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    • 6. 发明授权
    • Non-aqueous electrolyte secondary battery comprising composite particles
    • 包含复合颗粒的非水电解质二次电池
    • US06824920B1
    • 2004-11-30
    • US09601421
    • 2000-09-28
    • Kazuya IwamotoHizuru KoshinaHarunari ShimamuraYoshiaki Nitta
    • Kazuya IwamotoHizuru KoshinaHarunari ShimamuraYoshiaki Nitta
    • H01M438
    • H01M4/38H01M4/366H01M4/386H01M4/387H01M4/42H01M10/0525H01M10/0568H01M10/0569
    • The present invention relates to a non-aqueous electrolyte secondary battery. The negative electrode of the present invention is characterized by its composite particles constructed in such a manner that at least part of the surrounding surface of nuclear particles containing at least one of tin, silicon and zinc as a constituent element, is coated with a solid solution or an intermetallic compound, which are composed of the element contained in the nuclear particles, and at least one other element except the elements contained in the nuclear particles selected from a group comprising group 2 elements, transition elements, group 12 elements, group 13 elements and group 14 elements except carbon of the Periodic Table. The electrolyte uses anion lithium salts of organic acid dissolved in organic solvent with high oxidation resistant characteristics. By adopting the above construction, a battery which generates only a small amount of gas during a high temperature storing can be obtained. Furthermore, the batteries enjoy high energy density and a lower reduction rate of discharge capacity when used repeatedly as well as high charge/discharge properties.
    • 本发明涉及一种非水电解质二次电池。 本发明的负极的特征在于,其复合颗粒的构成是将含有锡,硅和锌中的至少一种作为构成元素的至少一部分核粒子的周围表面涂布固溶体 或由包含在核粒子中的元素组成的金属间化合物,以及除了选自包含第2族元素,过渡元素,第12族元素,第13族元素的核粒子中的元素以外的至少一种其它元素 和除了周期表碳以外的第14组元素。 电解质使用溶解于有机溶剂中的有机酸的阴离子锂盐,具有高抗氧化特性。 通过采用上述结构,可以获得在高温保存期间仅产生少量气体的电池。 此外,当重复使用电池以及高充电/放电性能时,电池具有高的能量密度和较低的放电容量的减小率。