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1. 发明授权

US5883146A Dimensionally stable closed cell rigid polyisocyanate based foam prepared from a froth foaming mixture 失效
标题翻译：由泡沫发泡混合物制备的尺寸稳定的闭孔刚性多异氰酸酯基泡沫
公开(公告)号：US5883146A
公开(公告)日：1999-03-16
申请号：US971019
申请日：1997-11-14
申请人： John R. Tucker
发明人： John R. Tucker
IPC分类号： C08G18/66 , C08J9/14 , C08G18/00
CPC分类号： C08J9/149 , C08G18/6692 , C08J9/146 , C08G2101/0025 , C08G2101/005 , C08J2205/052 , C08J2205/10 , C08J2375/04
摘要： There is now provided a closed cell rigid polyisocyanate based foam blown with a C.sub.1 -C.sub.4 hydrofluorocarbon and formic acid as blowing agents, which possesses a uniform density gradient varying by not more than 10 percent. There is also now provided a polyol composition and a froth foaming mixture having good flow by employing a polyol and formic acid in the presence of a C.sub.1 -C.sub.4 hydrofluorocarbon having a boiling point of 300K or less as co-blowing agents. The polyol composition advantageously has an average OH number of less than 400 and an average functionality of greater than 4, which when reacted with the isocyanate in the presence of a C.sub.1 -C.sub.4 hydrofluorocarbon, yields a rigid closed cell polyisocyanate based dimensionally stable foam having a fine cell structure.
摘要翻译：现在提供了以C1-C4氢氟烃和甲酸为发泡剂吹制的密闭单元刚性多异氰酸酯基泡沫，其具有均匀的密度梯度，其变化不超过10％。现在还提供一种多元醇组合物和泡沫发泡混合物，其在具有300K以下沸点的C1-C4氢氟烃作为共发泡剂的情况下，使用多元醇和甲酸，具有良好的流动性。多元醇组合物有利地具有小于400的平均OH值和大于4的平均官能度，当其在C1-C4氢氟烃的存在下与异氰酸酯反应时，得到刚性闭孔聚异氰酸酯基尺寸稳定的泡沫体，其具有细胞细胞结构。

2. 发明授权

US5470891A Dimensionally stable closed cell rigid polyisocyanate based foam prepared from a froth foaming mixture 失效
标题翻译：由泡沫发泡混合物制备的尺寸稳定的闭孔刚性多异氰酸酯基泡沫
公开(公告)号：US5470891A
公开(公告)日：1995-11-28
申请号：US491555
申请日：1995-06-16
申请人： Todd J. Green , John R. Tucker
发明人： Todd J. Green , John R. Tucker
IPC分类号： C08G18/18 , C08G18/20 , C08J9/14 , C08G18/48
CPC分类号： C08J9/146 , C08G18/1833 , C08G18/2081 , C08G2101/0025 , C08J2375/04
摘要： There is now provided a closed cell rigid polyisocyanate based foam blowing with a C.sub.1 -C.sub.4 hydrofluorocarbon and water as blowing agents, which possesses a uniform density gradient varying by not more than 10 percent. There is also now provided a froth foaming mixture having good flow by employing a hydroxy terminated polyol which is pH neutral and a tertiary amine ether blow catalyst in an amount of 0.5 weight percent or more, using water and a C.sub.1 -C.sub.4 hydrofluorocarbon having a boiling point of 300 K or less as co-blowing agents.There is also provided a polyol composition having an average OH number of less than 400 and an average functionality of greater than 4, which when reacted with the isocyanate in the presence of a C.sub.1 -C.sub.4 hydrofluorocarbon, yields a rigid closed cell polyisocyanate based dimensionally stable foam.The formulation according to an especially preferred embodiment of the invention simultaneously satisfies the following requirements:1) a formulated polyol composition having a viscosity of 550 cP or less;2) the isocyanate stream and the formulated polyol stream dispensable at a 0.9:1 to 1.3:1 weight ratio, respectively;3) frothing when dispensed from a static mixer;4) produces a frothing foaming mixture having excellent flow characteristics as demonstrated by a substantially uniform density gradient;5) and produces a dimensionally stable closed cell foam having a low overall density of 2.5 pcf or less.
摘要翻译：现在提供了以C1-C4氢氟烃和水作为发泡剂吹制的密闭单元刚性多异氰酸酯基泡沫，其具有不超过10％的均匀密度梯度。现在还使用水和具有沸点的C 1 -C 4氢氟碳化合物，通过使用pH中性的羟基封端的多元醇和叔胺醚吹制催化剂的量为0.5重量％以上，提供了具有良好流动性的泡沫发泡混合物 300K以下作为共发泡剂。还提供了平均OH值小于400且平均官能度大于4的多元醇组合物，其在C1-C4氢氟碳化合物的存在下与异氰酸酯反应时产生尺寸稳定的刚性闭孔聚异氰酸酯泡沫。根据本发明特别优选的实施方案的制剂同时满足以下要求：1）粘度为550cP以下的配制多元醇组合物; 2）异氰酸酯流和配制的多元醇流分别以0.9:1至1.3:1的重量比分配; 3）从静态混合器分配时发泡; 4）产生具有优异流动特性的发泡发泡混合物，如通过基本均匀的密度梯度所证明的; 5），并产生尺寸稳定的闭孔泡沫，其具有2.5pcs或更低的总密度。

