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    • 3. 发明授权
    • Red nitride phosphor and production method thereof
    • 红色氮化物荧光粉及其制备方法
    • US08148886B2
    • 2012-04-03
    • US11795298
    • 2006-01-25
    • Shin-ichi SakataTakeshi YamaoTetsuo Yamada
    • Shin-ichi SakataTakeshi YamaoTetsuo Yamada
    • C09K11/59C09K11/08
    • C09K11/0883C01B21/0602C01P2002/54C01P2002/72C01P2002/77C01P2002/84C01P2006/60C09K11/7728
    • A red phosphor where the crystal phase constituting the phosphor is monoclinic Eu-activated CaAlSiN3. A red phosphor which is Eu-activated CaAlSiN3 powder having an average particle diameter of 10 μm or less as measured in the non-pulverized state by the laser scattering particle size distribution analysis. A light-emitting device comprising a blue light-emitting element, a yellow phosphor capable of converting the blue light emitted from the blue light-emitting element into yellow light, and the above-described red phosphor capable of converting the blue light emitted from the blue light-emitting element into red light. A method for producing Eu-activated CaAlSiN3, comprising firing a raw material powder comprising Ca3N2, AlN, Si3N4 and EuN at 1,400 to 2,000° C. in a nitrogen-containing atmosphere, the Ca3N2, AlN and Si3N4 giving a composition falling in the region surrounded by a straight line connecting the following four points A to D in the composition diagram of FIG. 1, and EuN being contained in an amount of 0.01 to 10 parts by weight as Eu per 100 parts by weight in total of Ca3N2, AlN and Si3N4.
    • 构成荧光体的晶相的红色荧光体为单斜晶Eu激活CaAlSiN3。 一种红色荧光体,其是通过激光散射粒度分布分析在非粉碎状态下测定的平均粒径为10μm以下的Eu活化CaAlSiN 3粉末。 一种发光装置,包括蓝色发光元件,能够将从蓝色发光元件发射的蓝色光转换成黄色光的黄色荧光体,以及上述红色荧光体,其能够将从蓝色发光元件发出的蓝色光 蓝色发光元件变成红灯。 一种Eu活化的CaAlSiN 3的制造方法,其特征在于,在含氮气氛中,在1400〜2000℃下烧成含有Ca3N2,AlN,Si3N4,EuN的原料粉末,使Ca3N2,AlN,Si3N4在该区域 由连接图4的组成图中的以下四点A至D的直线包围。 1,EuN的含量相对于Ca3N2,AlN和Si3N4总计为100重量份,为Eu为0.01〜10重量份。