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1. 发明申请

US20100093876A1 FISCHER-TROPSCH CATALYST 失效
标题翻译： FISCHER-TROPSCH催化剂
公开(公告)号：US20100093876A1
公开(公告)日：2010-04-15
申请号：US12448373
申请日：2007-12-18
申请人： Sander Gaemers
发明人： Sander Gaemers
IPC分类号： C07C1/02
CPC分类号： B01J37/0201 , B01J23/80 , B01J23/8953 , B01J37/0009 , B01J37/031 , B01J37/08 , C10G2/331 , C10G2/333
摘要： A composition for use as a catalyst or catalyst precursor for the conversion of synthesis gas to hydrocarbons said composition comprises (i) cobalt either as the elemental metal, oxide or a compound thermally decomposable to the elemental metal or oxide and (ii) zinc in the form of the oxide or a compound thermally decomposable to the oxide and (iii) platinum in elemental form or in the form of a compound characterised in that the platinum metal is present in the composition in amount in the range 0.0001 to 1.50% w/w. The compositions show improved activity over a wide temperature range than prior art compositions and also exhibit improved methane selectivity.
摘要翻译：用作催化剂或用于将合成气转化为烃的催化剂前体的组合物所述组合物包含（i）钴作为元素金属，氧化物或可分解成元素金属或氧化物的化合物和（ii）形式的氧化物或可热分解成氧化物的化合物，（iii）元素形式或化合物形式的铂，其特征在于铂金属以0.0001至1.50％w / w的量存在于组合物中。组合物在比现有技术组合物宽的温度范围内显示出改进的活性，并且还表现出改善的甲烷选择性

2. 发明授权

US07977391B2 Process for producing condensed-phase product from one or more gas-phase reactants 有权
标题翻译：用于从一种或多种气相反应物生产冷凝相产物的方法
公开(公告)号：US07977391B2
公开(公告)日：2011-07-12
申请号：US12086427
申请日：2006-11-22
申请人： Sander Gaemers
发明人： Sander Gaemers
IPC分类号： C07C1/04
CPC分类号： C10G2/341 , B01J8/04 , B01J8/067 , B01J19/2485 , B01J23/24 , B01J23/462 , B01J23/74 , B01J23/75 , B01J23/80 , B01J2208/00663 , B01J2208/00884 , B01J2219/0004 , C10G2/332 , Y02P20/582
摘要： Process for the production of a condensed-phase product from one or more gas-phase reactants, by feeding one or more reactants into a reactor, in which reactor the one or more reactants react in the gas-phase in the presence of a solid catalyst having one or more catalyst components to produce at least one product which is in a condensed-phase under reaction conditions. The solid catalyst is present as a bed having two or more regions in which the contact time of the one or more gas-phase reactants with the one or more catalyst components is different.
摘要翻译：通过将一种或多种反应物加入到反应器中来生产来自一种或多种气相反应物的冷凝相产物的方法，其中一种或多种反应物在气相中在固体催化剂存在下反应具有一种或多种催化剂组分以产生在反应条件下处于冷凝相的至少一种产物。固体催化剂作为具有两个或更多个区域的床存在，其中一种或多种气相反应物与一种或多种催化剂组分的接触时间不同。

3. 发明申请

US20090272673A1 Process for Producing Condensed-Phase Product From One or More Gas-Phase Reactants 有权
标题翻译：从一种或多种气相反应物生产冷凝相产物的方法
公开(公告)号：US20090272673A1
公开(公告)日：2009-11-05
申请号：US12086427
申请日：2006-11-22
申请人： Sander Gaemers
发明人： Sander Gaemers
IPC分类号： C10G11/02 , C10G11/00
CPC分类号： C10G2/341 , B01J8/04 , B01J8/067 , B01J19/2485 , B01J23/24 , B01J23/462 , B01J23/74 , B01J23/75 , B01J23/80 , B01J2208/00663 , B01J2208/00884 , B01J2219/0004 , C10G2/332 , Y02P20/582
摘要： A process for producing at least one condensed-phase product from one or more gas-phase reactants in the presence of a solid catalyst having one or more catalyst components, wherein the solid catalyst has two or more regions in which the contact time of the one or more gas-phase reactants with the one or more catalyst components is different. On one embodiment this is achieved by the solid catalyst having two or more regions in which the cross-sectional area and volume of each region is different. In another embodiment, this is achieved by the solid catalyst having regions with different concentrations of the one or more catalyst components.
摘要翻译：一种在具有一种或多种催化剂组分的固体催化剂存在下从一种或多种气相反应物制备至少一种冷凝相产物的方法，其中固体催化剂具有两个或更多个区域，其中一个或更多的气相反应物与一种或多种催化剂组分不同。在一个实施方案中，这通过具有两个或更多个区域的固体催化剂来实现，其中每个区域的横截面积和体积不同。在另一个实施方案中，这通过具有不同浓度的一种或多种催化剂组分的区域的固体催化剂来实现。