3. 外观设计

USD421016S Remote control housing 失效
公开(公告)号：USD421016S
公开(公告)日：2000-02-22
申请号：US83107
申请日：1997-12-13
申请人： Donald H. Bowen , David I. Chang , John R. Tucker
设计人： Donald H. Bowen , David I. Chang , John R. Tucker

4. 发明授权

US5447964A Dimensionally stable closed cell rigid polyisocyanate based foam prepared from a froth foaming mixture 失效
标题翻译：由泡沫发泡混合物制备的尺寸稳定的闭孔刚性多异氰酸酯基泡沫
公开(公告)号：US5447964A
公开(公告)日：1995-09-05
申请号：US419203
申请日：1995-04-10
申请人： Todd J. Green , John R. Tucker
发明人： Todd J. Green , John R. Tucker
IPC分类号： C08G18/18 , C08G18/20 , C08J9/14 , C09K3/00
CPC分类号： C08J9/146 , C08G18/1833 , C08G18/2081 , C08G2101/0025 , C08J2375/04
摘要： There is now provided a closed cell rigid polyisocyanate based foam blowing with a C.sub.1 -C.sub.4 hydrofluorocarbon and water as blowing agents, which possesses a uniform density gradient varying by not more than 10 percent. There is also now provided a froth foaming mixture having good flow by employing a hydroxy terminated polyol which is pH neutral and a tertiary amine ether blow catalyst in an amount of 0.5 weight percent or more, using water and a C.sub.1 -C.sub.4 hydrofluorocarbon having a boiling point of 300 K. or less as co-blowing agents.There is also provided a polyol composition having an average OH number of less than 400 and an average functionality of greater than 4, which when reacted with the isocyanate in the presence of a C.sub.1 -C.sub.4 hydrofluorocarbon, yields a rigid closed cell polyisocyanate based dimensionally stable foam.The formulation according to an especially preferred embodiment of the invention simultaneously satisfies the following requirements:1) a formulated polyol composition having a viscosity of 550 cP or less;2) the isocyanate stream and the formulated polyol stream dispensable at a 0.9:1 to 1.3:1 weight ratio, respectively;3) frothing when dispensed from a static mixer;4) produces a frothing foaming mixture having excellent flow characteristics as demonstrated by a substantially uniform density gradient;5) and produces a dimensionally stable closed cell foam having a low overall density of 2.5 pcf or less.
摘要翻译：现在提供了以C1-C4氢氟烃和水作为发泡剂吹制的密闭单元刚性多异氰酸酯基泡沫，其具有不超过10％的均匀密度梯度。现在还使用水和具有沸点的C 1 -C 4氢氟碳化合物，通过使用pH中性的羟基封端的多元醇和叔胺醚吹制催化剂的量为0.5重量％以上，提供了具有良好流动性的泡沫发泡混合物点为300K以下作为共发泡剂。还提供了平均OH值小于400且平均官能度大于4的多元醇组合物，其在C1-C4氢氟碳化合物的存在下与异氰酸酯反应时产生尺寸稳定的刚性闭孔聚异氰酸酯泡沫。根据本发明特别优选的实施方案的制剂同时满足以下要求：1）粘度为550cP以下的配制多元醇组合物; 2）异氰酸酯流和配制的多元醇流分别以0.9:1至1.3:1的重量比分配; 3）从静态混合器分配时发泡; 4）产生具有优异流动特性的发泡发泡混合物，如通过基本均匀的密度梯度所证明的; 5），并产生尺寸稳定的闭孔泡沫，其具有2.5pcs或更低的总密度。

