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    • 2. 发明授权
    • Alkyl-modified vinyl alcohol polymer solution
    • 烷基改性乙烯醇聚合物溶液
    • US09303146B2
    • 2016-04-05
    • US14351734
    • 2012-10-11
    • KURARAY CO., LTD
    • Yuta TaokaShinsuke NiiMasato Nakamae
    • C08K5/06C08K5/42C08K3/20C08F216/06C08L71/02
    • C08K5/42C08F8/12C08F216/06C08K3/20C08K5/06C08L71/02C08F218/08C08F220/54C08L29/04
    • An alkyl-modified PVA solution is provided which has low viscosity at high temperatures leading to superior handleability, accompanied by rapidly increased viscosity upon lowering of the temperature, even in the case in which the concentration of the alkyl-modified PVA in a solution is increased. An alkyl-modified vinyl alcohol polymer solution containing an alkyl-modified vinyl alcohol polymer, a surfactant and water. The alkyl-modified vinyl alcohol polymer has a monomer unit that includes an alkyl group having 5 to 29 carbon atoms. The percentage content of the monomer unit is no less than 0.05 mol % and no greater than 5 mol %. The degree of saponification of the alkyl-modified vinyl alcohol polymer is no less than 20 mol % and no greater than 99.99 mol %. The surfactant is a compound represented by the following formula (I) having hydrophilic groups X1 and X2, and an alkyleneoxy group having 3 to 5 carbon atoms (—R1—O—). X1—OR1—OmR2—X2  (I)
    • 提供烷基改性的PVA溶液,其在高温下具有低粘度,导致优异的可操作性,伴随着降低温度时粘度迅速增加,即使在溶液中烷基改性PVA的浓度增加的情况下 。 含烷基改性乙烯醇聚合物,表面活性剂和水的烷基改性乙烯醇聚合物溶液。 烷基改性的乙烯醇聚合物具有包含碳原子数为5〜29的烷基的单体单元。 单体单元的含量百分比不小于0.05mol%且不大于5mol%。 烷基改性乙烯醇系聚合物的皂化度为20摩尔%以上,99.99摩尔%以下。 表面活性剂是具有亲水基团X1和X2以及具有3至5个碳原子的亚烷基氧基(-R1-O-)的下式(I)表示的化合物。 X1-OR1-OmR2-X2(I)
    • 4. 发明申请
    • ALKYL-MODIFIED VINYL ALCOHOL POLYMER SOLUTION
    • 烷基改性的乙烯醇聚合物溶液
    • US20140243462A1
    • 2014-08-28
    • US14351734
    • 2012-10-11
    • KURARAY CO., LTD.
    • Yuta TaokaShinsuke NiiMasato Nakamae
    • C08K5/06C08K3/20C08K5/42
    • C08K5/42C08F8/12C08F216/06C08K3/20C08K5/06C08L71/02C08F218/08C08F220/54C08L29/04
    • An alkyl-modified PVA solution is provided which has low viscosity at high temperatures leading to superior handleability, accompanied by rapidly increased viscosity upon lowering of the temperature, even in the case in which the concentration of the alkyl-modified PVA in a solution is increased. An alkyl-modified vinyl alcohol polymer solution containing an alkyl-modified vinyl alcohol polymer, a surfactant and water. The alkyl-modified vinyl alcohol polymer has a monomer unit that includes an alkyl group having 5 to 29 carbon atoms. The percentage content of the monomer unit is no less than 0.05 mol % and no greater than 5 mol %. The degree of saponification of the alkyl-modified vinyl alcohol polymer is no less than 20 mol % and no greater than 99.99 mol %. The surfactant is a compound represented by the following formula (I) having hydrophilic groups X1 and X2, and an alkyleneoxy group having 3 to 5 carbon atoms (—R1—O—). X1—OR1—OmR2—X2  (I)
    • 提供烷基改性的PVA溶液,其在高温下具有低粘度,导致优异的可操作性,伴随着降低温度时粘度迅速增加,即使在溶液中烷基改性PVA的浓度增加的情况下 。 含烷基改性乙烯醇聚合物,表面活性剂和水的烷基改性乙烯醇聚合物溶液。 烷基改性的乙烯醇聚合物具有包含碳原子数为5〜29的烷基的单体单元。 单体单元的含量百分比不小于0.05mol%且不大于5mol%。 烷基改性乙烯醇系聚合物的皂化度为20摩尔%以上,99.99摩尔%以下。 表面活性剂是具有亲水基团X1和X2以及具有3至5个碳原子的亚烷基氧基(-R1-O-)的下式(I)表示的化合物。 X1-OR1R1-O-mR2-X2(I)