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    • 3. 发明申请
    • BLOCK COPOLYMER COMPOSITION, PRODUCTION METHOD THEREFOR, AND FILM
    • 嵌段共聚物组合物,其制备方法和薄膜
    • US20170009070A1
    • 2017-01-12
    • US15107179
    • 2014-12-26
    • ZEON CORPORATION
    • Ryoji ODAYuta ISHII
    • C08L53/02C08J5/18
    • C08L53/02A61F13/49009C08J5/18C08J2353/02C08L2203/16C08L2205/025
    • The present invention provides a block copolymer composition comprising a block copolymer A represented by formula (A) and a block copolymer B represented by formula (B), the block copolymer composition having a water content of 200 ppm by weight or less when the block copolymer composition has been formed in a shape of pellets, dried, and allowed to stand at a temperature of 37° C. and a relative humidity of 70% for 24 hours. In the formulas, Ar1a, Ar1b, and Ar2b are aromatic vinyl polymer blocks having a weight average molecular weight of 6,000-18,000, Ar2a is an aromatic vinyl polymer block having a weight average molecular weight of 40,000-400,000, and Da and Db are specific conjugated diene polymer blocks. The block copolymer composition has a high modulus of elasticity, exhibits low tension set, and ensures that the formation of a hole is prevented when a film is formed by melt-forming the block copolymer composition. Ar11-Da-Ar2a   (A) Ar1b-Db-Ar2b   (B)
    • 本发明提供包含式(A)表示的嵌段共聚物A和式(B)所示的嵌段共聚物B的嵌段共聚物组合物,嵌段共聚物组合物的含水量为200重量ppm以下时, 组合物已经形成为颗粒形状,干燥并在37℃的温度和70%的相对湿度下静置24小时。 式中,Ar1a,Ar1b,Ar2b为重均分子量为6000〜1800的芳香族乙烯基聚合物嵌段,Ar2a为重均分子量为40,000〜40000的芳香族乙烯基聚合物嵌段,D a和d b是特定的共轭二烯聚合物嵌段。 嵌段共聚物组合物具有高弹性模量,显示低张力设定,并且确保当通过熔融形成嵌段共聚物组合物形成膜时,防止形成孔。 €ƒ€€ƒ€ƒ€ƒ€ƒ€ƒAr1a -D a -Ar2 a€ƒ€ƒ€ƒ€(ƒ)€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ €ƒAr1b -D b -Ar2 b€ƒ€ƒ€ƒ€ƒ(B)