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    • 3. 发明申请
    • Stoichiometric Lithium Cobalt Oxide and Method for Preparation of the Same
    • 化学计量氧化钴钴及其制备方法
    • US20070218363A1
    • 2007-09-20
    • US11688636
    • 2007-03-20
    • Jens M. PaulsenSun Sik ShinHong-Kyu Park
    • Jens M. PaulsenSun Sik ShinHong-Kyu Park
    • H01M4/52C01G51/04
    • H01M4/525C01G51/42C01G51/50C01G53/50C01P2002/77C01P2004/03C01P2006/40H01M4/04H01M4/131H01M4/366H01M4/483H01M4/505H01M4/523H01M10/0525Y02E60/122Y02P70/54
    • The present invention provides a LiCoO2-containing powder comprising LiCoO2 having a stoichiometric composition via heat treatment of a lithium cobalt oxide and a lithium buffer material to make equilibrium of a lithium chemical potential therebetween: a lithium buffer material which acts as a Li acceptor or a Li donor to remove or supplement Li-excess or Li-deficiency, coexisting with a stoichiometric lithium metal oxide; and a method for preparing a LiCoO2-containing powder. Further, provided is an electrode comprising the above-mentioned LiCoO2-containing powder as an active material, and a rechargeable battery comprising the same electrode.The present invention enables production of a LiCoO2 electrode active material which has improved high-temperature storage properties and high-voltage cycling properties, and is robust in composition fluctuation in the production process. Therefore, the present invention provides advantages such as reduction of time and labor required for quality control and process management in the mass-production of the electrode active material, and decreased production costs of LiCoO2.
    • 本发明通过热处理锂钴氧化物和锂缓冲材料提供包含具有化学计量组成的LiCoO 2 N 2的含LiCoO 2 N的粉末,以使锂的平衡 它们之间的化学势:用作Li受体或Li给体以除去或补充Li-过量或Li-缺乏的锂缓冲材料,与化学计量的锂金属氧化物共存; 以及制备含有LiCoO 2 N的粉末的方法。 此外,提供了包含上述含有LiCoO 2 N 2的粉末作为活性材料的电极和包含相同电极的可再充电电池。 本发明能够生产具有改进的高温储存性能和高电压循环性能的LiCoO 2 N 2电极活性材料,并且在生产过程中的组成波动中是稳定的。 因此,本发明提供了在电极活性物质的批量生产中减少质量控制和工艺管理所需的时间和劳动以及降低LiCoO 2 2的生产成本的优点。
    • 8. 发明申请
    • STOICHIOMETRIC LITHIUM COBALT OXIDE AND METHOD FOR PREPARATION OF THE SAME
    • 硅铝酸锂氧化物及其制备方法
    • US20110309290A1
    • 2011-12-22
    • US12968706
    • 2010-12-15
    • Jens M. PaulsenSun Sik SHINHong-Kyu PARK
    • Jens M. PaulsenSun Sik SHINHong-Kyu PARK
    • H01M4/525
    • H01M4/525C01G51/42C01G51/50C01G53/50C01P2002/77C01P2004/03C01P2006/40H01M4/04H01M4/131H01M4/366H01M4/483H01M4/505H01M4/523H01M10/0525Y02E60/122Y02P70/54
    • The present invention provides a LiCoO2-containing powder comprising LiCoO2 having a stoichiometric composition via heat treatment of a lithium cobalt oxide and a lithium buffer material to make equilibrium of a lithium chemical potential therebetween; a lithium buffer material which acts as a Li acceptor or a Li donor to remove or supplement Li-excess or Li-deficiency, coexisting with a stoichiometric lithium metal oxide; and a method for preparing a LiCoO2-containing powder. Further, provided is an electrode comprising the above-mentioned LiCoO2-containing powder as an active material, and a rechargeable battery comprising the same electrode.The present invention enables production of a LiCoO2 electrode active material which has improved high-temperature storage properties and high-voltage cycling properties, and is robust in composition fluctuation in the production process. Therefore, the present invention provides advantages such as reduction of time and labor required for quality control and process management in the mass-production of the electrode active material, and decreased production costs of LiCoO2.
    • 本发明提供一种含有LiCoO 2的粉末,其包含通过锂钴氧化物和锂缓冲材料的热处理而具有化学计量组成的LiCoO 2,以在其间形成锂化学势的平衡; 用作Li受体或Li供体以除去或补充Li-过量或Li-缺乏的锂缓冲材料,与化学计量的锂金属氧化物共存; 以及制备含有LiCoO 2的粉末的方法。 此外,提供了包含上述含有LiCoO 2的粉末作为活性材料的电极和包含相同电极的可再充电电池。 本发明能够生产具有改善的高温储存性能和高电压循环性能的LiCoO 2电极活性材料,并且在生产过程中的组成波动中是稳定的。 因此,本发明提供了在电极活性物质的批量生产中减少质量控制和工艺管理所需的时间和劳动力以及降低LiCoO 2的生产成本的优点。