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1. 发明授权

US3328451A beta-mercapto alkyl amino alkyl alkoxy silanes 失效
标题翻译： β-巯基烷基氨基烷基烷氧基硅烷
公开(公告)号：US3328451A
公开(公告)日：1967-06-27
申请号：US33542664
申请日：1964-01-02
申请人： THIOKOL CHEMICAL CORP
发明人： BULBENKO GEORGE F
IPC分类号： C07F7/18 , C08L81/00
CPC分类号： C07F7/182 , C07F7/1804 , C08L81/00
摘要： The invention comprises compounds of formula , where R is an alkyl group of 1 to 4 carbon atoms, R1, R11 are H or an alkyl group of 1 to 4 carbon atoms, a is 1 to 3, b is 0 to 2, a + b = 3, and n is 1 to 6. The compounds are prepared by reacting silanes of the formula (R1)b(OR)a-Si(CH2)nNH2 and an alkylene sulphide. The compound may be used as adhesive additives for liquid polysulphide polymer based sealant and caulking compositions. The liquid polysulphide polymer curing agents which may be used in these compositions include polyepoxy resins, lead peroxide, calcium peroxide, barium peroxide, tellurium dioxide and various chromous salts. Such curable compositions may also contain fillers, plasticizers, pigments, ultraviolet light stabilizers and cure accelerators. The compounds and are prepared in the examples. In Example 3, the compound is used as a primer on aluminium, stainless steel and glass. The polysulphide polymer based sealant composition is then applied and cured. The composition contains polysulphide polymer, calcium carbonate, titanium dioxide, hydrated silica, calcium stearate, stearic acid and sulphur and is mixed with a lead dioxide-chlorinated biphenyl plasticizer admixture before application to the substrates.ALSO:Substrates are coated with a curable sealant composition comprising a polysulphide polymer and an organosilicon compound of the formula (R1)b (OR)a Si(CH2)n NH.CH(R11) CH2SH, where R is an alkyl group of 1 to 4 carbon atoms R1, R11 are H or an alkyl group of 1 to 4 carbon atoms, a is 1 to 3, b is 0 to 2, a + b = 3, and n is 1 to 6. Substrates include those of a wood nature, those of a silicaceous nature such as glass, and those of a metallic nature such as aluminium, iron and steel, and zinc and/or chrome coated iron or steel. Polymers of molecular weight 500 to 4000 are preferred curing agents which may be used include polyepoxy resins, lead peroxide, calcium peroxide, barium peroxide, tellurium dioxide and various chromous salts. The compositions may also contain fillers, plasticizers, pigments, ultraviolet light stabilizers, and cure accelerators. In example 3, aluminium, stainless steel and glass are coated with a primer of an ethenolic solution of b -mercapto ethyl amino propyl triethoxy silane. The polysulphide polymer is then applied and cured. The sealant used contains polysulphide polymer, calcium carbonate, titanium dioxide, hydrated silica, calcium stearate, stearic acid and sulphur, and is mixed with a lead dioxide chlorinated bisphenyl plasticizer admixture before application to the substrates.

2. 发明授权

US3235589A Liquid carboxy-terminated polymers and preparation thereof with dicarboxylic acid peroxides 失效
标题翻译：液体羧基封端的聚合物及其与二羧酸过氧化物的制备
公开(公告)号：US3235589A
公开(公告)日：1966-02-15
申请号：US14058561
申请日：1961-09-25
申请人： THIOKOL CHEMICAL CORP
发明人： BERENBAUM MORRIS B , BULBENKO GEORGE F , GOBRAN RIAD H , HOFFMAN ROBERT F
IPC分类号： C08F36/04
CPC分类号： C08F36/04 , C08F4/28

3. 发明授权

US3479337A Aziridinyl derivatives of polyfunctional epoxides 失效
标题翻译：多官能环氧化物的亚胺基衍生物
公开(公告)号：US3479337A
公开(公告)日：1969-11-18
申请号：US3479337D
申请日：1967-03-01
申请人： THIOKOL CHEMICAL CORP
发明人： BULBENKO GEORGE F , GOBRAN RIAD H , BLOMMERS ELIZABETH A
IPC分类号： C07D203/10 , C07D203/12 , C08G59/28 , C08G59/32 , C08G59/50 , C07D23/04
CPC分类号： C07D203/10 , C07D203/12 , C08G59/28 , C08G59/32 , C08G59/5066

