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    • 8. 发明授权
    • All-solid lithium ion secondary battery
    • 全固态锂离子二次电池
    • US09413033B2
    • 2016-08-09
    • US14030358
    • 2013-09-18
    • OHARA INC.
    • Kazuhito Ogasa
    • H01M10/0562H01M10/0525H01M4/485H01M4/58
    • H01M10/0562H01M4/485H01M4/5825H01M10/0525H01M2300/0071Y02E60/122Y02P70/54
    • To provide an all-solid lithium ion secondary battery having a high voltage, a small internal resistance, and a discharge capacity close to a theoretical capacity and being able to be produced at low cost, and therefore, even in the case of collective sintering, generation of an inactive material due to interface reaction at the interface between an electrode active material and a solid electrolyte is reduced. An all-solid lithium ion secondary battery including a positive electrode layer, a negative electrode layer, and a solid electrolyte layer disposed between the positive electrode layer and the negative electrode layer, wherein an electrode active material included in the positive electrode layer is a phosphate having an olivine structure; and a solid electrolyte crystal included in the solid electrolyte layer includes polyphosphoric acid and the content of Li2O is 16 mol % to 25 mol % in terms of mol % on an oxide basis.
    • 为了提供具有高电压,小内阻和接近理论容量的放电容量并且能够以低成本制造的全固态锂离子二次电池,因此即使在集体烧结的情况下, 由于在电极活性物质和固体电解质之间的界面处的界面反应导致的非活性材料的产生减少。 包括设置在正极层和负极层之间的正极层,负极层和固体电解质层的全固体锂离子二次电池,其中,包含在正极层中的电极活性物质是磷酸盐 具有橄榄石结构; 包含在固体电解质层中的固体电解质晶体包含多磷酸,Li 2 O的含量以氧化物为基准的摩尔%计为16摩尔%〜25摩尔%。
    • 10. 发明授权
    • Glass-ceramics
    • 玻璃陶瓷
    • US08257831B2
    • 2012-09-04
    • US12108109
    • 2008-04-23
    • Toshitaka Yagi
    • Toshitaka Yagi
    • B32B17/00C03C10/12
    • G11B5/7315C03C3/083C03C10/0027
    • Glass-ceramics include SiO2, Al2O3 and Li2O on oxide basis. In the glass-ceramics, total amount in mass % of SiO2 and Al2O3 is less than 77% and Li2O/(SiO2+Al2O3) which is the ratio in mass % of the amount of Li2O to the total amount of SiO2 and Al2O3 is 0.064 or over. The glass-ceramics include at least one crystal phase selected from the group consisting of β-quartz, β-quartz solid solution, β-eucryptite, β-eucryptite solid solution, β-spodumene and β-spodumene solid solution.
    • 玻璃陶瓷包括基于氧化物的SiO 2,Al 2 O 3和Li 2 O。 在玻璃陶瓷中,SiO 2和Al 2 O 3的质量%的总量小于77%,作为Li 2 O的质量%与SiO 2和Al 2 O 3的总量的比例的Li 2 O /(SiO 2 + Al 2 O 3)为0.064 或以上。 玻璃陶瓷包括至少一种选自以下的结晶相:石英,石英固溶体,白云母,白云母固体溶液,白云母和白云母固体; 解。