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1. 发明授权

US07728079B2 Hydrolytically stable postcrosslinked superabsorbents 失效
标题翻译：水解稳定的后交联超吸收剂
公开(公告)号：US07728079B2
公开(公告)日：2010-06-01
申请号：US11885250
申请日：2006-02-24
申请人： Jörg Harren , Jörg Issberner , Mirko Walden , Rainer Teni , Franck Furno , Peter Werle , Hans-Peter Krimmer
发明人： Jörg Harren , Jörg Issberner , Mirko Walden , Rainer Teni , Franck Furno , Peter Werle , Hans-Peter Krimmer
IPC分类号： C08F8/30
CPC分类号： C08J3/24 , C08F220/06 , C08J2333/02
摘要： The present invention relates to a process for producing postcrosslinked water-absorbing polymeric formations, comprising the steps of contacting water-absorbing polymeric formations P1 obtained by polymerization of ethylenically unsaturated acid-functional monomers or salts thereof in the presence of a crosslinker with a fluid F1 comprising a postcrosslinker, heating the water-absorbing polymeric formations in contact with the fluid F1 to a temperature in a range from 40 to 300° C. to obtain postcrosslinked water-absorbing polymeric formations P2, the water-absorbing polymeric formations P1 having a thermal stability, as determined in accordance with the test method described herein, of less than 3.0%. The invention also relates to water-absorbing polymeric formations, to the water-absorbing polymeric formations obtainable by this process, to water-absorbing polymeric formations based on crosslinked carboxyl-bearing monomers, to a composite comprising water-absorbing polymeric formations and a substrate, to a process for producing a composite, to a composite obtainable by this process, to chemical products comprising water-absorbing polymeric formations or a composite, to the use of water-absorbing polymeric formations or of a composite in chemical products and also to the use of triallyl isocyanurate as an internal crosslinker in the production of water-absorbing polymeric formations based on crosslinked carboxyl-bearing monomers.
摘要翻译：本发明涉及一种生产后交联吸水聚合物地层的方法，包括以下步骤：将交联剂存在下烯属不饱和酸官能单体或其盐聚合得到的吸水聚合物地层P1与流体F1 包括后交联剂，将与流体F1接触的吸水聚合物层加热到40-300℃的温度，以获得后交联的吸水聚合物层P2，吸水聚合物层P1具有热根据本文所述的测试方法测定的稳定性小于3.0％。本发明还涉及吸水聚合物地层，可通过该方法获得的吸水聚合物地层，基于交联的含羧基单体的吸水聚合物地层，包括吸水聚合物地层和基底的复合材料，涉及通过该方法可获得的复合材料的方法，涉及包含吸水聚合物结构或复合材料的化学产品，使用吸水聚合物结构或化学产品中的复合材料，以及使用的三烯丙基异氰脲酸酯作为内部交联剂在基于交联的含羧基单体的吸水性聚合物地层的生产中。

2. 发明申请

US20080214740A1 Hydrolytically Stable Postcrosslinked Superabsorbents 失效
标题翻译：水解稳定的后交联超吸收剂
公开(公告)号：US20080214740A1
公开(公告)日：2008-09-04
申请号：US11885250
申请日：2006-02-24
申请人： Jorg Harren , Jorg Issberner , Mirko Walden , Rainer Teni , Franck Furno , Peter Werle , Hans-Peter Krimmer
发明人： Jorg Harren , Jorg Issberner , Mirko Walden , Rainer Teni , Franck Furno , Peter Werle , Hans-Peter Krimmer
IPC分类号： C08F8/30
CPC分类号： C08J3/24 , C08F220/06 , C08J2333/02
摘要： The present invention relates to a process for producing postcrosslinked water-absorbing polymeric formations, comprising the steps of contacting water-absorbing polymeric formations P1 obtained by polymerization of ethylenically unsaturated acid-functional monomers or salts thereof in the presence of a crosslinker with a fluid F1 comprising a postcrosslinker, heating the water-absorbing polymeric formations in contact with the fluid F1 to a temperature in a range from 40 to 300° C. to obtain postcrosslinked water-absorbing polymeric formations P2, the water-absorbing polymeric formations P1 having a thermal stability, as determined in accordance with the test method described herein, of less than 3.0%. The invention also relates to water-absorbing polymeric formations, to the water-absorbing polymeric formations obtainable by this process, to water-absorbing polymeric formations based on crosslinked carboxyl-bearing monomers, to a composite comprising water-absorbing polymeric formations and a substrate, to a process for producing a composite, to a composite obtainable by this process, to chemical products comprising water-absorbing polymeric formations or a composite, to the use of water-absorbing polymeric formations or of a composite in chemical products and also to the use of triallyl isocyanurate as an internal crosslinker in the production of water-absorbing polymeric formations based on crosslinked carboxyl-bearing monomers.
摘要翻译：本发明涉及一种生产后交联的吸水聚合物地层的方法，包括以下步骤：通过烯键式不饱和酸官能单体或其盐的聚合获得的吸水聚合物地层P 1 存在具有包含后交联剂的流体F 1 N的交联剂，将与流体F 1 1接触的吸水聚合物层加热到40〜 300℃以获得后交联的吸水聚合物组合物P 2，根据测试方法测定的具有热稳定性的吸水性聚合物组合物P 1 <1> 如本文所述，小于3.0％。本发明还涉及吸水聚合物地层，可通过该方法获得的吸水聚合物地层，基于交联的含羧基单体的吸水聚合物地层，包括吸水聚合物地层和基底的复合材料，涉及通过该方法可获得的复合材料的方法，涉及包含吸水聚合物结构或复合材料的化学产品，使用吸水聚合物结构或化学产品中的复合材料，以及使用的三烯丙基异氰脲酸酯作为内部交联剂在基于交联的含羧基单体的吸水性聚合物地层的生产中。