4. 发明授权

US07368597B2 Carbonylation process using metal-polydentate ligand catalysts 失效
标题翻译：使用金属多齿配体催化剂的羰基化方法
公开(公告)号：US07368597B2
公开(公告)日：2008-05-06
申请号：US10555739
申请日：2004-05-05
申请人： Sander Gaemers , John Glenn Sunley
发明人： Sander Gaemers , John Glenn Sunley
IPC分类号： C07C51/12
CPC分类号： C07C67/36 , C07C51/12 , C07C53/08 , C07C69/14
摘要： A process for the liquid phase carbonylation of an alcohol and/or a reactive derivative thereof in the presence of hydrogen in which there is employed a catalyst comprising rhodium of iridium coordinated with a polydentate ligand.
摘要翻译：在氢气存在下使醇和/或其活性衍生物液相羰基化的方法，其中使用包含与多齿配体配位的铱铑的催化剂。

5. 发明授权

US07009074B2 Process for direct oxidation of methane to acetic acid 有权
标题翻译：将甲烷直接氧化成乙酸的方法
公开(公告)号：US07009074B2
公开(公告)日：2006-03-07
申请号：US10901643
申请日：2004-07-28
申请人： Mark Zerella , Sudip Mukhopadhyay , Alexis T. Bell , John Glenn Sunley , Sander Gaemers , Philip Howard , Brian Ellis , Andrew Richard Lucy
发明人： Mark Zerella , Sudip Mukhopadhyay , Alexis T. Bell , John Glenn Sunley , Sander Gaemers , Philip Howard , Brian Ellis , Andrew Richard Lucy
IPC分类号： C07C51/14
CPC分类号： C07C51/305 , C07C53/08
摘要： Acetic acid is produced by oxidation of methane with an oxygen-containing gas in the presence of an acid selected from concentrated sulfuric acid and fuming sulfuric acid, a palladium-containing catalyst and a promoter, preferably a copper or iron salt. The addition of a promoter and O2 to a system that includes a palladium-containing catalyst such as PdCl2 increases the rate of acetic acid formation from methane by more than an order of magnitude as compared with prior art and, in addition, inhibits the precipitation of Pd black.
摘要翻译：在选自浓硫酸和发烟硫酸的酸，含钯催化剂和促进剂，优选铜或铁盐的存在下，用含氧气体氧化甲酸来生产乙酸。将促进剂和O 2加入到包含含钯催化剂如PdCl 2 N的体系中增加了甲烷形成乙酸的速率超过一个量级与现有技术相比，并且还抑制了Pd黑的沉淀。

6. 发明授权

US08053482B2 Fischer-tropsch catalyst 失效
标题翻译：费 - 托催化剂
公开(公告)号：US08053482B2
公开(公告)日：2011-11-08
申请号：US12448373
申请日：2007-12-18
申请人： Sander Gaemers
发明人： Sander Gaemers
IPC分类号： C07C27/00
CPC分类号： B01J37/0201 , B01J23/80 , B01J23/8953 , B01J37/0009 , B01J37/031 , B01J37/08 , C10G2/331 , C10G2/333
摘要： Process for reducing the methane selectivity in a Fischer-Tropsch conversion of syngas to hydrocarbons, by using a catalyst composition containing (i) cobalt, either as the elemental metal, oxide, or a compound thermally decomposable to the elemental metal or oxide, (ii) zinc, in the form of the oxide or a compound thermally decomposable to the oxide, and (iii) platinum, in the elemental metal form, or in the form of a compound wherein the amount of platinum metal present in the composition is in the range 0.0001 to 1.50% w/w.
摘要翻译：通过使用含有（i）作为元素金属，氧化物或可分解成元素金属或氧化物的化合物的钴的催化剂组合物，将合成气转化为合成气的甲苯选择性降低到烃的方法，（ii））锌，以氧化物或可热分解成氧化物的化合物的形式，和（iii）以元素金属形式或以化合物形式存在的铂，其中存在于组合物中的铂金属的量为范围0.0001至1.50％w / w。

7. 发明申请

US20070010687A1 Carbonylation process using metal-polydentate ligand catalysts 失效
标题翻译：使用金属多齿配体催化剂的羰基化方法
公开(公告)号：US20070010687A1
公开(公告)日：2007-01-11
申请号：US10555739
申请日：2004-05-05
申请人： Sander Gaemers , John Sunley
发明人： Sander Gaemers , John Sunley
IPC分类号： C07C51/12
CPC分类号： C07C67/36 , C07C51/12 , C07C53/08 , C07C69/14
摘要： A process for the liquid phase carbonylation of an alcohol and/or a reactive derivative thereof in the presence of hydrogen in which there is employed a catalyst comprising rhodium of iridium coordinated with a polydentate ligand.
摘要翻译：在氢气存在下使醇和/或其活性衍生物液相羰基化的方法，其中使用包含与多齿配体配位的铱铑的催化剂。

