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1. 发明申请

US20090221748A1 COATING COMPOSITIONS COMPRISING A POLYMER CONTAINING AN OLIGOMERIC MACROMONOMER 有权
标题翻译：包含含有低聚物的聚合物的涂料组合物
公开(公告)号：US20090221748A1
公开(公告)日：2009-09-03
申请号：US12040380
申请日：2008-02-29
申请人： Simion Coca , Deborah E. Hayes , Jonathan T. Martz , Karen A. Morow , Calum H. Munro , Kurt G. Olson , Dennis A. Simpson , Jane N. Valenta , Richard J. Winters , Stephen J. Thomas
发明人： Simion Coca , Deborah E. Hayes , Jonathan T. Martz , Karen A. Morow , Calum H. Munro , Kurt G. Olson , Dennis A. Simpson , Jane N. Valenta , Richard J. Winters , Stephen J. Thomas
IPC分类号： C08L33/08
CPC分类号： C08F290/046 , C08L33/08 , C08L61/28 , C09D133/066 , C09D133/068 , C08L2666/02
摘要： The present invention is directed to a coating composition comprising a polymer that comprises an oligomeric macromonomer and a core from which the oligomeric macromonomer extends, wherein the oligomeric macromonomer comprises reactive functional groups and has an average functionality ranging from 1.0 to 30, and wherein the core is
摘要翻译：本发明涉及包含聚合物的涂料组合物，所述聚合物包含低聚物大分子单体和低聚物大分子单体从其延伸的核心，其中所述低聚物大分子单体包含反应性官能团并且平均官能度为1.0至30，并且其中所述核心是聚合物总重量的10重量％。

2. 发明授权

US08071679B2 Coating compositions comprising a polymer containing an oligomeric macromonomer 有权
标题翻译：包含含有低聚大分子单体的聚合物的涂料组合物
公开(公告)号：US08071679B2
公开(公告)日：2011-12-06
申请号：US12040380
申请日：2008-02-29
申请人： Simion Coca , Deborah E. Hayes , Jonathan T. Martz , Karen A. Morow , Calum H. Munro , Kurt G. Olson , Dennis A. Simpson , Jane N. Valenta , Richard J. Winters , Stephen J. Thomas
发明人： Simion Coca , Deborah E. Hayes , Jonathan T. Martz , Karen A. Morow , Calum H. Munro , Kurt G. Olson , Dennis A. Simpson , Jane N. Valenta , Richard J. Winters , Stephen J. Thomas
IPC分类号： C08F8/00 , C08G63/91
CPC分类号： C08F290/046 , C08L33/08 , C08L61/28 , C09D133/066 , C09D133/068 , C08L2666/02
摘要： The present invention is directed to a coating composition comprising a polymer that comprises an oligomeric macromonomer and a core from which the oligomeric macromonomer extends, wherein the oligomeric macromonomer comprises reactive functional groups and has an average functionality ranging from 1.0 to 30, and wherein the core is
摘要翻译：本发明涉及包含聚合物的涂料组合物，所述聚合物包含低聚物大分子单体和低聚物大分子单体从其延伸的核心，其中所述低聚物大分子单体包含反应性官能团并且平均官能度为1.0至30，并且其中所述核心是聚合物总重量的10重量％。

3. 发明申请

US20090221757A1 POLYMERS CONTAINING AN OLIGOMERIC MACROMONOMER 审中-公开
标题翻译：含有低分子大分子的聚合物
公开(公告)号：US20090221757A1
公开(公告)日：2009-09-03
申请号：US12040371
申请日：2008-02-29
申请人： Simion Coca , Stephen J. Thomas , Jonathan T. Martz , Kurt G. Olson , Dennis A. Simpson , Jane N. Valenta , Richard J. Winters
发明人： Simion Coca , Stephen J. Thomas , Jonathan T. Martz , Kurt G. Olson , Dennis A. Simpson , Jane N. Valenta , Richard J. Winters
IPC分类号： C08F2/00 , C08F289/00
CPC分类号： C08F290/00 , C08F265/04 , C08F283/12 , C08F289/00 , C08F290/06 , C08F291/00 , C08L51/003 , C09D151/003 , C08L2666/02
摘要： The present invention is directed to a polymer that comprises an oligomeric macromonomer and a core from which the oligomeric macromonomer extends, wherein the oligomeric macromonomer comprises reactive functional groups and has an average functionality ranging from 1.0 to 30.0, and wherein the core is
摘要翻译：本发明涉及包含低聚大分子单体和寡聚大分子单体延伸的核心的聚合物，其中所述低聚物大分子单体包含反应性官能团并且平均官能度为1.0至30.0，并且其中所述核心为<10重量％总聚合物重量的百分比。本发明还涉及其制造方法。

