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1. 发明授权

US07884172B2 Tetraglycidyl ether of 1,1,2,2-tetrakis(hydroxyphenyl)ethane 有权
标题翻译： 1,1,2,2-四（羟基苯基）乙烷的四缩水甘油醚
公开(公告)号：US07884172B2
公开(公告)日：2011-02-08
申请号：US12083284
申请日：2006-10-10
申请人： Masataka Nakanishi , Katsuhiko Oshimi , Ryutaro Tanaka , Toru Kurihashi
发明人： Masataka Nakanishi , Katsuhiko Oshimi , Ryutaro Tanaka , Toru Kurihashi
IPC分类号： C08G59/06 , C08L63/00
CPC分类号： C08G59/32 , C08G59/42
摘要： To provide an epoxy resin giving a cured object having high heat resistance, which is improved in impact resistance and moisture resistance as compared with conventional high-heat-resistance epoxy resins.The epoxy resin is obtained by glycidylating one or more phenol compounds comprising 95% or more 1,1,2,2-tetrakis (hydroxyphenyl)ethane, and is characterized in that in an examination by gel permeation chromatography, the epoxy resin has a tetranucleus-form content of 50 to 90% by area and an octanucleus-form content of at least 5% by area and has a total chlorine content of 5,000 ppm or smaller.
摘要翻译：为了提供具有高耐热性的固化物的环氧树脂，与常规的高耐热性环氧树脂相比，其耐冲击性和耐湿性得到改善。环氧树脂通过将一种或多种包含95％或更多的1,1,2,2-四（羟基苯基）乙烷的酚化合物缩水甘油化而获得，其特征在于在通过凝胶渗透色谱法的检查中，环氧树脂具有四核形式的含量为50〜90％的面积，8个核形式的含量为5面积％以上，总氯含量为5000ppm以下。

2. 发明申请

US20090131607A1 Epoxy Resin, Epoxy Resin Composition, Photosensitive Resin Composition and Cured Object Obtained Therefrom 有权
标题翻译：环氧树脂，环氧树脂组合物，感光树脂组合物和其中获得的固化物
公开(公告)号：US20090131607A1
公开(公告)日：2009-05-21
申请号：US12083284
申请日：2006-10-10
申请人： Masataka Nakanishi , Katsuhiko Oshimi , Ryutaro Tanaka , Toru Kurihashi
发明人： Masataka Nakanishi , Katsuhiko Oshimi , Ryutaro Tanaka , Toru Kurihashi
IPC分类号： C08L63/00 , C08G59/06
CPC分类号： C08G59/32 , C08G59/42
摘要： [Problems] To provide an epoxy resin giving a cured object having high heat resistance, which is improved in impact resistance and moisture resistance as compared with conventional high-heat-resistance epoxy resins.[Means for Solving Problems] The epoxy resin is obtained by glycidylating one or more phenol compounds comprising 95% or more 1,1,2,2-tetrakis(hydroxyphenyl)ethane, and is characterized in that in an examination by gel permeation chromatography, the epoxy resin has a tetranucleus-form content of 50 to 90% by area and an octanucleus-form content of at least 5% by area and has a total chlorine content of 5,000 ppm or smaller.
摘要翻译： [问题]提供与常规的高耐热性环氧树脂相比，具有高耐热性的固化物质的环氧树脂，其耐冲击性和耐湿性得到改善。解决问题的手段环氧树脂通过使包含95％以上的1,1,2,2-四（羟基苯基）乙烷的一种或多种酚化合物缩水甘油化而得到，其特征在于，在通过凝胶渗透色谱法的检查中，环氧树脂具有面积为50至90％的四核形式含量和至少5％（面积）的八核形式含量，并且总氯含量为5,000ppm或更小。

