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1. 发明申请

US20160355621A1 Process for the Preparation of Ethylene Polymers Using a Number of Reactors Arranged in Series 审中-公开
标题翻译：使用多个串联的反应器制备乙烯聚合物的方法
公开(公告)号：US20160355621A1
公开(公告)日：2016-12-08
申请号：US15237705
申请日：2016-08-16
申请人： Total Research & Technology Feluy
发明人： Mieke Dams , Daniel Siraux
IPC分类号： C08F210/16
CPC分类号： C08F210/16 , C08F4/24 , C08F4/65912 , C08F4/65927 , C08F10/00 , C08F110/02 , C08F4/65916 , C08F2/001 , C08F2500/12 , C08F210/14
摘要： The present invention relates to a process for the preparation of ethylene polymers using a number of reactors arranged in series comprising the steps in whicha) ethylene, a diluent, a catalyst, a co-catalyst and optionally comonomers and hydrogen are introduced into a first reactor, b) polymerization of ethylene and optionally comonomers is carried out in the reaction mixture of said first reactor to make ethylene polymers, c) reaction mixture is discharged from said first reactor, d) said reaction mixture and fresh ethylene and optionally comonomers and hydrogen are introduced into the consecutive reactor to make additional ethylene polymers, e) said reaction mixture is discharged from said consecutive reactor and introduced into the further consecutive reactor, if any, with fresh ethylene and optionally comonomers and hydrogen to make additional ethylene polymers, steps c) and d) are repeated until the last reactor of the series, f) reaction mixture is discharged from last reactor of the series and ethylene polymers are recovered, wherein, additional co-catalyst is injected in at least a subsequent reactor of the series. Advantage of the process of the present invention is mainly to decrease catalyst consumption for the same polyethylene production, in other words to increase the productivity. In a most preferred embodiment the process of the present invention is carried out in two loop reactors under slurry conditions.
摘要翻译：本发明方法的优点主要是减少相同聚乙烯生产的催化剂消耗，换句话说是提高生产率。在最优选的实施方案中，本发明的方法在浆液条件下在两个环管反应器中进行。

2. 发明授权

US09340631B2 Process for preparing a polyethylene resin 有权
标题翻译：制备聚乙烯树脂的方法
公开(公告)号：US09340631B2
公开(公告)日：2016-05-17
申请号：US14417530
申请日：2013-07-24
申请人： TOTAL RESEARCH & TECHNOLOGY FELUY
发明人： Christopher Willocq , Daniel Siraux , Aurélien Vantomme , Olivier Miserque
IPC分类号： C08F4/02 , C08F4/6592 , C08F210/16 , C08L23/08 , C08F110/02 , C08L23/06 , C08F4/659
CPC分类号： C08F110/02 , C08F4/02 , C08F4/65912 , C08F4/65916 , C08F210/16 , C08L23/06 , C08L23/0815 , C08F10/02 , C08F4/65927 , C08F4/025 , C08F2/001 , C08F210/14 , C08F2500/05 , C08F2500/07 , C08F2500/12 , C08F2500/26
摘要： A process for preparing a polyethylene resin having a multimodal molecular weight distribution in at least two loop slurry reactors connected in series can include polymerizing ethylene in the presence of at least one supported metallocene catalyst, a diluent, optionally one or more co-monomers, and optionally hydrogen, thereby obtaining the polyethylene resin. The supported metallocene catalyst can have a particle size distribution of a span value lower than 2.5 and a D50 value within the range of from 5 μm to 20 μm.
摘要翻译：在至少两个串联连接的循环淤浆反应器中制备具有多峰分子量分布的聚乙烯树脂的方法可以包括在至少一种负载的茂金属催化剂，稀释剂，任选的一种或多种共聚单体的存在下聚合乙烯，以及任选地氢，由此得到聚乙烯树脂。负载型茂金属催化剂可以具有跨度值低于2.5的粒度分布和在5μm至20μm范围内的D50值。