5. 发明授权

US5514724A Dimensionally stable closed cell rigid polyisocyanate based foam prepared from a froth foaming mixture 失效
公开(公告)号：US5514724A
公开(公告)日：1996-05-07
申请号：US509255
申请日：1995-07-31
申请人： Todd J. Green , John R. Tucker
发明人： Todd J. Green , John R. Tucker
IPC分类号： C08G18/18 , C08G18/20 , C08J9/14 , C08G18/06
CPC分类号： C08J9/146 , C08G18/1833 , C08G18/2081 , C08G2101/0025 , C08J2375/04
摘要： There is now provided a closed cell rigid polyisocyanate based foam blowing with a C.sub.1 -C.sub.4 hydrofluorocarbon and water as blowing agents, which possesses a uniform density gradient varying by not more than 10 percent. There is also now provided a froth foaming mixture having good flow by employing a hydroxy terminated polyol which is pH neutral and a tertiary amine ether blow catalyst in an amount of 0.5 weight percent or more, using water and a C.sub.1 -C.sub.4 hydrofluorocarbon having a boiling point of 300 K. or less as co-blowing agents.There is also provided a polyol composition having an average OH number of less than 400 and an average functionality of greater than 4, which when reacted with the isocyanate in the presence of a C.sub.1 -C.sub.4 hydrofluorocarbon, yields a rigid closed cell polyisocyanate based dimensionally stable foam.The formulation according to an especially preferred embodiment of the invention simultaneously satisfies the following requirements:1) a formulated polyol composition having a viscosity of 550 cP or less;2) the isocyanate stream and the formulated polyol stream dispensable at a 0.9:1 to 1.3:1 weight ratio, respectively;3) frothing when dispensed from a static mixer;4) produces a frothing foaming mixture having excellent flow characteristics as demonstrated by a substantially uniform density gradient;5) and produces a dimensionally stable closed cell foam having a low overall density of 2.5 pcf or less.

6. 发明授权

US5430071A Dimensionally stable closed cell rigid polyisocyanate based foam prepared from a froth foaming mixture 失效
公开(公告)号：US5430071A
公开(公告)日：1995-07-04
申请号：US272401
申请日：1994-07-08
申请人： Todd J. Green , John R. Tucker
发明人： Todd J. Green , John R. Tucker
IPC分类号： C08G18/18 , C08G18/20 , C08J9/14 , C09K3/00 , C08G18/48
CPC分类号： C08J9/146 , C08G18/1833 , C08G18/2081 , C08G2101/0025 , C08J2375/04
摘要： There is now provided a closed cell rigid polyisocyanate based foam blowing with a C.sub.1 -C.sub.4 hydrofluorocarbon and water as blowing agents, which possesses a uniform density gradient varying by not more than 10 percent. There is also now provided a froth foaming mixture having good flow by employing a hydroxy terminated polyol which is pH neutral and a tertiary amine ether blow catalyst in an amount of 0.5 weight percent or more, using water and a C.sub.1 -C.sub.4 hydrofluorocarbon having a boiling point of 300 K. or less as co-blowing agents.There is also provided a polyol composition having an average OH number of less than 400 and an average functionality of greater than 4, which when reacted with the isocyanate in the presence of a C.sub.1 -C.sub.4 hydrofluorocarbon, yields a rigid closed cell polyisocyanate based dimensionally stable foam.The formulation according to an especially preferred embodiment of the invention simultaneously satisfies the following requirements:1) a formulated polyol composition having a viscosity of 550 cP or less;2) the isocyanate stream and the formulated polyol stream dispensable at a 0.9:1 to 1.3:1 weight ratio, respectively;3) frothing when dispensed from a static mixer;4) produces a frothing foaming mixture having excellent flow characteristics as demonstrated by a substantially uniform density gradient;5) and produces a dimensionally stable closed cell foam having a low overall density of 2.5 pcf or less.

