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1. 发明申请

US20140038486A1 Catalyst System, Process For Olefin Polymerization, And Polymer Compositions Produced Therefrom 有权
标题翻译：催化剂体系，烯烃聚合方法及其制备的聚合物组合物
公开(公告)号：US20140038486A1
公开(公告)日：2014-02-06
申请号：US14049558
申请日：2013-10-09
申请人： ExxonMobil Chemical Patents Inc.
发明人： Donna J. Crowther , Peijun Jiang , Rainer Kolb
IPC分类号： C08F4/76
CPC分类号： C08F210/06 , B01J31/0201 , B01J31/0235 , B01J31/0239 , B01J31/0254 , B01J31/0255 , B01J31/146 , B01J31/1608 , B01J31/1616 , B01J31/2295 , B01J2231/122 , B01J2531/0269 , B01J2531/0297 , B01J2531/40 , B01J2531/48 , B01J2531/49 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F10/06 , C08F110/06 , C08F210/02 , C08F210/16 , Y10S526/943 , Y10T442/60 , C08F4/65908 , C08F2500/08 , C08F2500/20 , C08F2500/03 , C08F2500/17
摘要： Provided are catalyst systems, processes for polymerizing one or more olefins, polymers resulting therefrom, and articles prepared from such polymers. The processes comprise contacting under polymerization conditions one or more olefin monomers, preferably propylene, with a catalyst system comprising a transition metal compound and an activator of the formula (1) or (2) as described herein. The polymer compositions described herein exhibit advantageously narrow composition distributions and high melting points in comparison to conventional polymers having the same comonomer content. The polymers described herein exhibit improved properties, e.g., pellet stability, impact properties, heat seal properties, and structural integrity in film and fabricated parts applications.
摘要翻译：提供催化剂体系，聚合一种或多种烯烃的方法，由此产生的聚合物和由这些聚合物制备的制品。该方法包括在聚合条件下使一种或多种烯烃单体，优选丙烯与包含如本文所述的过渡金属化合物和式（1）或（2）的活化剂的催化剂体系接触。与具有相同共聚单体含量的常规聚合物相比，本文所述的聚合物组合物显示出有限的组成分布和高熔点。本文所述的聚合物表现出改进的性能，例如膜和制造零件应用中的颗粒稳定性，冲击性能，热封性能和结构完整性。

2. 发明申请

US20140005035A1 Supported Metallocene Catalysts 审中-公开
标题翻译：负载金属茂催化剂
公开(公告)号：US20140005035A1
公开(公告)日：2014-01-02
申请号：US14012420
申请日：2013-08-28
申请人： FINA TECHNOLOGY, INC.
发明人： William Gauthier , David Rauscher , Jun Tian , Nathan Williams
IPC分类号： C08F210/06
CPC分类号： C08F210/06 , B01J31/143 , B01J31/2295 , B01J2231/122 , B01J2531/48 , C08F4/65912 , C08F4/65927 , C08F210/16 , C08F4/65916 , C08F2500/15 , C08F2500/12 , C08F2500/18
摘要： Method employing a supported metallocene catalyst, composition in the production of an isotactic ethylene propylene co-polymer. The composition comprises a metallocene component supported on a particulate silica support having average particle size of 10-40 microns, a pore volume of 1.3-1.6 ml/g, a surface area of 200-400 m2/g. An alkylalumoxane cocatalyst component is incorporated on the support. The isospecific metallocene is characterized by the formula: B(CpRaRb)(FlR′2)MQn (1) or by the formula; B′(Cp′R′aR′b)(Fl′)M′Q′n′ (2) In the formulas Cp and Cp′ are substituted cyclopentadienyl groups, Fl and Fl′ are fluorenyl groups, and B and B′ are structural bridges. R′ are substituents at the 2 and 7 positions, Ra and R′are substituents distal to the bridge, and Rb and R′b are proximal to the bridge. M and M′ are transition metals, Q′ is a halogen or a C1-C4 alkyl group; and n′ is an integer of from 0-4.
摘要翻译：使用负载型茂金属催化剂的方法，制备全同立构乙烯丙烯共聚物的组合物。组合物包含负载在平均粒度为10-40微米，孔体积为1.3-1.6ml / g，表面积为200-400m2 / g的颗粒状二氧化硅载体上的金属茂组分。在载体上加入烷基铝氧烷助催化剂组分。特异性茂金属的特征在于下式：B（CpRaRb）（FlR'2）MQn（1）或式 B'（Cp'R'aR'b）（F1'）M'Q'n'（2）式中Cp和Cp'是取代的环戊二烯基，Fl和Fl'是芴基，B和B' 结构桥梁。 R'是2和7位的取代基，R a和R'是远离桥的取代基，Rb和R'b位于桥附近。 M和M'是过渡金属，Q'是卤素或C 1 -C 4烷基; 并且n'是0-4的整数。