3. 发明申请

US20140371397A1 HIGH-DENSITY POLYETHYLENE FOR CAPS AND CLOSURES 有权
标题翻译：高密度聚乙烯胶囊和胶囊
公开(公告)号：US20140371397A1
公开(公告)日：2014-12-18
申请号：US14348135
申请日：2012-09-28
申请人： TOTAL RESEARCH & TECHNOLOGY FELUY
发明人： David Ribour , Alain Standaert , Daniel Siraux , Ludovic Horion , Olivier Lhost
IPC分类号： C08L23/06 , B29D99/00
CPC分类号： C08L23/06 , B29D99/0096 , B29L2031/565 , C08L23/04 , C08L2205/02 , C08L2205/025 , C08L2207/062
摘要： A high-density polyethylene (HDPE) can be adapted for the manufacture of caps and closures. The caps and closures can be used as screw-on caps for carbonated or still drinks. The high-density polyethylene can have a density of at least 940 kg/m3 and of at most 970 kg/m3, and a high load melt index HLMI of at least 35 dg/min and of at most 180 dg/min. The high-density polyethylene can include a first polyethylene fraction and a second polyethylene fraction. The first polyethylene fraction can have a density of at least 920 kg/m3 and of at most 945 kg/m3, and a melt index HL275 of at least 3 dg/min and of at most 12 dg/min. The second polyethylene fraction can have a density of at least 960 kg/m3 and of at most 980 kg/m3.
摘要翻译：高密度聚乙烯（HDPE）可用于制造瓶盖和瓶盖。盖子和盖子可用作碳酸饮料或静止饮料的螺旋盖。高密度聚乙烯可以具有至少940kg / m 3和至多970kg / m 3的密度和至少35dg / min和至多180dg / min的高负荷熔体指数HLMI。高密度聚乙烯可以包括第一聚乙烯部分和第二聚乙烯部分。第一聚乙烯部分的密度可以至少为920kg / m 3，至多945kg / m 3，熔体指数HL275至少为3dg / min，最高为12dg / min。第二聚乙烯部分的密度可以至少为960kg / m 3，至多为980kg / m 3。

4. 发明申请

US20140288258A1 Bimodal Polyethylene 有权
标题翻译：双峰聚乙烯
公开(公告)号：US20140288258A1
公开(公告)日：2014-09-25
申请号：US14299702
申请日：2014-06-09
申请人： TOTAL RESEARCH & TECHNOLOGY FELUY
发明人： Aurélien Vantomme , Daniel Siraux , Alain Van Sinoy , Jean-Léon Gielens
IPC分类号： C08F110/02
CPC分类号： B01J19/2435 , B01J8/00 , C08F2/01 , C08F10/00 , C08F10/02 , C08F110/02 , Y10T428/1352 , Y10T428/139 , Y10T428/1393 , Y10T428/1397 , Y10T428/31855 , C08F2/001 , C08F4/6548 , C08F2/14 , C08F4/6546 , C08F4/6557
摘要： The invention relates to A process for the polymerisation of ethylene to produce a polyethylene resin in at least two slurry loop reactors connected to each other in series, the resin having a bimodal molecular weight distribution, a molecular weight distribution MWD of at least 7.0, an HLMI of from 1 to 100 g/10 min, and a density of from 0.935 to 0.960 g/cm3, wherein in one reactor 30 to 47 wt % based on the total weight of the polyethylene resin of a high molecular weight (HMW) polyethylene fraction is produced having an HL275 of from 0.05 to 1.8 g/10 min (the equivalent of HLMI of from 0.01 to 1.56 g/10 min), a density of from 0.925 to 0.942 g/cm3 and an MWD of at least 5.0, and in the other reactor a low molecular weight (LMW) polyethylene fraction is produced having an HLMI of from 10 to 1500 g/10 min and a density of from 0.960 to 0.975 g/cm3, in the presence of a Ziegler-Natta catalyst system.
摘要翻译：本发明涉及一种在至少两个串联连接的浆料环管反应器中聚合乙烯以生产聚乙烯树脂的方法，该树脂具有双峰分子量分布，至少7.0的分子量分布MWD， HLMI为1至100g / 10分钟，密度为0.935至0.960g / cm3，其中在一个反应器中基于聚乙烯树脂的总重量为30至47wt％的高分子量（HMW）聚乙烯产生HL275为0.05〜1.8g / 10min（相当于HLMI为0.01〜1.56g / 10min），密度为0.925〜0.942g / cm3，MWD为5.0以上的级分，以及在另一反应器中，在齐格勒 - 纳塔催化剂体系的存在下，制备HLMI为10-1500g / 10min，密度为0.960-0.975g / cm3的低分子量（LMW）聚乙烯级分。

