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    • 1. 发明授权
    • Extrudable halogen-free mixture
    • 可挤出无卤素混合物
    • US06140411A
    • 2000-10-31
    • US305118
    • 1999-05-04
    • Klaus SchwambornWalter SteffesManfred Sikora
    • Klaus SchwambornWalter SteffesManfred Sikora
    • C08L79/08C08L83/10C08L83/00
    • C08L79/08C08L83/10
    • Extrudable halogen-free mixture comprising 95-5 weight-% polyetherimide polymer with an elastic modulus greater than 2000 MPa and 5-95 weight-% flexible siloxane-polyetherimide copolymer with an elastic modulus of less than 2000 MPa. Electrical cable or wiring insulated with the extrudable halogen-free mixture comprising 60-90 weight-% of a polyetherimide polymer with an elastic modulus greater than 2000 MPa and 40-10 weight-% of a flexible siloxane-polyetherimide copolymer with an elastic modulus of less than 1000 MPa. Electrical or optical cable or tubing sheathed with the extrudable halogen-free mixture comprising 40-10 weight-% of a polyetherimide polymer with an elastic modulus greater than 2000 MPa and 60-90 weight-% of a flexible siloxane-polyetherimide copolymer with an elastic modulus of less than 1000 MPa. The extrudable halogen-free mixtures may additionally comprise reinforcement elements selected from the group consisting of glass fibers, carbon fibers, and mixtures thereof, flame-retardant additives selected from the group consisting of aluminum hydroxide, magnesium hydroxide, and mixtures thereof, and color pigments. The extrudable halogen-free mixtures may be cross-linked. A process for the manufacture of workable granulates of an extrudable halogen-free mixture which comprises the steps of: a.) drying a polyetherimide polymer with an elastic modulus greater than 2000 MPa, b.) drying a flexible siloxane-polyetherimide copolymer with an elastic modulus less than 2000 MPa, c.) combining 95-5 weight-% of said polyetherimide polymer with an elastic modulus greater than 2000 MPa with 5-95 weight-% of said flexible siloxane-polyetherimide copolymer with an elastic modulus of less than 2000 MPa to form a mixture batch, d.) melting said mixture batch to form a melt, and e.) extruding said melt to produce a workable granulate.
    • 包含弹性模量大于2000MPa的95-5重量%聚醚酰亚胺聚合物和弹性模量小于2000MPa的5-95重量%柔性硅氧烷 - 聚醚酰亚胺共聚物的可挤出无卤混合物。 用可挤出的无卤素混合物绝缘的电缆或布线包含60-90重量%的弹性模量大于2000MPa的聚醚酰亚胺聚合物和40-10重量%的柔软硅氧烷 - 聚醚酰亚胺共聚物,其弹性模量为 小于1000MPa。 包含40-10重量%弹性模量大于2000MPa的聚醚酰亚胺聚合物和60-90重量%的具有弹性的柔性硅氧烷 - 聚醚酰亚胺共聚物的可挤出无卤素混合物的电缆或光缆或管材 模量小于1000MPa。 可挤出的无卤素混合物可以另外包含选自玻璃纤维,碳纤维及其混合物的增强元素,选自氢氧化铝,氢氧化镁及其混合物的阻燃添加剂和彩色颜料 。 可挤出的无卤素混合物可以是交联的。 一种用于制造可挤出无卤素混合物的可加工颗粒的方法,其包括以下步骤:a)将具有大于2000MPa的弹性模量的聚醚酰亚胺聚合物干燥,b)将具有弹性的柔性硅氧烷 - 聚醚酰亚胺共聚物 模量小于2000MPa,c。)将95-5重量%的所述聚醚酰亚胺聚合物与弹性模量大于2000MPa的5-95重量%的弹性模量小于2000的所述柔性硅氧烷 - 聚醚酰亚胺共聚物 以形成混合物批料,d。)熔化所述混合物批料以形成熔体,e)挤出所述熔体以产生可加工的颗粒。