7. 发明授权

US5262447A Composites having a dimensionally stable water-blown polyurethane foam by employing lithium salts for cooling containers 失效
标题翻译：通过使用锂盐来冷却容器的具有尺寸稳定的水泡聚氨酯泡沫的复合材料
公开(公告)号：US5262447A
公开(公告)日：1993-11-16
申请号：US997006
申请日：1992-12-28
申请人： John R. Tucker
发明人： John R. Tucker
IPC分类号： B32B15/095 , B32B21/00 , C08G18/00 , C08G18/08 , C08G18/22 , C08G18/48 , C08G18/65 , C08G101/00 , C08K5/098 , C08G18/14
CPC分类号： C08G18/482 , C08G18/225 , C08K5/098 , C08G2101/0025 , C08G2101/005 , C08G2101/0083 , C08G2170/60 , Y10T428/249987 , Y10T428/24999 , Y10T428/249991 , Y10T428/249992 , Y10T428/249993
摘要： A water-blown polyurethane foam is provided between two substrates in foamed-in-place applications such as cooling containers. The water-blown polyurethane foam is made dimensionally stable at low densities by adding lithium salts of a 2 to 24 carbon atom carboxylic acid to the polyol component. The dimensional stability of the foam at the low densities further results in raw material savings.
摘要翻译：在发泡就地应用如冷却容器中，在两个基板之间设置水泡聚氨酯泡沫。通过向多元醇组分中加入2〜24个碳原子的羧酸的锂盐，水性聚氨酯泡沫体以低密度尺寸稳定。泡沫在低密度下的尺寸稳定性进一步导致原料节省。

8. 发明授权

US06538595B1 System and method for using infrared remote control packet delivery in a wireless keyboard having a pointing device 有权
标题翻译：在具有指示设备的无线键盘中使用红外遥控分组传送的系统和方法
公开(公告)号：US06538595B1
公开(公告)日：2003-03-25
申请号：US09491561
申请日：2000-01-26
申请人： John R. Tucker , David I. Chang , William L. Lott
发明人： John R. Tucker , David I. Chang , William L. Lott
IPC分类号： G08C1912
CPC分类号： G06F3/04892 , G06F3/0213 , G06F3/023 , G06F3/0231
摘要： An infrared (IR) keyboard having a communication protocol and a method for operating same includes circuitry for converting a standard recognized keystroke into a corresponding IR data word for transmission to an IR receiver. The IR keyboard includes circuitry and logic which determines the type of key being actuated and assigns a communication protocol based upon the detected key. An IR code word corresponding to the detected key is associated with the key press and is transmitted from the IR keyboard to an IR receiver using a protocol corresponding to the type of key detected.
摘要翻译：具有通信协议的红外（IR）键盘及其操作方法包括用于将标准识别的击键转换成相应的IR数据字以传送到IR接收器的电路。 IR键盘包括电路和逻辑，其确定被激活的键的类型，并且基于检测到的键分配通信协议。与检测到的键相对应的IR码字与按键相关联，并且使用与检测到的键的类型对应的协议从IR键盘发送到IR接收器。

9. 发明授权

US5762822A Dimensionally stable closed cell rigid polyisocyanate based foam prepared from a froth foaming mixture 失效
标题翻译：由泡沫发泡混合物制备的尺寸稳定的闭孔刚性多异氰酸酯基泡沫
公开(公告)号：US5762822A
公开(公告)日：1998-06-09
申请号：US367032
申请日：1994-12-29
申请人： John R. Tucker
发明人： John R. Tucker
IPC分类号： C08G18/66 , C08J9/14 , C09K3/00
CPC分类号： C08J9/149 , C08G18/6692 , C08J9/146 , C08G2101/0025 , C08G2101/005 , C08J2205/052 , C08J2205/10 , C08J2375/04
摘要： There is now provided a closed cell rigid polyisocyanate based foam blown with a C.sub.1 -C.sub.4 hydrofluorocarbon and formic acid as blowing agents, which possesses a uniform density gradient varying by not more than 10 percent. There is also now provided a polyol composition and a froth foaming mixture having good flow by employing a polyol and formic acid in the presence of a C.sub.1 -C.sub.4 hydrofluorocarbon having a boiling point of 300 K or less as co-blowing agents. The polyol composition advantageously has an average OH number of less than 400 and an average functionality of greater than 4, which when reacted with the isocyanate in the presence of a C.sub.1 -C.sub.4 hydrofluorocarbon, yields a rigid closed cell polyisocyanate based dimensionally stable foam having a fine cell structure.
摘要翻译：现在提供了以C1-C4氢氟烃和甲酸为发泡剂吹制的密闭单元刚性多异氰酸酯基泡沫，其具有均匀的密度梯度，其变化不超过10％。现在还提供一种多元醇组合物和泡沫发泡混合物，其在沸点为300K以下的C 1 -C 4氢氟烃作为共发泡剂的存在下，使用多元醇和甲酸，具有良好的流动性。多元醇组合物有利地具有小于400的平均OH值和大于4的平均官能度，当其在C1-C4氢氟烃的存在下与异氰酸酯反应时，得到刚性闭孔聚异氰酸酯基尺寸稳定的泡沫体，其具有细胞细胞结构。