5. 发明授权

US08796400B2 Double loop technology 有权
标题翻译：双环技术
公开(公告)号：US08796400B2
公开(公告)日：2014-08-05
申请号：US13917795
申请日：2013-06-14
申请人： Total Research & Technology Feluy
发明人： Louis Fouarge , Eric Damme , Olivier Miserque , Daniel Siraux , Philippe Bodart , Andre Lewalle , Marc Van der Auwera , Frans Van den Brande , Giacomo Conti , Hugo Vandaele , Mark Verleysen , Carl Van Camp , Etienne Laurent , Philippe Marechal , Marc Moers , Leopold D'Hooghe , Marjan Sillis , Kai Hortman , Pascal Folie , Renaud Oreins
IPC分类号： C08F2/12 , B01J19/18
CPC分类号： C08F110/02 , B01J8/0015 , B01J2208/00548 , C08F2/005 , C08F2/01 , C08F10/02 , C08F210/16 , Y10S526/919 , Y10T137/85978 , Y10T137/86035 , C08F2/14 , C08F210/14 , C08F2500/04 , C08F2500/12 , C08F2500/18 , C08F210/08 , C08F2/001
摘要： A method for the copolymerization of ethylene and a C3+ olefin in a loop reactor and polymers formed therefrom are described herein. The method generally includes introducing an ethylene monomer, a C3+ olefin and a diluent carrier liquid into a loop reactor. A catalyst system can be supplied to said loop reactor. The diluent liquid, ethylene monomer, and C3+ olefin can be circulated through said loop reactor, while copolymerizing said ethylene and C3+ olefin in the presence of said catalyst system to produce a slurry. The slurry can be diverted into a settling leg, and sequentially discharged therefrom and withdrawn from said loop reactor. An ethylene monomer co-feed can be introduced into said loop reactor at spaced locations downstream of the ethylene and diluent. The ethylene co-feed can be introduced in an amount effective to reduce the variation in the ratio of ethylene and C3+ olefin.
摘要翻译：本文描述了环管式反应器中乙烯与C 3+烯烃的共聚方法及其形成的聚合物。该方法通常包括将乙烯单体，C 3+烯烃和稀释剂载体液体引入环管反应器。催化剂体系可以供应到所述环管反应器。稀释液体，乙烯单体和C3 +烯烃可以在所述环管反应器中循环，同时在所述催化剂体系存在下共聚所述乙烯和C 3+烯烃以产生浆料。浆料可以转移到沉降腿中，并且顺序地从其中排出并从所述环管反应器中取出。可以在乙烯和稀释剂下游的间隔位置将乙烯单体共进料引入所述环管反应器。可以以有效减少乙烯和C 3+烯烃的比例变化的量引入乙烯共进料。

6. 发明申请

US20190194371A1 Process for the Preparation of Ethylene Polymers Using a Number of Reactors Arranged in Series 审中-公开
公开(公告)号：US20190194371A1
公开(公告)日：2019-06-27
申请号：US16291354
申请日：2019-03-04
申请人： Total Research & Technology Feluy
发明人： Mieke Dams , Daniel Siraux
IPC分类号： C08F210/16 , C08F10/00
CPC分类号： C08F210/16 , C08F4/24 , C08F4/65912 , C08F4/65927 , C08F10/00 , C08F110/02 , C08F4/65916 , C08F2/001 , C08F2500/12 , C08F210/14
摘要： The present invention relates to a process for the preparation of ethylene polymers using a number of reactors arranged in series comprising the steps in whicha) ethylene, a diluent, a catalyst, a co-catalyst and optionally comonomers and hydrogen are introduced into a first reactor, b) polymerization of ethylene and optionally comonomers is carried out in the reaction mixture of said first reactor to make ethylene polymers, c) reaction mixture is discharged from said first reactor, d) said reaction mixture and fresh ethylene and optionally comonomers and hydrogen are introduced into the consecutive reactor to make additional ethylene polymers, e) said reaction mixture is discharged from said consecutive reactor and introduced into the further consecutive reactor, if any, with fresh ethylene and optionally comonomers and hydrogen to make additional ethylene polymers, steps c) and d) are repeated until the last reactor of the series, f) reaction mixture is discharged from last reactor of the series and ethylene polymers are recovered, wherein, additional co-catalyst is injected in at least a subsequent reactor of the series. Advantage of the process of the present invention is mainly to decrease catalyst consumption for the same polyethylene production, in other words to increase the productivity. In a most preferred embodiment the process of the present invention is carried out in two loop reactors under slurry conditions.