3. 发明授权

US08563671B2 Supported metallocene catalysts 有权
标题翻译：负载金属茂催化剂
公开(公告)号：US08563671B2
公开(公告)日：2013-10-22
申请号：US13622206
申请日：2012-09-18
申请人： Fina Technology, Inc.
发明人： William Gauthier , David Rauscher , Jun Tian , Nathan Williams
IPC分类号： C08F4/642 , C08F4/6592 , C08F210/06
CPC分类号： C08F210/06 , B01J31/143 , B01J31/2295 , B01J2231/122 , B01J2531/48 , C08F4/65912 , C08F4/65927 , C08F210/16 , C08F4/65916 , C08F2500/15 , C08F2500/12 , C08F2500/18
摘要： Method employing a supported metallocene catalyst composition in the production of an isotactic ethylene propylene co-polymer. The composition comprises a metallocene component supported on a particulate silica support having average particle size of 10-40 microns, a pore volume of 1.3-1.6 ml/g, a surface area of 200-400 m2/g. An alkylalumoxane cocatalyst component is incorporated on the support. The isospecific metallocene is characterized by the formula: B(CpRaRb)(FlR′2)MQn (1) or by the formula: B′(Cp′R′aR′b)(Fl′)M′Q′n′ (2) In the formulas Cp and Cp′ are substituted cyclopentadienyl groups, Fl and Fl′ are fluorenyl groups, and B and B′ are structural bridges. R′ are substituents at the 2 and 7 positions, Ra and R′a are substituents distal to the bridge, and Rb and R′b are proximal to the bridge. M and M′ are transition metals, Q′ is a halogen or a C1-C4 alkyl group; and n′ is an integer of from 0-4.
摘要翻译：在制备全同立构乙烯丙烯共聚物中使用负载型茂金属催化剂组合物的方法。组合物包含负载在平均粒度为10-40微米，孔体积为1.3-1.6ml / g，表面积为200-400m2 / g的颗粒状二氧化硅载体上的金属茂组分。在载体上加入烷基铝氧烷助催化剂组分。特异性金属茂的特征是：B（CpRaRb）（FlR'2）MQn（1）或式：B'（Cp'R'aR'b）（Fl'）M'Q'n'（2 ）式中Cp和Cp'是取代的环戊二烯基，Fl和Fl'是芴基，B和B'是结构桥。 R'是2和7位的取代基，Ra和R'a是桥的远端的取代基，Rb和R'b靠近桥。 M和M'是过渡金属，Q'是卤素或C 1 -C 4烷基; 并且n'是0-4的整数。