3. 发明授权

US08198381B2 Phenol aralkyl epoxy resin with secondary hydroxyl groups 失效
标题翻译：具有仲羟基的苯酚芳烷基环氧树脂
公开(公告)号：US08198381B2
公开(公告)日：2012-06-12
申请号：US12083030
申请日：2006-10-16
申请人： Masataka Nakanishi , Katsuhiko Oshimi , Kazuyuki Ohhashi , Toru Kurihashi
发明人： Masataka Nakanishi , Katsuhiko Oshimi , Kazuyuki Ohhashi , Toru Kurihashi
IPC分类号： C08K5/07 , C08K5/16 , C08K5/523 , C08L61/14 , C08L63/00
CPC分类号： C08G59/245 , B32B5/26 , B32B15/08 , B32B2260/023 , B32B2260/046 , B32B2262/0261 , B32B2262/0276 , B32B2262/10 , B32B2262/101 , B32B2262/106 , B32B2307/206 , B32B2307/306 , B32B2307/50 , B32B2307/546 , B32B2307/718 , B32B2457/04 , B32B2457/08 , C08J5/24 , C08J2363/00 , Y10T428/31511
摘要： Disclosed is a phenol aralkyl epoxy resin having a structure wherein at least a phenol or a naphthol is bound by using an aralkyl group as a linking group and a structure represented by formula (1) below, while satisfying the condition 1 below. This epoxy resin is excellent in workability during production of a composition and is easy to control quality. Condition 1: The following relation (α) is satisfied with A being the hydroxyl equivalent (as measured in accordance with JIS K 0070) of a phenol-modified epoxy resin obtained by adding an equivalent molar amount of phenol relative to the epoxy equivalent of the epoxy resin, and B being the epoxy equivalent of the epoxy resin. 50≦1000×(A−B)/B≦250 (α).
摘要翻译：公开了一种苯酚芳烷基环氧树脂，其具有以下结构，其中在满足下述条件1的同时，通过使用芳烷基作为连接基团和式（1）表示的结构，至少使苯酚或萘酚结合。该环氧树脂在组合物的制造中的加工性优异，容易控制质量。条件1：通过将等当量的苯酚相对于环氧当量添加而得到的酚改性环氧树脂的羟基当量（根据JIS K 0070测定）满足以下关系式（α）环氧树脂，B为环氧树脂的环氧当量。 50＆nlE; 1000×（A-B）/ B＆nlE; 250（α）。

4. 发明申请

US20090117388A1 Epoxy Resin, Curable Resin Composition and Cured Product Thereof 失效
标题翻译：环氧树脂，可固化树脂组合物及其固化产物
公开(公告)号：US20090117388A1
公开(公告)日：2009-05-07
申请号：US12083030
申请日：2006-10-16
申请人： Masataka Nakanishi , Katsuhiko Oshimi , Kazuyuki Ohhashi , Toru Kurihashi
发明人： Masataka Nakanishi , Katsuhiko Oshimi , Kazuyuki Ohhashi , Toru Kurihashi
IPC分类号： B32B27/38 , C08G65/38 , C08L71/02 , C08L75/04 , C08K9/00
CPC分类号： C08G59/245 , B32B5/26 , B32B15/08 , B32B2260/023 , B32B2260/046 , B32B2262/0261 , B32B2262/0276 , B32B2262/10 , B32B2262/101 , B32B2262/106 , B32B2307/206 , B32B2307/306 , B32B2307/50 , B32B2307/546 , B32B2307/718 , B32B2457/04 , B32B2457/08 , C08J5/24 , C08J2363/00 , Y10T428/31511
摘要： Disclosed is a phenol aralkyl epoxy resin having a structure wherein at least a phenol or a naphthol is bound by using an aralkyl group as a linking group and a structure represented by formula (1) below, while satisfying the condition 1 below. This epoxy resin is excellent in workability during production of a composition and is easy to control quality. Condition 1: The following relation (α) is satisfied with A being the hydroxyl equivalent (as measured in accordance with JIS K 0070) of a phenol-modified epoxy resin obtained by adding an equivalent molar amount of phenol relative to the epoxy equivalent of the epoxy resin, and B being the epoxy equivalent of the epoxy resin. 50≦1000×(A−B)/B≦250 (α)
摘要翻译：公开了一种苯酚芳烷基环氧树脂，其具有以下结构，其中在满足下述条件1的同时，通过使用芳烷基作为连接基团和式（1）表示的结构，至少使苯酚或萘酚结合。该环氧树脂在组合物的制造中的加工性优异，容易控制质量。条件1：通过将等摩尔量的苯酚相对于环氧当量添加而得到的苯酚改性环氧树脂的羟基当量（按照JIS K 0070测定）满足下列关系式（α）：环氧树脂，B为环氧树脂的环氧当量。 50 <= 1000x（A-B）/ B <= 250（α）