7. 发明申请

US20150175720A1 Double Loop Technology 审中-公开
标题翻译：双回路技术
公开(公告)号：US20150175720A1
公开(公告)日：2015-06-25
申请号：US14573095
申请日：2014-12-17
申请人： Total Research & Technology Feluy
发明人： Louis Fouarge , Eric Damme , Olivier Miserque , Daniel Siraux , Philippe Bodart , Andre Lewalle , Marc Van der Auwera , Frans Van den Brande , Giacomo Conti , Hugo Vandaele , Mark Verleysen , Carl Van Camp , Etienne Laurent , Philippe Marechal , Marc Moers , Leopold D'Hooghe , Marjan Sillis , Kai Hortman , Pascal Folie , Renaud Oreins
IPC分类号： C08F2/01 , C08F2/00
CPC分类号： C08F110/02 , B01J8/0015 , B01J2208/00548 , C08F2/005 , C08F2/01 , C08F10/02 , C08F210/16 , Y10S526/919 , Y10T137/85978 , Y10T137/86035 , C08F2/14 , C08F210/14 , C08F2500/04 , C08F2500/12 , C08F2500/18 , C08F210/08 , C08F2/001
摘要： The present invention relates to an apparatus and process for polymerizing olefins. One embodiment comprises polymerizing at least one monomer in a first loop reactor in the presence of a catalyst to produce a first polyolefin fraction. A portion of the first polyolefin fraction is transferred to a second loop reactor, connected in series with the first loop reactor. The process further comprises polymerizing in the second loop reactor at least one monomer in the presence of a catalyst to produce a second polyolefin fraction in addition to the first polyolefin fraction. The combination of the first and second polyolefin fractions can produce a polymer resin fluff having bimodal molecular weight distribution.
摘要翻译：本发明涉及一种聚合烯烃的装置和方法。一个实施方案包括在催化剂存在下在第一环管反应器中聚合至少一种单体以产生第一聚烯烃级分。将第一聚烯烃部分的一部分转移到与第一回路反应器串联连接的第二回路反应器。该方法还包括在催化剂存在下在第二环管反应器中聚合至少一种单体，以产生除第一聚烯烃级分之外的第二聚烯烃级分。第一和第二聚烯烃级分的组合可产生具有双峰分子量分布的聚合物树脂绒毛。

8. 发明申请

US20140050873A1 Blow Moulded Articles of Bimodal Polyethylene 有权
标题翻译：双模聚乙烯吹塑制品
公开(公告)号：US20140050873A1
公开(公告)日：2014-02-20
申请号：US14060779
申请日：2013-10-23
申请人： TOTAL RESEARCH & TECHNOLOGY FELUY
发明人： Aurélien Vantomme , Daniel Siraux , Alain Van Sinoy , Jean-Léon Gielens
IPC分类号： C08F10/02
CPC分类号： B01J19/2435 , B01J8/00 , C08F2/01 , C08F10/00 , C08F10/02 , C08F110/02 , Y10T428/1352 , Y10T428/139 , Y10T428/1393 , Y10T428/1397 , Y10T428/31855 , C08F2/001 , C08F4/6548 , C08F2/14 , C08F4/6546 , C08F4/6557
摘要： The invention relates to A process for the polymerisation of ethylene to produce a polyethylene resin in at least two slurry loop reactors connected to each other in series, the resin having a bimodal molecular weight distribution, a molecular weight distribution MWD of at least 7.0, an HLMI of from 1 to 100 g/10 min, and a density of from 0.935 to 0.960 g/cm3,wherein in one reactor 30 to 47 wt % based on the total weight of the polyethylene resin of a high molecular weight (HMW) polyethylene fraction is produced having an HL275 of from 0.05 to 1.8 g/10 min (the equivalent of HLMI of from 0.01 to 1.56 g/10 min), a density of from 0.925 to 0.942 g/cm3 and an MWD of at least 5.0, and in the other reactor a low molecular weight (LMW) polyethylene fraction is produced having an HLMI of from 10 to 1500 g/10 min and a density of from 0.960 to 0.975 g/cm3, in the presence of a Ziegler-Natta catalyst system.
摘要翻译：本发明涉及一种在至少两个串联连接的浆料环管反应器中聚合乙烯以生产聚乙烯树脂的方法，该树脂具有双峰分子量分布，至少7.0的分子量分布MWD， HLMI为1至100g / 10分钟，密度为0.935至0.960g / cm3，其中在一个反应器中基于聚乙烯树脂的总重量为30至47wt％的高分子量（HMW）聚乙烯产生HL275为0.05〜1.8g / 10min（相当于HLMI为0.01〜1.56g / 10min），密度为0.925〜0.942g / cm3，MWD为5.0以上的级分，以及在另一反应器中，在齐格勒 - 纳塔催化剂体系的存在下，制备HLMI为10-1500g / 10min，密度为0.960-0.975g / cm3的低分子量（LMW）聚乙烯级分。