4. 发明申请

US20120116033A1 Catalyst Components, Process for Their Preparation and Their Use as Catalyst Components in Polymerization of Olefins 审中-公开
标题翻译：催化剂组分，其制备方法及其作为烯烃聚合中催化剂组分的用途
公开(公告)号：US20120116033A1
公开(公告)日：2012-05-10
申请号：US13344368
申请日：2012-01-05
申请人： Abbas Razavi , Vladimir Marin , Margarito Lopez
发明人： Abbas Razavi , Vladimir Marin , Margarito Lopez
IPC分类号： C08F4/80 , C08F210/16 , C08F36/04 , C08F10/02 , C08F10/00 , C08F4/70 , C08F110/02
CPC分类号： B01J31/1815 , B01J2231/122 , B01J2531/842 , C07F15/025 , C08F10/00 , C08F110/02 , C08F2500/12 , C08F2500/04 , C08F2500/20 , C08F2500/19 , C08F2500/17 , C08F4/60089 , C08F4/7042
摘要： Catalyst compositions having Cs symmetry and processes utilizing Cs symmetric catalyst components for the polymerization of ethylenically unsaturated monomers to produce polymers, including copolymers or homopolymers. Monomers, which are polymerized or copolymerized include ethylene, C3+ alpha olefins and substituted vinyl compounds, such as styrene and vinyl chloride. The catalyst component is characterized by the formula: wherein M is a Group 4-11 transition metal, n is an integer of from 1-3, Q is halogen or a C1-C2 alkyl group, PY is a pyridinyl group, R′ and R″ are each C1-C20 hydrocarbyl group, A1 is a mononuclear aromatic group, and A2 is a polynuclear aromatic group, such as a terphenyl group. The catalyst component is used with an activating co-catalyst component such as an alumoxane. Also disclosed is a process for the preparation of a pyridinyl-linked bis-amino ligand suitable for use in forming the catalyst component.
摘要翻译：具有Cs对称性的催化剂组合物和利用Cs对称催化剂组分用于烯键式不饱和单体聚合以产生聚合物（包括共聚物或均聚物）的方法。聚合或共聚的单体包括乙烯，C 3+α-烯烃和取代的乙烯基化合物，例如苯乙烯和氯乙烯。催化剂组分的特征在于下式：其中M是4-11族过渡金属，n是1-3的整数，Q是卤素或C 1 -C 2烷基，P Y是吡啶基，R'和 R“分别为C1-C20烃基，A1为单核芳香族基团，A2为三联苯基等多核芳香族基团。催化剂组分与活化助催化剂组分如铝氧烷一起使用。还公开了制备适于用于形成催化剂组分的吡啶基连接的双 - 氨基配体的方法。

5. 发明申请

US20120029159A1 POLYDENTATE HETEROATOM LIGAND CONTAINING METAL COMPLEXES, CATALYSTS AND METHODS OF MAKING AND USING THE SAME 有权
标题翻译：包含金属复合物，催化剂及其制备和使用方法的聚异戊二烯配位体
公开(公告)号：US20120029159A1
公开(公告)日：2012-02-02
申请号：US13272569
申请日：2011-10-13
申请人： Jerzy Klosin , Lily Ackerman , Xiaohong Bei , Gary M. Diamond , James Longmire , Vince Murphy , Victor Nava-Salgado , James A.W. Shoemaker
发明人： Jerzy Klosin , Lily Ackerman , Xiaohong Bei , Gary M. Diamond , James Longmire , Vince Murphy , Victor Nava-Salgado , James A.W. Shoemaker
IPC分类号： C08F12/08
CPC分类号： B01J31/2204 , B01J2231/122 , B01J2531/0238 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07F7/003 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F110/06 , C08F112/08 , C08F4/659 , C08F4/64193 , C08F4/64196
摘要： Metal complexes comprising certain polydentate heteroatom containing ligands, catalysts, and coordination polymerization processes employing the same are suitably employed to prepare polymers having desirable physical properties.
摘要翻译：包含某些多齿杂原子的配体的金属配合物，催化剂和使用其的配位聚合方法适合用于制备具有所需物理性质的聚合物。

6. 发明申请

US20110312489A1 Fluorinated Alkoxy-Imino Catalyst Components 审中-公开
标题翻译：氟化烷氧基亚氨基催化剂组分
公开(公告)号：US20110312489A1
公开(公告)日：2011-12-22
申请号：US13214747
申请日：2011-08-22
申请人： Jean-Francois Carpentier , Evgueni Kirillov , Christophe Thomas , Abbas Razavi , Nicolas Marquet
发明人： Jean-Francois Carpentier , Evgueni Kirillov , Christophe Thomas , Abbas Razavi , Nicolas Marquet
IPC分类号： B01J31/22 , C07F7/28 , C07F7/00
CPC分类号： B01J31/143 , B01J31/2243 , B01J2231/122 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2540/22 , C07C251/08 , C07F7/00 , C07F7/003 , C08F10/00 , C08F4/64048
摘要： This invention relates to fluorinated alkoxy-imino metallic complexes and their use in catalyst systems for the polymerisation or oligomerisation of ethylene and alpha-olefins.
摘要翻译：本发明涉及氟化烷氧基 - 亚氨基金属络合物及其在催化剂体系中用于乙烯和α-烯烃聚合或低聚的用途。

