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    • 8. 发明申请
    • CELLULOSE ACETATE WITH A LOW DEGREE OF SUBSTITUTION
    • 具有较低取代度的纤维素乙酸酯
    • US20160032020A1
    • 2016-02-04
    • US14775369
    • 2014-03-12
    • DAICEL CORPORATION
    • Shizuka UKITAHiroki TANIGUCHIShu SHIMAMOTOToshikazu NAKAMURA
    • C08B3/06C08B3/24
    • C08B3/06C08B3/24C08B3/28C08J5/18C08J2301/12C08L1/12C08L1/14D01F2/28
    • A cellulose acetate according to the present invention has a total degree of acetyl substitution of 0.4 to 1.1 and has a compositional distribution index (CDI) of 3.0 or less, where the CDI is specified by the formula: CDI=(Measured value of half height width of chemical composition)/(Theoretical value of half height width of chemical composition) where the measured value of half height width of chemical composition is a half height width of chemical composition determined by analyzing a cellulose acetate propionate by HPLC, where the cellulose acetate propionate is prepared by propionylating all residual hydroxy groups of the cellulose acetate (sample); and Theoretical value of half height width of chemical composition=2·35482√{square root over (3*DPw*(DS/3)*(1−DS/3))}{square root over (3*DPw*(DS/3)*(1−DS/3))}/DPw  [Math. 1] where DS is the total degree of acetyl substitution; and DPw is a weight-average degree of polymerization determined by a GPC-light scattering method using a cellulose acetate propionate prepared by propionylating all residual hydroxy groups of the cellulose acetate (sample).
    • 本发明的乙酸纤维素的总乙酰基取代度为0.4〜1.1,组成分布指数(CDI)为3.0以下,其中CDI由下式确定:CDI =(半高度的测定值 化学成分的宽度)/化学成分的半高宽度的测定值为通过HPLC分析醋酸丙酸纤维素而测定的化学成分的半高宽度的化学成分的半高宽度的理论值,其中乙酸纤维素 通过丙酰化乙酸纤维素(样品)的所有残留羟基来制备丙酸酯; (3 * DPw *(DS / 3)*(1-DS / 3))} {平方根超过(3 * DPw *(DS))的化学成分的半高宽度的理论值= 2·35482 / 3)*(1-DS / 3))} / DPw [ 1]其中DS是乙酰基取代的总量; DPw是通过使用通过丙酰化乙酸纤维素(样品)的所有残留羟基制备的丙酸纤维素的GPC-光散射法测定的重均聚合度。