9. 发明授权

US09126179B2 Reactor for preparing polyolefin 有权
标题翻译：用于制备聚烯烃的反应器
公开(公告)号：US09126179B2
公开(公告)日：2015-09-08
申请号：US14444351
申请日：2014-07-28
申请人： Total Research & Technology Feluy
发明人： Eric Damme , Louis Fouarge , Jerome Bette , Alvaro Fernandez , Aurelien Vantomme , Renaud Oreins , Daniel Siraux
IPC分类号： B01J19/18 , C08F2/00 , C08F210/00 , B01J19/24 , C08F10/00 , C08F110/02 , C08F10/02 , C08F2/01 , B01J8/00
CPC分类号： B01J19/2435 , B01J8/00 , C08F2/01 , C08F10/00 , C08F10/02 , C08F110/02 , Y10T428/1352 , Y10T428/139 , Y10T428/1393 , Y10T428/1397 , Y10T428/31855 , C08F2/001 , C08F4/6548 , C08F2/14 , C08F4/6546 , C08F4/6557
摘要： The invention relates to a process for preparing polyolefin in a loop reactor. The polymer is prepared by polymerizing olefin monomers in the presence of a catalyst to produce a polyolefin slurry while pumping said slurry through said loop reactor by means of a pump. The present process is characterized in that the catalyst is fed in the loop reactor at a distance to the pump. The invention allows production of the polymer with advantageous properties while leading to fewer blockages of the reactor.
摘要翻译：本发明涉及在环管反应器中制备聚烯烃的方法。通过在催化剂存在下聚合烯烃单体制备聚合物，以产生聚烯烃淤浆，同时通过泵将所述浆料泵送通过所述环管反应器。本发明的方法的特征在于催化剂在环流反应器中与泵相距一定距离。本发明允许生产具有有利性质的聚合物，同时导致更少的反应器阻塞。

10. 发明申请

US20150239999A1 Process for Preparing a Polyethylene Resin 有权
标题翻译：制备聚乙烯树脂的方法
公开(公告)号：US20150239999A1
公开(公告)日：2015-08-27
申请号：US14417530
申请日：2013-07-24
申请人： TOTAL RESEARCH & TECHNOLOGY FELUY
发明人： Christopher Willocq , Daniel Siraux , Aurélien Vantomme , Olivier Miserque
IPC分类号： C08F110/02
CPC分类号： C08F110/02 , C08F4/02 , C08F4/65912 , C08F4/65916 , C08F210/16 , C08L23/06 , C08L23/0815 , C08F10/02 , C08F4/65927 , C08F4/025 , C08F2/001 , C08F210/14 , C08F2500/05 , C08F2500/07 , C08F2500/12 , C08F2500/26
摘要： A process for preparing a polyethylene resin having a multimodal molecular weight distribution in at least two loop slurry reactors connected in series can include polymerizing ethylene in the presence of at least one supported metallocene catalyst, a diluent, optionally one or more co-monomers, and optionally hydrogen, thereby obtaining the polyethylene resin. The supported metallocene catalyst can have a particle size distribution of a span value lower than 2.5 and a D50 value within the range of from 5 μm to 20 μm.
摘要翻译：在至少两个串联连接的循环淤浆反应器中制备具有多峰分子量分布的聚乙烯树脂的方法可以包括在至少一种负载的茂金属催化剂，稀释剂，任选的一种或多种共聚单体的存在下聚合乙烯，以及任选地氢，由此得到聚乙烯树脂。负载型茂金属催化剂可以具有跨度值低于2.5的粒度分布和在5μm至20μm范围内的D50值。

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