4. 发明授权

US06485788B1 Thermosetting compositions containing epoxy-functional polymers prepared using atom transfer radical 失效
标题翻译：含有使用原子转移自由基聚合制备的环氧官能聚合物的热固性组合物
公开(公告)号：US06485788B1
公开(公告)日：2002-11-26
申请号：US09934384
申请日：2001-08-21
申请人： Simion Coca , Dennis A. Simpson , James B. O'Dwyer , Kurt G. Olson
发明人： Simion Coca , Dennis A. Simpson , James B. O'Dwyer , Kurt G. Olson
IPC分类号： C08G5932
CPC分类号： C08L53/00 , C08F8/26 , C08F293/005 , C08F2438/01 , C08G59/3209 , C08K5/0025 , C09D153/00 , Y10T428/31511 , C08L33/12 , C08L2666/02
摘要： A thermosetting composition is provided comprising: (a) a crosslinking agent having at least two functional groups that are reactive with epoxides; and (b) a non-gelled, epoxy functional polymer prepared by atom transfer radical polymerization, in the presence of an initiator having at least one radically transferable group. The polymer contains at least one of the following polymer chain structures: —{(M)p—(G)q}x— or —{(G)q—(M)p}x— wherein M is a residue, that is free of epoxy functionality, of at least one ethylenically unsaturated radically polymerizable monomer; G is a residue, that has epoxy functionality, of at least one ethylenically unsaturated radically polymerizable monomer; p and q represent average numbers of residues occurring in a block of residues in each polymer chain structure; and p, q, and x are each independently selected for each structure such that the epoxy functional polymer has a number average molecular weight of at least 250. Also provided by the present invention are methods of coating a substrate using compositions of the present invention and substrates coated by such methods, as well as color-plus-clear composite coatings.
摘要翻译：提供一种热固性组合物，其包括：（a）具有至少两个与环氧化物反应的官能团的交联剂; 和（b）在具有至少一个可自由基转移基团的引发剂的存在下通过原子转移自由基聚合制备的非胶凝的环氧官能聚合物。聚合物含有至少一种以下聚合物链结构：或其中M是不含环氧官能团的至少一种烯属不饱和自由基聚合单体的残基; G是具有至少一个烯属不饱和自由基聚合单体的具有环氧官能度的残基; p和q表示在每个聚合物链结构的残基块中发生的残基的平均数目; 对于每种结构，p，q和x各自独立地选择，使得环氧官能聚合物的数均分子量至少为250.本发明还提供了使用本发明的组合物涂覆底物的方法和通过这些方法涂覆的基材，以及彩色 - 透明复合涂层。

5. 发明授权

US06319967B1 Thermosetting compositions containing epoxy-functional polymers prepared using atom transfer radical polymerization 有权
标题翻译：含有使用原子转移自由基聚合制备的环氧官能聚合物的热固性组合物
公开(公告)号：US06319967B1
公开(公告)日：2001-11-20
申请号：US09375021
申请日：1999-08-16
申请人： Simion Coca , Dennis A. Simpson , James B. O'Dwyer , Kurt G. Olson
发明人： Simion Coca , Dennis A. Simpson , James B. O'Dwyer , Kurt G. Olson
IPC分类号： C08G5932
CPC分类号： C08L53/00 , C08F8/26 , C08F293/005 , C08F2438/01 , C08G59/3209 , C08K5/0025 , C09D153/00 , Y10T428/31511 , C08L33/12 , C08L2666/02
摘要： A thermosetting composition is provided comprising: (a) a crosslinking agent having at least two functional groups that are reactive with epoxides; and (b) a non-gelled, epoxy functional polymer prepared by atom transfer radical polymerization, in the presence of an initiator having at least one radically transferable group. The polymer contains at least one of the following polymer chain structures: —{(M)p—(G)q}x—or —{(G)q—(M)p}x— wherein M is a residue, that is free of epoxy functionality, of at least one ethylenically unsaturated radically polymerizable monomer; G is a residue, that has epoxy functionality, of at least one ethylenically unsaturated radically polymerizable monomer; p and q represent average numbers of residues occurring in a block of residues in each polymer chain structure; and p, q, and x are each independently selected for each structure such that the epoxy functional polymer has a number average molecular weight of at least 250. Also provided by the present invention are methods of coating a substrate using compositions of the present invention and substrates coated by such methods, as well as color-plus-clear composite coatings.
摘要翻译：提供一种热固性组合物，其包括：（a）具有至少两个与环氧化物反应的官能团的交联剂; 和（b）在具有至少一个可自由基转移基团的引发剂的存在下通过原子转移自由基聚合制备的非胶凝的环氧官能聚合物。聚合物含有至少一种以下聚合物链结构：其中M是至少一种烯属不饱和可自由基聚合单体的残基，不含环氧官能团; G是具有至少一个烯属不饱和自由基聚合单体的具有环氧官能度的残基; p和q表示在每个聚合物链结构的残基块中发生的残基的平均数目; 对于每种结构，p，q和x各自独立地选择，使得环氧官能聚合物的数均分子量至少为250.本发明还提供了使用本发明的组合物涂覆底物的方法和通过这些方法涂覆的基材，以及彩色 - 透明复合涂层。