3. 发明授权

US6060571A Acrolein-releasing copolymers 失效
标题翻译：丙烯醛释放共聚物
公开(公告)号：US6060571A
公开(公告)日：2000-05-09
申请号：US804698
申请日：1997-02-21
申请人： Peter Werle , Hans-Peter Krimmer , Martin Trageser , Franz-Rudolf Kunz
发明人： Peter Werle , Hans-Peter Krimmer , Martin Trageser , Franz-Rudolf Kunz
IPC分类号： C08G2/14 , C08G2/18 , C08G4/00 , C08G6/00 , C08G2/00 , C02F3/32 , C08F16/34
CPC分类号： C08G2/14 , C08G2/18 , C08G4/00 , C08G6/00 , Y10S526/909
摘要： Acrolein polymer from acrolein and one or more polyhydric alcohols, characterized by release of monomeric acrolein in aqueous systems and hence by a prolonged effect on microorganisms, is prepared by adding acrolein to a reaction medium containing catalyst in dissolved form, and not allowing the temperature of the reaction medium to rise about 50.degree. C. The acrolein polymer may be used in aqueous systems as a biocide.
摘要翻译：丙烯醛和一种或多种多元醇的丙烯醛聚合物，其特征在于在水性体系中释放单体丙烯醛，并因此通过延长对微生物的作用，通过将丙烯醛加入到含有溶解形式的催化剂的反应介质中，并且不允许反应介质升高约50℃。丙烯醛聚合物可用作水系统中的杀生物剂。

4. 发明授权

US08198431B2 Process for preparing triallyl isocyanurate (TAIC) 有权
标题翻译：三烯丙基异氰脲酸酯（TAIC）的制备方法
公开(公告)号：US08198431B2
公开(公告)日：2012-06-12
申请号：US12307592
申请日：2007-06-14
申请人： Peter Werle , Hans-Peter Krimmer , Manfred Schmidt , Klaus Stadtmueller , Martin Trageser
发明人： Peter Werle , Hans-Peter Krimmer , Manfred Schmidt , Klaus Stadtmueller , Martin Trageser
IPC分类号： C07D487/22 , C07B47/00
CPC分类号： C07D251/34
摘要： The invention is directed to an improved, reliably performable process for preparing triallyl isocyanurate (TAIC) by Cu2+-catalysed rearrangement of triallyl cyanurate (TAC) at at least 90° C. According to the invention, TAC and, if required, also a Cu2+ catalyst and solvent are fed continuously to a start reaction mixture after onset of the initially inhibited isomerization reaction, the isomerization is performed at from 90 to 160° C. and an amount of reaction mixture equivalent to the amount of reactant is drawn off continuously and sent to the workup. Preference is given to effecting the isomerization in TAIC as the reaction medium.
摘要翻译：本发明涉及通过三聚氰尿酸三烯丙酯（TAC）在至少90℃下通过Cu 2+催化重排制备三烯丙基异氰脲酸酯（TAIC）的改进的，可靠的可操作的方法。根据本发明，如果需要，TAC和Cu 2+ 催化剂和溶剂在最初抑制的异构化反应开始后连续进料到起始反应混合物中，异构化在90至160℃下进行，反应混合物的量等于反应物的量连续排出并发送到后台。优选在TAIC中作为反应介质进行异构化。