7. 发明授权

US07998895B2 Catalysts for olefin polymerization 失效
标题翻译：用于烯烃聚合的催化剂
公开(公告)号：US07998895B2
公开(公告)日：2011-08-16
申请号：US12184467
申请日：2008-08-01
申请人： Lin Wang , Elisabeth M. Hauptman , Lynda Kaye Johnson , Elizabeth Forrester McCord , Stephan J. McLain , Ying Wang
发明人： Lin Wang , Elisabeth M. Hauptman , Lynda Kaye Johnson , Elizabeth Forrester McCord , Stephan J. McLain , Ying Wang
IPC分类号： C08F4/60 , C08F4/70 , C08F4/642
CPC分类号： C08F10/00 , B01J31/1805 , B01J31/2282 , B01J2231/122 , B01J2531/847 , C07F9/46 , C07F9/5004 , C07F9/5009 , C07F15/0066 , C07F15/04 , C07F15/045 , C08F4/619 , C08F110/02 , C08F210/02 , C08F2500/04 , C08F2500/10 , C08F2500/20 , C08F220/10 , C08F2500/03 , C08F220/12 , C08F4/6028 , C08F4/64065 , C08F4/7031 , C08F4/7029 , C08F4/7019 , C08F4/7022 , C08F4/7014 , C08F4/7008 , C08F4/7006 , C08F4/40
摘要： Transition metal complexes of selected monoanionic phosphine ligands, which also contain a selected Group 15 or 16 (IUPAC) element and which are coordinated to a Group 3 to 11 (IUPAC) transition metal or a lanthanide metal, are polymerization catalysts for the (co)polymerization of olefins such as ethylene and α-olefins, and the copolymerization of such olefins with polar group-containing olefins. These and other nickel complexes of neutral and monoanionic bidentate ligands copolymerize ethylene and polar comonomers, especially acrylates, at relatively high ethylene pressures and surprisingly high temperatures, and give good incorporation of the polar comonomers and good polymer productivity. These copolymers are often unique structures, which are described.
摘要翻译：还包含选定的第15或16族（IUPAC）元素并且与第3至11族（IUPAC）过渡金属或镧系元素金属配位的选择性单阴离子膦配体的过渡金属络合物是用于（共）烯烃如乙烯和α-烯烃的聚合，以及这些烯烃与极性基团烯烃的共聚。中性和单阴离子双齿配体的这些和其它镍配合物在相对高的乙烯压力和惊人的高温下共聚乙烯和极性共聚单体，特别是丙烯酸酯，并且使极性共聚单体具有良好的掺入性和良好的聚合物生产率。这些共聚物通常是独特的结构，其被描述。

8. 发明授权

US07951743B2 Preparation of ultra high molecular weight linear low density polyethylene 失效
标题翻译：制备超高分子线性低密度聚乙烯
公开(公告)号：US07951743B2
公开(公告)日：2011-05-31
申请号：US12220941
申请日：2008-07-29
申请人： Shaotian Wang
发明人： Shaotian Wang
IPC分类号： B01J31/38 , B01J31/34 , C08F4/52 , C08F4/64 , C08F4/76
CPC分类号： B01J31/128 , B01J31/143 , B01J31/146 , B01J31/2295 , B01J2231/122 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F4/65927 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2420/05 , C08F4/65904 , C08F210/08 , C08F2500/01 , C08F2500/08 , C08F2500/03
摘要： Disclosed is a method of preparing an ultra-high molecular weight, linear low density polyethylene with a catalyst system that comprises a bridged indenoindolyl transition metal complex, a non-bridged indenoindolyl transition metal complex, an alumoxane activator and a boron-containing activator. The ultra-high molecular weight, linear low density polyethylene has a weight average molecular weight greater than 1,000,000 and a density less than 0.940 g/cm3.
摘要翻译：公开了一种制备具有包含桥连茚基吲哚基过渡金属络合物，非桥连茚基吲哚基过渡金属络合物，铝氧烷激活剂和含硼活化剂的催化剂体系的超高分子量线性低密度聚乙烯的方法。超高分子量线性低密度聚乙烯的重均分子量大于1,000,000，密度小于0.940g / cm3。