10. 发明授权

US5455283A Dimensionally stable closed cell rigid polyisocyanate based foam prepared from a froth foaming mixture 失效
标题翻译：由泡沫发泡混合物制备的尺寸稳定的闭孔刚性多异氰酸酯基泡沫
公开(公告)号：US5455283A
公开(公告)日：1995-10-03
申请号：US420163
申请日：1995-04-11
申请人： Todd J. Green , John R. Tucker
发明人： Todd J. Green , John R. Tucker
IPC分类号： C08G18/18 , C08G18/20 , C08J9/14 , C08G18/12
CPC分类号： C08J9/146 , C08G18/1833 , C08G18/2081 , C08G2101/0025 , C08J2375/04
摘要： There is now provided a closed cell rigid polyisocyanate based foam blowing with a C.sub.1 -C.sub.4 hydrofluorocarbon and water as blowing agents, which possesses a uniform density gradient varying by not more than 10 percent. There is also now provided a froth foaming mixture having good flow by employing a hydroxy terminated polyol which is pH neutral and a tertiary amine ether blow catalyst in an amount of 0.5 weight percent or more, using water and a C.sub.1 -C.sub.4 hydrofluorocarbon having a boiling point of 300.degree. K. or less as co-blowing agents.There is also provided a polyol composition having an average OH number of less than 400 and an average functionality of greater than 4, which when reacted with the isocyanate in the presence of a C.sub.1 -C.sub.4 hydrofluorocarbon, yields a rigid closed cell polyisocyanate based dimensionally stable foam.The formulation according to an especially preferred embodiment of the invention simultaneously satisfies the following requirements:1) a formulated polyol composition having a viscosity of 550 cP or less;2) the isocyanate stream and the formulated polyol stream dispensable at a 0.9:1 to 1.3:1 weight ratio, respectively;3) frothing when dispensed from a static mixer;4) produces a frothing foaming mixture having excellent flow characteristics as demonstrated by a substantially uniform density gradient;5) and produces a dimensionally stable dosed cell foam having a low overall density of 2.5 pcf or less.
摘要翻译：现在提供了以C1-C4氢氟烃和水作为发泡剂吹制的密闭单元刚性多异氰酸酯基泡沫，其具有不超过10％的均匀密度梯度。现在还使用水和具有沸点的C 1 -C 4氢氟碳化合物，通过使用pH中性的羟基封端的多元醇和叔胺醚吹制催化剂的量为0.5重量％以上，提供了具有良好流动性的泡沫发泡混合物 300℃以下作为共发泡剂。还提供了平均OH值小于400且平均官能度大于4的多元醇组合物，其在C1-C4氢氟碳化合物的存在下与异氰酸酯反应时产生尺寸稳定的刚性闭孔聚异氰酸酯泡沫。根据本发明特别优选的实施方案的制剂同时满足以下要求：1）粘度为550cP以下的配制多元醇组合物; 2）异氰酸酯流和配制的多元醇流分别以0.9:1至1.3:1的重量比分配; 3）从静态混合器分配时发泡; 4）产生具有优异流动特性的发泡发泡混合物，如通过基本均匀的密度梯度所证明的; 5），并产生具有2.5PCF或更低的总体密度低的尺寸稳定的剂量泡沫体。

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