5. 发明申请

US20090312545A1 PROCESS FOR PREPARING TRIALLYL ISOCYANURATE (TAIC) 有权
标题翻译：制备三异氰酸酯（TAIC）的方法
公开(公告)号：US20090312545A1
公开(公告)日：2009-12-17
申请号：US12307592
申请日：2007-06-14
申请人： Peter Werle , Hans-Peter Krimmer , Manfred Schmidt , Klaus Stadtmueller , Martin Trageser
发明人： Peter Werle , Hans-Peter Krimmer , Manfred Schmidt , Klaus Stadtmueller , Martin Trageser
IPC分类号： C07D251/30
CPC分类号： C07D251/34
摘要： The invention is directed to an improved, reliably performable process for preparing triallyl isocyanurate (TAIC) by Cu2+-catalysed rearrangement of triallyl cyanurate (TAC) at least 90° C. According to the invention, TAC and, if required, also a Cu2+ catalyst and solvent are fed continuously to a start reaction mixture after onset of the initially inhibited isomerization reaction, the isomerization is performed at from 90 to 160° C. and an amount of reaction mixture equivalent to the amount of reactant is drawn off continuously and sent to the workup. Preference is given to effecting the isomerization in TAIC as the reaction medium.
摘要翻译：本发明涉及一种改进的，可靠的可行的制备三烯丙基异氰脲酸酯（TAIC）的方法，所述三烯丙基异氰脲酸酯是通过三异丙烯酸三烯丙酯（TAC）至少90℃的Cu 2+催化重排来制备的。根据本发明，如果需要，TAC和Cu 2+催化剂在最初抑制的异构化反应开始后，将溶剂连续加入到起始反应混合物中，异构化在90〜160℃下进行，反应混合物的量等同于反应物的量连续排出并送至的后卫。优选在TAIC中作为反应介质进行异构化。

6. 发明授权

US07993676B2 Free-flowing, powdery composition containing alpha-liponic acid (derivates) 有权
标题翻译：含有α-脂肪酸（衍生物）的自由流动的粉状组合物
公开(公告)号：US07993676B2
公开(公告)日：2011-08-09
申请号：US10515671
申请日：2003-05-28
申请人： Hans Schuhbauer , Claus-Peter Drexel , Herbert Clinton Fairow , Hans-Peter Krimmer
发明人： Hans Schuhbauer , Claus-Peter Drexel , Herbert Clinton Fairow , Hans-Peter Krimmer
IPC分类号： A61K9/14 , A61K31/385 , A01N43/26
CPC分类号： A61K31/385 , A61K9/143
摘要： A free-flowing, powdery composition contains a lipoic acid component and from 0.1 to 25% by weight of the total composition of a silica-based flow aid having a particle size (×100 value) of
摘要翻译：一种自由流动的粉状组合物含有硫辛酸组分和占组合物总重量的0.1至25重量％的具有<800μm粒径（×100值）的二氧化硅基流动助剂。

7. 发明授权

US5856478A Anellated (oxa)hydantoins and their use as herbicides 失效
标题翻译：茴香（oxa）乙内酰脲及其作为除草剂的用途
公开(公告)号：US5856478A
公开(公告)日：1999-01-05
申请号：US752031
申请日：1996-11-19
申请人： Matthias Schafer , Helmut Baier , Karlheinz Drauz , Hans-Peter Krimmer , Sabine Landmann
发明人： Matthias Schafer , Helmut Baier , Karlheinz Drauz , Hans-Peter Krimmer , Sabine Landmann
IPC分类号： A01N43/90 , A01N55/00 , A01N57/16 , A01P13/00 , C07D413/04 , C07D471/04 , C07D487/04 , C07D491/048 , C07D498/04 , C07D498/10 , C07D513/04 , C07F7/18 , C07F9/6561
CPC分类号： C07D471/04 , A01N43/90 , C07D487/04 , C07D498/04 , C07D498/10 , C07D513/04
摘要： The invention relates to new anellated (oxa) hydantoins, and herbicidal compositions containing same. The invention also relates to methods for controlling noxious plants using the anellated (oxa) hydantoins of the invention.
摘要翻译：本发明涉及新的安瓿（oxa）乙内酰脲和含有它们的除草组合物。本发明还涉及使用本发明的安定（oxa）乙内酰脲来控制有害植物的方法。