6. 发明授权

US06657001B1 Coating compositions having improved scratch resistance, coated substrates and methods related thereto 有权
标题翻译：涂层组合物具有改进的耐刮擦性，涂覆的基材和与其有关的方法
公开(公告)号：US06657001B1
公开(公告)日：2003-12-02
申请号：US09629444
申请日：2000-07-31
申请人： Lawrence G. Anderson , Karen A. Barkac , Shawn A. DeSaw , Marvis E. Hartman , Deborah E. Hayes , Thomas R. Hockswender , Kymarie L. Kuster , Masayuki Nakajima , Kurt G. Olson , Richard J. Sadvary , Dennis A. Simpson , Shiryn Tyebjee , Truman F. Wilt
发明人： Lawrence G. Anderson , Karen A. Barkac , Shawn A. DeSaw , Marvis E. Hartman , Deborah E. Hayes , Thomas R. Hockswender , Kymarie L. Kuster , Masayuki Nakajima , Kurt G. Olson , Richard J. Sadvary , Dennis A. Simpson , Shiryn Tyebjee , Truman F. Wilt
IPC分类号： C08L8304
CPC分类号： B82Y30/00 , C08J3/20 , C08K3/01 , C08K3/22 , C08K3/36 , C08K2201/011 , C09D7/00 , C09D7/61 , C09D7/67 , C09D7/68 , C09D7/69 , C09D183/04 , C08L2666/14 , C08L2666/54 , C08L2666/04
摘要： Compositions are provided which contain (a) one or more polysiloxanes comprising at least one reactive functional group; a plurality of particles; and, optionally, one or more curing agents comprising at least one functional group that is reactive with any reactive functional group of polysiloxane (a). Additionally, a process for applying the multi-component composite coatings described above to a substrate and coated substrates are provided. A process for preparing the coating compositions also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.
摘要翻译：提供了包含（a）一种或多种包含至少一个反应性官能团的聚硅氧烷的组合物; 多个颗粒; 和任选的一种或多种固化剂，其包含与聚硅氧烷（a）的任何反应性官能团反应的至少一个官能团。另外，提供了将上述多组分复合涂层施加到基底和涂覆的基底上的方法。还提供了制备涂料组合物的方法。本发明的多组分复合涂料组合物提供了耐风化后能够保持耐刮擦性的高耐划伤性的彩色 - 透明涂层。