5. 发明申请

US20130323994A1 Epoxy Resin Composition For Transparent Sheets And Cured Product Thereof 有权
标题翻译：环氧树脂组合物透明片及其固化产品
公开(公告)号：US20130323994A1
公开(公告)日：2013-12-05
申请号：US13878564
申请日：2011-11-15
申请人： Noriko Kiyoyanagi , Masataka Nakanishi , Yoshihiro Kawata , Junko Ichikawa , Toru Kurihashi
发明人： Noriko Kiyoyanagi , Masataka Nakanishi , Yoshihiro Kawata , Junko Ichikawa , Toru Kurihashi
IPC分类号： C08K5/12 , D06M15/55
CPC分类号： C08G59/4215 , C03C17/326 , C08G59/4246 , C08K5/12 , C08L63/00 , C08L67/02 , C08L2201/08 , C08L2201/10 , C08L2205/025 , C09D163/00 , D06M15/55 , G02B1/04 , G02B1/14 , Y10T442/2951
摘要： To provide an epoxy resin composition that is suitable for producing optical sheets which exhibit excellent transparency, heat resistance, strength, smoothness and light resistance, and a cured product thereof.An epoxy resin composition for optical3 sheets, the composition comprising a polyvalent carboxylic acid (A) represented by formula (I): (wherein, R1's each independently represent a hydrogen atom, an alkyl group having 1 to 15 carbon atoms, or a carboxyl group; q represents the number of substituent R1's, and represents an integer from 1 to 4; and P represents any one of the following x, y and z): (wherein, there may be a plural number of R2's per ring, and R2's each independently represent a hydrogen atom or a methyl group; and * represents a bonding site linked to the oxygen atom; y. A linear alkylene linker having 6 to 20 carbon atoms, with a main chain having 3 or more carbon atoms and being substituted with an alkyl group in at least one site); (wherein, R's each independently represent a hydrogen atom, an alkyl group having 1 to 15 carbon atoms, or a carboxyl group; and * represents a bonding site linked to the oxygen atom, and an epoxy resin (B) having an aliphatic cyclic structure in the molecule).
摘要翻译：提供一种适用于制造透明性，耐热性，强度，光滑性，耐光性优异的光学片的环氧树脂组合物及其固化物。用于光学3片的环氧树脂组合物，该组合物包含由式（I）表示的多价羧酸（A）：（其中，R 1各自独立地表示氢原子，具有1至15个碳原子的烷基或羧基 ; q表示取代基R 1的数，表示1〜4的整数，P表示以下x，y，z中的任一个：（其中，每个环可以有多个R 2，独立地表示氢原子或甲基; *表示与氧原子连接的键合位置; y。具有6〜20个碳原子的直链亚烷基连接体，具有3个以上碳原子的主链，并被至少一个位点的烷基）; （其中，R 3各自独立地表示氢原子，碳原子数1〜15的烷基或羧基; *表示与氧原子连接的键合位置，具有脂肪族环状结构的环氧树脂（B）在分子中）。

6. 发明申请

US20080268373A1 Imide-Urethane Resin, Photosensitive Resin Composition Including the Same and Cured Product 失效
标题翻译：酰胺 - 聚氨酯树脂，包含其的固化产物的光敏树脂组合物
公开(公告)号：US20080268373A1
公开(公告)日：2008-10-30
申请号：US12083029
申请日：2006-10-05
申请人： Ryutaro Tanaka , Toru Kurihashi
发明人： Ryutaro Tanaka , Toru Kurihashi
IPC分类号： G03C1/73 , C08G18/72
CPC分类号： C08F283/006 , C08F290/06 , C08F290/067 , C08G18/346 , C08G18/672 , C08G18/73 , C08G18/755 , C08G73/1035 , C09D175/16 , G03F7/027 , G03F7/038
摘要： [PROBLEMS] To provide a photosensitive resin composition which has excellent photosensitivity and gives a cured product reduced in warpage and excellent in flexing properties, adhesion, pencil hardness, solvent resistance, acid resistance, heat resistance, resistance to gold plating, etc.[MEANS FOR SOLVING PROBLEMS] A urethane resin (A) soluble in aqueous alkali solutions and curable with active energy rays which is obtained by reacting a diisocyanate compound (a) with a tetrabasic acid dianhydride (b) to obtain a compound (E), reacting the compound (E) with a hydroxylated compound (c) having an unsaturated group and optionally with a hydroxylated compound (d) other than the compound (c) to obtain a compound (F), and further reacting hydroxy groups of the compound (F) with a diisocyanate compound (e).
摘要翻译：本发明提供光敏性优异的感光性树脂组合物，使弯曲性降低，弯曲性，粘合性，铅笔硬度，耐溶剂性，耐酸性，耐热性，耐镀金性等优异的固化物。[MEANS 用于解决问题的聚氨酯树脂（A）可溶于碱性水溶液并用活性能量射线固化的聚氨酯树脂（A），其通过使二异氰酸酯化合物（a）与四元酸二酐（b）反应得到化合物（E），使化合物（E）与具有不饱和基团的羟基化合物（c）和任选与化合物（c）以外的羟化化合物（d）反应得到化合物（F），进一步使化合物（F）的羟基反应，与二异氰酸酯化合物（e）。