8. 发明授权

US5116872A Microbicidal compositions 失效
标题翻译：微生物组合物
公开(公告)号：US5116872A
公开(公告)日：1992-05-26
申请号：US643882
申请日：1991-01-22
申请人： Peter Ackermann , Hanspeter Fischer , Rolf Vogel , Karlheinz Drauz , Hans-Albrecht Hasseberg , Hans-Jochen Hasselbach , Gunter Knaup , Hans-Peter Krimmer , Matthias Schafer
发明人： Peter Ackermann , Hanspeter Fischer , Rolf Vogel , Karlheinz Drauz , Hans-Albrecht Hasseberg , Hans-Jochen Hasselbach , Gunter Knaup , Hans-Peter Krimmer , Matthias Schafer
IPC分类号： A01N37/44 , C07C229/48 , C07C229/76
CPC分类号： C07C229/76 , A01N37/44 , C07C229/48 , C07C2101/14
摘要： 1-Aminocyclohexanecarboxylic acid derivatives of the formula I ##STR1## or their acid addition salts or a metal complex can be employed for protecting plants from microorganisms. In the formula I, R.sub.1 is hydrogen or C.sub.1 -C.sub.4 alkyl, R.sub.2 is hydrogen, C.sub.1 -C.sub.6 alkyl, benzyl, or an ammonium radical which is unsubstituted or substituted by hydrocarbon radicals having not more than 20 C atoms, or a metal ion equivalent.Compounds of the formula I can be employed in the form of crop protection agents using suitable carrier materials.
摘要翻译：式I（I）的1-氨基环己烷羧酸衍生物或其酸加成盐或金属络合物可用于保护植物免受微生物侵害。在式I中，R 1是氢或C 1 -C 4烷基，R 2是氢，C 1 -C 6烷基，苄基或未被取代或被不大于20个碳原子的烃基取代的铵基或金属离子当量。式I的化合物可以使用合适的载体材料以作物保护剂的形式使用。

9. 发明授权

US4952706A Derivatives of 2-pyrrolidone-5-carboxylic acid and method of obtaining them 失效
标题翻译： 2-吡咯烷酮-5-羧酸的衍生物及其获得方法
公开(公告)号：US4952706A
公开(公告)日：1990-08-28
申请号：US417089
申请日：1989-10-04
申请人： Hans-Peter Krimmer , Karlheinz Drauz
发明人： Hans-Peter Krimmer , Karlheinz Drauz
IPC分类号： C07D207/28
CPC分类号： C07D207/28
摘要： The new, crystalline trihydrates of sodium L- and D-2-pyrrolidone-5-carboxylate. These trihydrates can be obtained by adjusting the concentration and the temperature in an aqueous solution of sodium L- or D-2-pyrrolidone-5-carboxlate in such a manner that the solubility of the desired trihydrate is exceeded.
摘要翻译： L-和D-2-吡咯烷酮-5-羧酸钠的新的结晶三水合物。这些三水合物可以通过调节L型或D-2-吡咯烷酮-5-甲酸钠水溶液的浓度和温度，从而超过所需三水合物的溶解度。

10. 发明申请

US20120208925A1 USE OF GUANIDINE DERIVATIVES AS CURING ACCELERATORS FOR EPOXY RESINS 有权
标题翻译：使用衍生物作为环氧树脂的固化加速剂
公开(公告)号：US20120208925A1
公开(公告)日：2012-08-16
申请号：US13498435
申请日：2010-11-05
申请人： Martin Hitzler , Hans-Peter Krimmer , Sylvia Strobel , Monika Brandl
发明人： Martin Hitzler , Hans-Peter Krimmer , Sylvia Strobel , Monika Brandl
IPC分类号： C08L63/00
CPC分类号： C08G59/50 , C08G59/4021 , C08G59/686
摘要： The present invention describes guanidine derivatives of the general formula (I) having the stated meanings for the residues R1, R2 and R3 as accelerators for cold-curing epoxy resin compositions. The curing of cold-curing epoxy resin systems may advantageously be accelerated with the assistance of these compounds.
摘要翻译：本发明描述了作为冷固化环氧树脂组合物的加速剂的残基R1，R2和R3具有所述含义的通式（I）的胍衍生物。在这些化合物的帮助下，可有利地加速冷固化环氧树脂体系的固化。

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