7. 发明授权

US07053149B2 Coating compositions having improved scratch resistance, coated substrates and methods related thereto 有权
标题翻译：涂层组合物具有改进的耐刮擦性，涂覆的基材和与其有关的方法
公开(公告)号：US07053149B2
公开(公告)日：2006-05-30
申请号：US10795216
申请日：2004-03-09
申请人： Lawrence G. Anderson , Karen A. Barkac , Shawn A. DeSaw , Marvis E. Hartman , Deborah E. Hayes , Thomas R. Hockswender , Kymarie L. Kuster , Masayuki Nakajima , Kurt G. Olson , Richard J. Sadvary , Dennis A. Simpson , Shiryn Tyebjee , Truman F. Wilt
发明人： Lawrence G. Anderson , Karen A. Barkac , Shawn A. DeSaw , Marvis E. Hartman , Deborah E. Hayes , Thomas R. Hockswender , Kymarie L. Kuster , Masayuki Nakajima , Kurt G. Olson , Richard J. Sadvary , Dennis A. Simpson , Shiryn Tyebjee , Truman F. Wilt
IPC分类号： C08L83/04 , C08L83/06 , C08L83/08
CPC分类号： B82Y30/00 , C08J3/20 , C08K3/01 , C08K3/22 , C08K3/36 , C08K2201/011 , C09D7/00 , C09D7/61 , C09D7/67 , C09D7/68 , C09D7/69 , C09D183/04 , C08L2666/14 , C08L2666/54 , C08L2666/04
摘要： Compositions are provided which contain (a) one or more polysiloxanes comprising at least one reactive functional group; a plurality of particles; and optionally, one or more curing agents comprising at least one functional group that is reactive with any reactive functional group of polysiloxane (a). Additionally, a process for applying the multi-component composite coatings described above to a substrate and coated substrates are provided. A process for preparing the coating compositions also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.
摘要翻译：提供了包含（a）一种或多种包含至少一个反应性官能团的聚硅氧烷的组合物; 多个颗粒; 和任选的一种或多种包含至少一种与聚硅氧烷（a）的任何反应性官能团反应的官能团的固化剂。另外，提供了将上述多组分复合涂层施加到基底和涂覆的基底上的方法。还提供了制备涂料组合物的方法。本发明的多组分复合涂料组合物提供了耐风化后能够保持耐刮擦性的高耐划伤性的彩色 - 透明涂层。

8. 发明授权

US06803408B2 Coating compositions having improved scratch resistance, coated substrates and methods related thereto 有权
标题翻译：涂层组合物具有改进的耐刮擦性，涂覆的基材和与其有关的方法
公开(公告)号：US06803408B2
公开(公告)日：2004-10-12
申请号：US10456854
申请日：2003-06-09
申请人： Lawrence G. Anderson , Karen A. Barkac , Shawn A. DeSaw , Marvis E. Hartman , Deborah E. Hayes , Thomas R. Hockswender , Kymarie L. Kuster , Masayuki Nakajima , Kurt G. Olson , Richard J. Sadvary , Dennis A. Simpson , Shiryn Tyebjee , Truman F. Wilt
发明人： Lawrence G. Anderson , Karen A. Barkac , Shawn A. DeSaw , Marvis E. Hartman , Deborah E. Hayes , Thomas R. Hockswender , Kymarie L. Kuster , Masayuki Nakajima , Kurt G. Olson , Richard J. Sadvary , Dennis A. Simpson , Shiryn Tyebjee , Truman F. Wilt
IPC分类号： C08L8304
CPC分类号： B82Y30/00 , C08J3/20 , C08K3/01 , C08K3/22 , C08K3/36 , C08K2201/011 , C09D7/00 , C09D7/61 , C09D7/67 , C09D7/68 , C09D7/69 , C09D183/04 , C08L2666/14 , C08L2666/54 , C08L2666/04
摘要： Compositions are provided which contain (a) one or more polysiloxanes comprising at least one reactive functional group; a plurality of particles; and, optionally, one or more curing agents comprising at least one functional group that is reactive with any reactive functional group of polysiloxane (a). Additionally, a process for applying the multi-component composite coatings described above to a substrate and coated substrates are provided. A process for preparing the coating compositions also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.
摘要翻译：提供了包含（a）一种或多种包含至少一个反应性官能团的聚硅氧烷的组合物; 多个颗粒; 和任选的一种或多种固化剂，其包含与聚硅氧烷（a）的任何反应性官能团反应的至少一个官能团。另外，提供了将上述多组分复合涂层施加到基底和涂覆的基底上的方法。还提供了制备涂料组合物的方法。本发明的多组分复合涂料组合物提供了耐风化后能够保持耐刮擦性的高耐划伤性的彩色 - 透明涂层。