7. 发明授权

US09328217B2 Epoxy resin composition for transparent sheets and cured product thereof 有权
标题翻译：透明片用环氧树脂组合物及其固化物
公开(公告)号：US09328217B2
公开(公告)日：2016-05-03
申请号：US13878564
申请日：2011-11-15
申请人： Noriko Kiyoyanagi , Masataka Nakanishi , Yoshihiro Kawata , Junko Ichikawa , Toru Kurihashi
发明人： Noriko Kiyoyanagi , Masataka Nakanishi , Yoshihiro Kawata , Junko Ichikawa , Toru Kurihashi
IPC分类号： C08L63/00 , C08K5/12 , C08G59/42 , G02B1/04 , D06M15/55
CPC分类号： C08G59/4215 , C03C17/326 , C08G59/4246 , C08K5/12 , C08L63/00 , C08L67/02 , C08L2201/08 , C08L2201/10 , C08L2205/025 , C09D163/00 , D06M15/55 , G02B1/04 , G02B1/14 , Y10T442/2951
摘要： An epoxy resin composition for optical sheets, the composition comprising a polyvalent carboxylic acid (A) represented by formula (I): wherein R1's each independently represent a hydrogen atom, an alkyl group having 1 to 15 carbon atoms, or a carboxyl group; q represents the number of substituent R1's, and represents an integer from 1 to 4; and P represents the following X: wherein there may be a plural number of R2's per ring, and R2's each independently represent a hydrogen atom or a methyl group; and * represents a bonding site linked to the oxygen atom; and an epoxy resin (B) having an aliphatic cyclic structure in the molecule.
摘要翻译：用于光学片的环氧树脂组合物，该组合物包含由式（I）表示的多价羧酸（A）：其中R 1各自独立地表示氢原子，具有1至15个碳原子的烷基或羧基; q表示取代基R 1的数，表示1〜4的整数。并且P表示以下X：其中每个环可以有多个R 2，并且R 2各自独立地表示氢原子或甲基; 和*表示与氧原子连接的键合位置; 和分子内具有脂肪族环状结构的环氧树脂（B）。

8. 发明授权

US07781147B2 Imide-urethane resin, photosensitive resin composition including the same and cured product 失效
标题翻译：酰亚胺基聚氨酯树脂，含有它的感光性树脂组合物和固化物
公开(公告)号：US07781147B2
公开(公告)日：2010-08-24
申请号：US12083029
申请日：2006-10-05
申请人： Ryutaro Tanaka , Toru Kurihashi
发明人： Ryutaro Tanaka , Toru Kurihashi
IPC分类号： C08G18/67 , C08G18/30 , C08G7/038 , B32B27/40 , C08F90/06 , G03F7/027 , G03F7/038 , G03F7/40
CPC分类号： C08F283/006 , C08F290/06 , C08F290/067 , C08G18/346 , C08G18/672 , C08G18/73 , C08G18/755 , C08G73/1035 , C09D175/16 , G03F7/027 , G03F7/038
摘要： [PROBLEMS] To provide a photosensitive resin composition which has excellent photosensitivity and gives a cured product reduced in warpage and excellent in flexing properties, adhesion, pencil hardness, solvent resistance, acid resistance, heat resistance, resistance to gold plating, etc.[MEANS FOR SOLVING PROBLEMS] A urethane resin (A) soluble in aqueous alkali solutions and curable with active energy rays which is obtained by reacting a diisocyanate compound (a) with a tetrabasic acid dianhydride (b) to obtain a compound (E), reacting the compound (E) with a hydroxylated compound (c) having an unsaturated group and optionally with a hydroxylated compound (d) other than the compound (c) to obtain a compound (F), and further reacting hydroxy groups of the compound (F) with a diisocyanate compound (e).
摘要翻译：本发明提供光敏性优异的感光性树脂组合物，使弯曲性降低，弯曲性，粘合性，铅笔硬度，耐溶剂性，耐酸性，耐热性，耐镀金性等优异的固化物。[MEANS 用于解决问题的聚氨酯树脂（A）可溶于碱性水溶液并用活性能量射线固化的聚氨酯树脂（A），其通过使二异氰酸酯化合物（a）与四元酸二酐（b）反应得到化合物（E），使化合物（E）与具有不饱和基团的羟基化合物（c）和任选与化合物（c）以外的羟化化合物（d）反应得到化合物（F），进一步使化合物（F）的羟基反应，与二异氰酸酯化合物（e）。

