胶，其中嵌入有植物营养素的离子交换剂; 此外，长期和均匀供应具有营养离子的植物的方法，其中将含有植物营养物的嵌入式离子交换剂的共价交联的水凝胶施用于植物或其环境。

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