4. 发明授权

US3382094A Fluid and mold resistant cellulosic materials and process therefor 失效
标题翻译：耐流体和耐霉素的纤维素材料及其工艺
公开(公告)号：US3382094A
公开(公告)日：1968-05-07
申请号：US36868464
申请日：1964-05-19
申请人： THIOKOL CHEMICAL CORP
发明人： BULBENKO GEORGE F , OSBORN STEPHEN W
IPC分类号： B27K3/15 , D06M13/11 , D06M13/252
CPC分类号： D06M13/252 , B27K3/15 , C08L81/04 , C08L97/02 , D06M13/11 , Y10T428/662 , Y10T442/2221 , Y10T442/2533

5. 发明授权

US3278489A Thermally stable copolymers of trioxane and cyclic disulfides and process for makingthe same 失效
标题翻译：三恶烷和环状二硫化物的热稳定性共聚物及其制备方法
公开(公告)号：US3278489A
公开(公告)日：1966-10-11
申请号：US22671762
申请日：1962-09-27
申请人： THIOKOL CHEMICAL CORP
发明人： PHILIP BERNSTEIN , BULBENKO GEORGE F
IPC分类号： C08G2/18
CPC分类号： C08G2/18

6. 发明授权

US3455952A Process for the production of thiiranes 失效
标题翻译：生产THIIRANES的过程
公开(公告)号：US3455952A
公开(公告)日：1969-07-15
申请号：US3455952D
申请日：1966-08-04
申请人： THIOKOL CHEMICAL CORP
发明人： BULBENKO GEORGE F , JACKLE WILLIAM A
IPC分类号： C07D331/02 , C07D339/06 , C07D59/00
CPC分类号： C07D339/06 , C07D331/02

7. 发明授权

US3338876A Thiourea-curable acrylate stocks, vulcanization process and vulcanizate therefrom 失效
标题翻译：硫脲可固化的丙烯酸酯原料，硫化工艺和硫化橡胶
公开(公告)号：US3338876A
公开(公告)日：1967-08-29
申请号：US36836964
申请日：1964-05-18
申请人： THIOKOL CHEMICAL CORP
发明人： KANAVEL GAYLORD A , BULBENKO GEORGE F
IPC分类号： C08K5/405
CPC分类号： C08K5/405 , C08L33/06 , C08L33/20

8. 发明授权

US3329674A Aziridinyl derivatives of polyfunctional epoxides 失效
标题翻译：多官能环氧化物的氮丙啶衍生物
公开(公告)号：US3329674A
公开(公告)日：1967-07-04
申请号：US32085663
申请日：1963-11-01
申请人： THIOKOL CHEMICAL CORP
发明人： BULBENKO GEORGE F , GOBRAN RIAD H , BLOMMERS ELIZABETH A
IPC分类号： C07D203/10 , C07D203/12 , C08G59/28 , C08G59/32 , C08G59/50 , C08K5/3412
CPC分类号： C07D203/12 , C07D203/10 , C08G59/28 , C08G59/32 , C08G59/5066 , C08K5/3412

9. 发明授权

US3522205A Ethylene sulfide polymers stabilized with polyamine additives 失效
标题翻译：用聚氨酯添加剂稳定的乙烯磺化聚合物
公开(公告)号：US3522205A
公开(公告)日：1970-07-28
申请号：US3522205D
申请日：1968-04-09
申请人： THIOKOL CHEMICAL CORP
发明人： GOBRAN RIAD H , BULBENKO GEORGE F , PETERSON ELIZABETH A
IPC分类号： C08K5/17 , C08G51/60
CPC分类号： C08K5/17 , C08L81/02

10. 发明授权

US3342770A Fluid resistant silicaceous compositions containing poly(episulfide) and impregnation process therefor 失效
标题翻译：含有聚（环硫化物）和浸渍方法的耐流体硅质组合物
公开(公告)号：US3342770A
公开(公告)日：1967-09-19
申请号：US36959864
申请日：1964-05-22
申请人： THIOKOL CHEMICAL CORP
发明人： OSBORN STEPHEN W , BULBENKO GEORGE F
IPC分类号： C08G75/08
CPC分类号： C08G75/08 , Y10T428/31533

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