8. 发明申请

US20050020856A1 Process for production of acetyl anhydrides and optionally acetic acid from methane and carbon dioxide 审中-公开
标题翻译：用于从甲烷和二氧化碳生产乙酰基酐和任选的乙酸的方法
公开(公告)号：US20050020856A1
公开(公告)日：2005-01-27
申请号：US10627254
申请日：2003-07-24
申请人： Alexis Bell , Sudip Mukhopadhyay , Mark Zerella , John Sunley , Sander Gaemers
发明人： Alexis Bell , Sudip Mukhopadhyay , Mark Zerella , John Sunley , Sander Gaemers
IPC分类号： C07C51/56 , C07C67/08 , C07C309/00 , C07C381/00 , C07C69/02
CPC分类号： C07C309/00 , C07C51/56 , C07C67/08 , C07C381/00 , C07C53/18 , C07C69/14
摘要： Acetyl anhydrides such as acetyl sulfate are produced by a process for comprising contacting methane and carbon dioxide in an anhydrous environment in the presence of effective amounts of a transition metal catalyst and a reaction promoter, and an acid anhydride compound, and optionally an acid. The acetyl anhydride can be contacted with water to produce acetic acid or with an alcohol to produce a product comprising an acetate ester and that may also comprise acetic acid.
摘要翻译：通过包括在有效量的过渡金属催化剂和反应促进剂以及酸酐化合物和任选的酸的存在下，在无水环境中使甲烷和二氧化碳接触的方法制备乙酰基酸酐。乙酸酐可以与水接触以产生乙酸或与醇反应生成包含乙酸酯并且也可以包含乙酸的产物。

9. 发明授权

US08802796B2 Air and water tolerant catalyst 有权
标题翻译：耐空气和耐水催化剂
公开(公告)号：US08802796B2
公开(公告)日：2014-08-12
申请号：US13441545
申请日：2012-04-06
申请人： Paul Oblad , Matthew S. Winston , Jay A. Labinger , John E. Bercaw , Sander Gaemers
发明人： Paul Oblad , Matthew S. Winston , Jay A. Labinger , John E. Bercaw , Sander Gaemers
IPC分类号： C08F4/80 , C08F4/70
CPC分类号： B01J31/2226 , B01J31/1805 , B01J2231/12 , B01J2531/0216 , B01J2531/824
摘要： A catalyst and/or precatalyst for olefin oligomerization comprising one or more coordination complexes having one or more central palladium metal atoms. Each palladium atom is bonded to four ligand donor atoms. Two of the donor atoms are group 16 elements and two of the donor atoms are group 15 elements. Also provided are neutral or cationic coordination complex dimers, so that the two palladium atoms are both bonded to one or two donor atoms from group 16, and each palladium atom is bonded to two donor atoms from group 15. In some instances, each of the two group 16 donor atoms are oxygen and each of the four group 15 donor atoms are nitrogen.
摘要翻译：一种用于烯烃低聚的催化剂和/或预催化剂，其包含一种或多种具有一个或多个中心钯金属原子的配位络合物。每个钯原子键合到四个配体供体原子。两个供体原子是16族元素，两个供体原子是15族元素。还提供了中性或阳离子配位络合物二聚体，使得两个钯原子都与第16族的一个或两个供体原子键合，并且每个钯原子与第15族键合到两个供体原子。在一些情况下，两个16族供体原子是氧，四个15族供体原子中的每一个都是氮。

10. 发明授权

US08524954B2 Hydrogenation of ethanoic acid to produce ethanol 失效
标题翻译：乙酸氢化生产乙醇
公开(公告)号：US08524954B2
公开(公告)日：2013-09-03
申请号：US12998639
申请日：2009-11-10
申请人： Evert Jan Ditzel , Sander Gaemers , John Glenn Sunley
发明人： Evert Jan Ditzel , Sander Gaemers , John Glenn Sunley
IPC分类号： C07C29/152 , C07C29/157 , C07C27/06
CPC分类号： C07C29/151 , C07C29/149 , C07C51/12 , Y02P20/582 , C07C31/08 , C07C31/04 , C07C53/08
摘要： The present invention relates to a process for producing methanol and ethanol, wherein the methanol is produced from synthesis gas and the ethanol is produced via the hydrogenation of an ethanoic acid feed; characterized in that the hydrogenation of the ethanoic acid feed is carried out within the same alcohol synthesis unit and in the presence of the same catalyst(s) that is used to produce the methanol from the synthesis gas and wherein the feed introduced to the alcohol synthesis unit comprises synthesis gas and ethanoic acid.
摘要翻译：本发明涉及一种生产甲醇和乙醇的方法，其中甲醇由合成气生产，乙醇通过乙酸进料的氢化生产; 其特征在于，所述乙酸进料的氢化在相同的醇合成单元内进行，并且在用于从合成气生产甲醇的相同催化剂的存在下进行，并且其中引入醇合成的进料单元包括合成气和乙酸。

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