9. 发明申请

US20110112262A1 SUPPORTED METALLOCENE CATALYSTS 有权
标题翻译：支持的金属催化剂
公开(公告)号：US20110112262A1
公开(公告)日：2011-05-12
申请号：US12882268
申请日：2010-09-15
申请人： William Gauthier , David Rauscher , Jun Tian , Nathan Williams
发明人： William Gauthier , David Rauscher , Jun Tian , Nathan Williams
IPC分类号： C08F4/76 , B01J31/14
CPC分类号： C08F210/06 , B01J31/143 , B01J31/2295 , B01J2231/122 , B01J2531/48 , C08F4/65912 , C08F4/65927 , C08F210/16 , C08F4/65916 , C08F2500/15 , C08F2500/12 , C08F2500/18
摘要： Method employing a supported metallocene catalyst composition in the production of an isotactic ethylene propylene co-polymer. The composition comprises a metallocene component supported on a particulate silica support having average particle size of 10-40 microns, a pore volume of 1.3-1.6 ml/g, a surface area of 200-400 m2/g. An alkylalumoxane cocatalyst component is incorporated on the support. The isospecific metallocene is characterized by the formula: B(CpRaRb)(FlR′2)MQn (1) or by the formula: B′(Cp′R′aR′b)(Fl′)M′Q′n′ (2) In the formulas Cp and Cp′ are substituted cyclopentadienyl groups, Fl and Fl′ are fluorenyl groups, and B and B′ are structural bridges. R′are substituents at the 2 and 7 positions, Ra and R′a are substituents distal to the bridge, and Rb and R′b are proximal to the bridge. M and M′ are transition metals, Q′ is a halogen or a C1-C4 alkyl group; and n′ is an integer of from 0-4.
摘要翻译：在制备全同立构乙烯丙烯共聚物中使用负载型茂金属催化剂组合物的方法。组合物包含负载在平均粒度为10-40微米，孔体积为1.3-1.6ml / g，表面积为200-400m2 / g的颗粒状二氧化硅载体上的金属茂组分。在载体上加入烷基铝氧烷助催化剂组分。特异性金属茂的特征是：B（CpRaRb）（FlR'2）MQn（1）或式：B'（Cp'R'aR'b）（Fl'）M'Q'n'（2 ）式中Cp和Cp'是取代的环戊二烯基，Fl和Fl'是芴基，B和B'是结构桥。 R'为2和7位的取代基，Ra和R'a是远离桥的取代基，Rb和R'b位于桥附近。 M和M'是过渡金属，Q'是卤素或C 1 -C 4烷基; 并且n'是0-4的整数。

10. 发明授权

US07932206B2 Magnesium dichloride-based adducts and catalyst components obtained therefrom 有权
标题翻译：二氯化镁基加合物和由此获得的催化剂组分
公开(公告)号：US07932206B2
公开(公告)日：2011-04-26
申请号：US10537079
申请日：2003-11-25
申请人： Diego Brita , Andrea Casalini , Daniele Evangelisti , Ofelia Fusco , Gianni Collina
发明人： Diego Brita , Andrea Casalini , Daniele Evangelisti , Ofelia Fusco , Gianni Collina
IPC分类号： B01J23/00 , B01J21/00 , B01J25/00 , B01J29/00 , B01J31/00 , B01J27/138
CPC分类号： B01J31/0209 , B01J23/02 , B01J31/0202 , B01J31/0204 , B01J31/0208 , B01J31/0212 , B01J31/0237 , B01J31/0274 , B01J31/128 , B01J31/143 , B01J2231/122 , B01J2531/22 , C08F10/06 , C08F110/06 , C08F4/6543 , C08F4/651 , C08F2500/18
摘要： Solid Lewis adducts comprising MgCl2, a Lewis base (LB) belonging to ethers, esters, ketones, silanes or amines and an alcohol ROH, in which R is a C1-C15 hydrocarbon group optionally substituted with heteroatoms containing groups, which compounds are in molar ratios to each other defined by the following formula MgCl2(ROH)m(LB)n in which m ranges from 0.05 to 6, n ranges from 0.08 to 6. The solid Lewis adducts herein can be used to prepare catalysts having good morphological stability, and high polymerization activity.
摘要翻译：固体Lewis加合物，其包含MgCl 2，属于醚，酯，酮，硅烷或胺的路易斯碱（LB）和醇ROH，其中R是任选被含杂原子的基团取代的C 1 -C 15烃基，该化合物为摩尔其中m为0.05至6，n为0.08至6.下列通式MgCl 2（ROH）m（LB）n定义：本文中的固体Lewis加合物可用于制备具有良好形态稳定性的催化剂，和高聚合活性。

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