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    • 1. 发明申请
    • LITHIUM SECONDARY BATTERY
    • 锂二次电池
    • US20120258343A1
    • 2012-10-11
    • US13516259
    • 2009-12-17
    • Koji TakahataHideki Sano
    • Koji TakahataHideki Sano
    • H01M10/36H01M10/04H01M4/04
    • H01M10/0525H01M4/131H01M4/621H01M10/052H01M10/0587Y10T29/49108
    • A lithium secondary battery obtained by the present invention has a negative electrode sheet 20 in which the theoretical capacities of the negative active material per unit area are equalized in a negative active material layer 24b on the outer circumference side and a negative active material layer 24a on the inner circumference side of a negative electrode collector 22, and at least one of the following conditions is met with respect to at least part of a bent section 85, which is bent toward the inside of a wound electrode body 80: (1) the percentage content of binder of the outer negative active material layer 24b is smaller than the percentage content of binder of the inner negative active material layer 24a; and (2) the density of the outer negative active material layer 24b is smaller than the density of the inner negative active material layer 24a.
    • 通过本发明获得的锂二次电池具有负极片20,其中负极活性物质每单位面积的理论容量在外周侧的负极活性物质层24b和 负电极集电体22的内周侧,以及至少部分朝向卷绕电极体80的内侧弯曲的弯曲部85的至少一部分满足以下条件中的至少一个:(1) 外负极活性物质层24b的粘合剂的含量百分比小于内负极活性物质层24a的粘合剂的含量百分比; 和(2)外部负极活性物质层24b的密度小于内侧负极活性物质层24a的密度。
    • 3. 发明授权
    • Negative electrode containing graphite for lithium ion secondary battery
    • 锂离子二次电池用负极含石墨
    • US08936875B2
    • 2015-01-20
    • US12937419
    • 2009-12-16
    • Koji TakahataHideki Sano
    • Koji TakahataHideki Sano
    • H01M4/133H01M4/583H01M10/0525H01M10/056H01M10/0566
    • H01M10/0525H01M4/133H01M10/0566Y02E60/122Y02T10/7011
    • In a lithium ion secondary battery, an electrode assembly, in which a positive electrode sheet having a positive electrode mixture layer and a negative electrode sheet having a negative electrode mixture layer are overlain each other, is housed in a container together with a nonaqueous electrolyte solution. The negative electrode mixture layer includes a carbon material having at least in part a graphite structure as a negative active material. When S (m2) represents a value obtained by calculating a total surface area of the negative electrode active material included in a region of the negative electrode mixture layer lying opposite the positive electrode mixture layer per 1 Ah of capacity of the battery, V represents a value obtained by calculating a total volume of pores included in the region of the negative electrode mixture layer per 1 Ah of capacity of the battery, and N represents the number of lithium ions included within the volume V of the nonaqueous electrolyte solution, the value α computed by the formula α=S×N is from 1×1022 to 2.5×1022.
    • 在锂离子二次电池中,将具有正极复合层的正极片和具有负极混合层的负极片彼此重叠的电极组件与非水电解质溶液一起容纳在容器中 。 负极混合物层包括至少部分具有作为负极活性物质的石墨结构的碳材料。 当S(m2)表示通过计算负极活性物质的总表面积而得到的值,该负极活性物质的总面积与负极混合物层的与电池容量的每Ah容量相对的区域相对,V表示 通过计算每单位电池容量的负极混合物层的区域中包含的孔的总体积得到的值,N表示包含在非水电解液的体积V内的锂离子数,值α 由公式α= S×N计算为1×1022〜2.5×1022。
    • 5. 发明申请
    • LITHIUM ION SECONDARY BATTERY
    • 锂离子二次电池
    • US20120244417A1
    • 2012-09-27
    • US12937419
    • 2009-12-16
    • Koji TakahataHideki Sano
    • Koji TakahataHideki Sano
    • H01M2/02H01M4/583
    • H01M10/0525H01M4/133H01M10/0566Y02E60/122Y02T10/7011
    • The present invention provides a lithium ion secondary battery in which an electrode assembly, in which a positive electrode sheet having a positive electrode mixture layer and a negative electrode sheet having a negative electrode mixture layer are overlain each other, is housed in a container together with a nonaqueous electrolyte solution. The negative electrode mixture layer includes a carbon material having at least in part a graphite structure as a negative active material. When S (m2) represents a value obtained by calculating a total surface area of the negative electrode active material included in a region of the negative electrode mixture layer lying opposite the positive electrode mixture layer per 1 Ah of capacity of the battery, V represents a value obtained by calculating a total volume of pores included in the region of the negative electrode mixture layer per 1 Ah of capacity of the battery, and N represents the number of lithium ions included within the volume V of the nonaqueous electrolyte solution, the value α computed by the formula α=S×N is from 1×1025 to 2.5×1025.