9. 发明申请

US20090042126A1 Photosensitive resin composition and cured article thereof 审中-公开
标题翻译：光敏树脂组合物及其固化制品
公开(公告)号：US20090042126A1
公开(公告)日：2009-02-12
申请号：US11988903
申请日：2006-07-20
申请人： Ryutaro Tanaka , Toru Kurihashi , Hiroo Koyanagi
发明人： Ryutaro Tanaka , Toru Kurihashi , Hiroo Koyanagi
IPC分类号： G03F7/004
CPC分类号： C08F283/10 , C08F290/00 , C08F290/02 , C08F299/00 , C08F299/02 , C08G59/1466 , C08G59/42 , C08L63/00 , G03F7/027 , G03F7/038 , G03F7/0388 , H05K3/287
摘要： A photosensitive resin composition which is excellent in photosensitivity and excellent in flame resistance, flexibility, adhesiveness, pencil hardness, resistance to solvent, acid resistance, heat resistance, resistance to gold plating and the like and a cured article thereof are provided.An alkaline aqueous solution-soluble photosensitive resin composition containing an alkaline aqueous solution-soluble resin (A) obtained by adding a polybasic acid anhydride (c) to a resin (C) which is a reaction product of an epoxy resin (a) represented by the formula (1) with an unsaturated monocarboxylic acid (b), an epoxy resin (a′) represented by the formula (1) as a curing agent (B) and a photopolymerization initiator. [In the formula, n represents a positive number of 1 to 10 as an average value.]
摘要翻译：提供了光敏性优异，耐火性，柔韧性，粘合性，铅笔硬度，耐溶剂性，耐酸性，耐热性，耐镀金性等优异的感光性树脂组合物及其固化物。一种碱性水溶性可溶性感光性树脂组合物，其含有通过将多元酸酐（c）添加到由（C）表示的环氧树脂（a）的反应产物的树脂（C）中而获得的碱性水溶性溶液性树脂（A）具有不饱和一元羧酸（b）的式（1），作为固化剂（B）的式（1）表示的环氧树脂（a'）和光聚合引发剂。 [式中，n表示作为平均值的1〜10的正数]

10. 发明授权

US5644010A Curable liquid resin, process for the production thereof and use thereof 失效
标题翻译：可固化液体树脂，其制备方法和用途
公开(公告)号：US5644010A
公开(公告)日：1997-07-01
申请号：US503723
申请日：1995-07-18
申请人： Toru Kurihashi , Miki Kawashima , Takeo Yamaguchi
发明人： Toru Kurihashi , Miki Kawashima , Takeo Yamaguchi
IPC分类号： C08F220/18 , C08F220/28 , C08F224/00 , C07C11/12 , C07C69/54 , C07C233/16 , C08F220/04 , C08F220/10 , C08F220/58 , C08F230/00
CPC分类号： C08F220/18 , C08F220/28 , Y10S106/901
摘要： A curable liquid resin which can give a coating composition capable of forming a film, the curable liquid resin being a copolymer obtained from(A) a monomer of the formula (1) or (2),CH.sub.2 .dbd.C(R.sup.1)COO--R.sup.2 (1)CH.sub.2 .dbd.C(R.sup.3)COO(C.sub.n H.sub.2n O).sub.m--R.sup.4(2)and(B) at least one monomer selected from the group consisting of(B1) a monomer prepared by reacting an ethylenically unsaturated epoxide (a) with a fatty acid (b) of the formula (3)R.sup.5 COOH (3)(B2) a monomer of the formula (4),CH.sub.2 .dbd.C(R.sup.6)CONR.sup.7 R.sup.8 (4)and(B3) a monomer whose molecule has at least two ethylenically unsaturated double bonds.
摘要翻译：一种可以得到能够形成膜的涂料组合物的可固化液体树脂，该可固化液体树脂是由（A）式（1）或（2）的单体获得的共聚物，CH 2 = C（R 1）COO-R 2 （1）CH 2 = C（R 3）COO（C n H 2n O）m -R 4（2）和（B）至少一种选自（B1）通过烯属不饱和环氧化物（a）与式（3）的脂肪酸（b）R5COOH（3）（B2）式（4）的单体，CH2 = C（R6）CONR7R8（4）和（B3）分子具有至少两个烯属不饱和双键。

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