9. 发明授权

US06759478B2 Coating compositions having improved scratch resistance, coated substrates and methods related thereto 有权
标题翻译：涂层组合物具有改进的耐刮擦性，涂覆的基材和与其有关的方法
公开(公告)号：US06759478B2
公开(公告)日：2004-07-06
申请号：US10456552
申请日：2003-06-09
申请人： Lawrence G. Anderson , Karen A. Barkac , Shawn A. DeSaw , Marvis E. Hartman , Deborah E. Hayes , Thomas R. Hockswender , Kymarie L. Kuster , Gregory J. McCollum , Masayuki Nakajima , Kurt G. Olson , Richard J. Sadvary , Dennis A. Simpson , Shiryn Tyebjee , Truman F. Wilt
发明人： Lawrence G. Anderson , Karen A. Barkac , Shawn A. DeSaw , Marvis E. Hartman , Deborah E. Hayes , Thomas R. Hockswender , Kymarie L. Kuster , Gregory J. McCollum , Masayuki Nakajima , Kurt G. Olson , Richard J. Sadvary , Dennis A. Simpson , Shiryn Tyebjee , Truman F. Wilt
IPC分类号： C08L8304
CPC分类号： B82Y30/00 , C08J3/20 , C08K3/01 , C08K3/013 , C08K3/22 , C08K3/36 , C08K2201/011 , C09D7/00 , C09D7/61 , C09D7/67 , C09D7/68 , C09D7/69 , C09D183/04 , C08L2666/28 , C08L2666/54 , C08L2666/14 , C08L2666/04
摘要： Coating compositions are provided which are formed from components comprising (a) at least one polysiloxane comprising at least one reactive functional group; (b) at least one reactant comprising at least one functional group that is reactive with at least one functional group selected from the at least one reactive functional group of the at least one polysiloxane and at least one functional group of at least one reactant; and (c) a plurality of particles, wherein each component is different, and wherein the at least one reactive functional group of the at least one polysiloxane and the at least one functional group of the at least one reactant are substantially nonreactive with the particles. A multi-component composite coating composition formed from a basecoat and a topcoat deposited from the curable coating composition also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.
摘要翻译：提供涂料组合物，其由包含（a）至少一种包含至少一个反应性官能团的聚硅氧烷的组分形成; （b）至少一种包含至少一种与至少一种选自至少一种聚硅氧烷的至少一种反应性官能团和至少一种反应物官能团的官能团反应的官能团的官能团; 和（c）多个颗粒，其中每个组分是不同的，并且其中所述至少一种聚硅氧烷的至少一种反应性官能团和所述至少一种反应物的至少一种官能团基本上与颗粒不反应。还提供了由底涂层和从可固化涂料组合物沉积的面涂层形成的多组分复合涂料组合物。本发明的多组分复合涂料组合物提供了耐风化后能够保持耐刮擦性的高耐划伤性的彩色 - 透明涂层。

10. 发明授权

US06610777B1 Flexible coating compositions having improved scratch resistance, coated substrates and methods related thereto 失效
标题翻译：柔性涂料组合物具有改善的耐刮擦性，涂布的基材和与其有关的方法
公开(公告)号：US06610777B1
公开(公告)日：2003-08-26
申请号：US09629420
申请日：2000-07-31
申请人： Lawrence G. Anderson , Shawn A. De Saw , Marvis E. Hartman , Deborah E. Hayes , Thomas R. Hockswender , Kymarie L. Kuster , Michael Allen Mayo , Masayuki Nakajima , Kurt G. Olson , Richard J. Sadvary , Laura E. Schilling , Dennis A. Simpson , Shiryn Tyebjee , Truman F. Wilt
发明人： Lawrence G. Anderson , Shawn A. De Saw , Marvis E. Hartman , Deborah E. Hayes , Thomas R. Hockswender , Kymarie L. Kuster , Michael Allen Mayo , Masayuki Nakajima , Kurt G. Olson , Richard J. Sadvary , Laura E. Schilling , Dennis A. Simpson , Shiryn Tyebjee , Truman F. Wilt
IPC分类号： C08L8304
CPC分类号： B82Y30/00 , C08J3/20 , C08K3/01 , C08K3/013 , C08K2201/011 , C09D7/00 , C09D7/61 , C09D7/62 , C09D7/69 , C09D183/04 , C08L2666/14 , C08L2666/54 , C08L2666/04 , C08L2666/28
摘要： Coating compositions are provided which include a polysiloxane comprising at least one reactive functional group and at least one material comprising at least one reactive functional group. Also provided are multi-layer composite coatings formed from a basecoat deposited from a pigmented coating composition and a topcoat applied over the basecoat, the topcoat deposited from the aforementioned coating composition. A method for improving the scratch resistance of a coated substrate, as well as coated substrates also are provided. The compositions of the invention provide highly scratch resistant coatings, particularly highly scratch resistant color-plus-clearcoatings.
摘要翻译：提供涂料组合物，其包括包含至少一个反应性官能团的聚硅氧烷和至少一种包含至少一个反应性官能团的材料。还提供了由从着色涂料组合物沉积的底涂层和涂覆在底涂层上的顶涂层，由上述涂料组合物沉积的面漆形成的多层复合涂层。还提供了一种用于改善涂覆基材的耐擦伤性的方法以及涂覆的基材。本发明的组合物提供高度耐刮擦的涂层，特别是高度耐刮擦的彩色 - 透明涂层。

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