    • 本发明提供一种锂离子二次电池,其中将具有正极合剂层的正极片和具有负极混合层的负极片彼此重叠的电极组件与容器一起容纳在容器中,以及 非水电解液。 负极混合物层包括至少部分具有作为负极活性物质的石墨结构的碳材料。 当S(m2)表示通过计算负极活性物质的总表面积而得到的值,该负极活性物质的总面积与负极混合物层的与电池容量的每Ah容量相对的区域相对,V表示 通过计算每单位电池容量的负极混合物层的区域中包含的孔的总体积得到的值,N表示包含在非水电解液的体积V内的锂离子数,值α 由公式α= S×N计算为1×1025〜2.5×1025。
    • 6. 发明申请
    • LITHIUM-ION SECONDARY BATTERY
    • 锂离子二次电池
    • US20140170487A1
    • 2014-06-19
    • US14235471
    • 2011-07-29
    • Koji TakahataHideki Sano
    • Koji TakahataHideki Sano
    • H01M4/587H01M4/04H01M4/1393
    • H01M4/0404H01M4/133H01M4/1393H01M4/364H01M4/587H01M10/0525Y02E60/122Y02P70/54Y02T10/7011
    • A negative electrode sheet of a lithium-ion secondary battery has a negative electrode current collector and a negative electrode active material layer on the negative electrode current collector. The negative electrode active material layer contains flake graphite particles and has a first region neighboring the negative electrode current collector and a second region neighboring a surface side that are different in perpendicularity of the graphite particles. The perpendicularity of the graphite particles is defined as (m1/m2), where, when the inclination θn of each of the graphite particles is specified relative to a surface of the negative electrode current collector, m1 is the number of the graphite particles having an inclination θn of 60°≦θn≦90° and m2 is the number of the graphite particles having an inclination θn of 0°≦θn≦30°.
    • 锂离子二次电池的负极片在负极集电体上具有负极集电体和负极活性物质层。 负极活性物质层含有片状石墨粒子,具有与负极集电体相邻的第一区域和与石墨粒子的垂直度不同的与表面侧相邻的第二区域。 石墨颗粒的垂直度定义为(m1 / m2),其中当相对于负极集电体的表面规定每个石墨颗粒的倾斜度和n时,m1是石墨颗粒的数量 具有倾斜度和角度; n为60°≦̸θ为n≦̸ 90°和m2为具有倾斜角度的石墨颗粒的数量; n为0°≦̸ n为n≦̸ 30°。
    • 7. 发明授权
    • Lithium-ion secondary battery
    • 锂离子二次电池
    • US09553299B2
    • 2017-01-24
    • US14235471
    • 2011-07-29
    • Koji TakahataHideki Sano
    • Koji TakahataHideki Sano
    • H01M4/587H01M4/04H01M4/133H01M4/1393H01M4/36H01M10/0525
    • H01M4/0404H01M4/133H01M4/1393H01M4/364H01M4/587H01M10/0525Y02E60/122Y02P70/54Y02T10/7011
    • A negative electrode sheet of a lithium-ion secondary battery has a negative electrode current collector and a negative electrode active material layer on the negative electrode current collector. The negative electrode active material layer contains flake graphite particles and has a first region neighboring the negative electrode current collector and a second region neighboring a surface side that are different in perpendicularity of the graphite particles. The perpendicularity of the graphite particles is defined as (m1/m2), where, when the inclination θn of each of the graphite particles is specified relative to a surface of the negative electrode current collector, m1 is the number of the graphite particles having an inclination θn of 60°≦θn≦90° and m2 is the number of the graphite particles having an inclination θn of 0°≦θn≦30°.
    • 锂离子二次电池的负极片在负极集电体上具有负极集电体和负极活性物质层。 负极活性物质层含有片状石墨粒子,具有与负极集电体相邻的第一区域和与石墨粒子的垂直度不同的与表面侧相邻的第二区域。 石墨颗粒的垂直度定义为(m1 / m2),其中当相对于负极集电体的表面规定每个石墨颗粒的倾斜度θn时,m1是具有 倾角θn为60°≤θn≤90°,m2为倾斜度θn为0°≤θn≤30°的石墨颗粒的数量。