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    • 1. 发明授权
    • Fragranced water-sensitive film
    • 香水敏感膜
    • US08927617B2
    • 2015-01-06
    • US12164539
    • 2008-06-30
    • Sarah A. FunkJames H. Wang
    • Sarah A. FunkJames H. Wang
    • A61L9/01A61F13/84B29C47/00B29C47/10C08J5/18C08L3/02B29C47/88B29C47/92A61L9/012B29K105/00
    • C08J5/18A61F13/8405A61L9/012B29C47/0021B29C47/0026B29C47/1063B29C47/1081B29C47/8845B29C47/8855B29C47/8865B29C47/887B29C47/8875B29C47/92B29C2947/92704B29K2105/0029C08J2303/02C08J2303/06C08J2303/08C08J2329/04C08K5/05C08K2201/007C08L3/02C08L3/06C08L3/08C08L29/04C08L67/00C08L2203/16Y10T428/31855
    • A film formed from a water-soluble polymer matrix within which is contained at least one fragrance is provided. The film is water-sensitive (e.g., water-soluble, water-dispersible, etc.) so that upon contact with a sufficient amount of water, the polymer matrix loses its integrity over time to increasingly expose the fragrance to the ambient environment for releasing its odor. The ability to incorporate a fragrance into the polymer matrix is achieved in the present invention by controlling a variety of aspects of the film construction, including the nature of the fragrance, the nature of the water-soluble polymer, the manner in which the polymer matrix and fragrance are melt processed, etc. For example, the fragrance may be injected directly into the extruder and melt blended with the water-soluble polymer. In this manner, the costly and time-consuming steps of pre-encapsulation or pre-compounding of the fragrance into a masterbatch are not required. Furthermore, to obtain a balance between the ability of the fragrance to release the desired odor during use and likewise to minimize the premature exhaustion of the odor during melt processing, the fragrance is selected to have a boiling point (at atmospheric pressure) within a certain range, such as from about 125° C. to about 350° C.
    • 提供由其中含有至少一种香料的水溶性聚合物基质形成的膜。 该膜具有水敏性(例如水溶性,水分散性等),使得在与足量的水接触时,聚合物基体随时间失去其完整性,以使香料逐渐暴露于周围环境以释放 其气味 通过控制膜结构的各个方面,包括香料的性质,水溶性聚合物的性质,聚合物基质的性质,在本发明中实现将香料引入聚合物基质中的能力 并且香料被熔融加工等。例如,香料可以直接注入挤出机中并与水溶性聚合物熔融共混。 以这种方式,不需要将预先包封或预混合成母料的昂贵且耗时的步骤。 此外,为了获得香料在使用期间释放所需气味的能力之间的平衡,并且同样使熔体加工期间气味的过早耗尽最小化,香味被选择为在一定程度上具有沸点(大气压) 范围,例如约125℃至约350℃
    • 6. 发明申请
    • Resin film forming method, and laminate production method and apparatus
    • 树脂膜形成方法和层压体制造方法和装置
    • US20040163769A1
    • 2004-08-26
    • US10790143
    • 2004-03-02
    • FUJI PHOTO FILM CO., LTD.
    • Tadahiro KegasawaRyuichi KatsumotoMasanori TakaseHidetoshi Okamura
    • B32B031/08B32B031/12
    • B32B37/153B29C47/0021B29C47/003B29C47/02B29C47/062B29C47/064B29C47/14B29C47/8845B29C47/8855B29C47/886B29C47/8875B32B37/0007B32B2309/66
    • In the resin film forming method for extruding a fused resin from an extruder die to form a resin film, the second resin forming both ends in width direction of the resin film uses a resin greater in extension viscosity than the first resin forming the center in width direction of the resin film. Thereby, even if production conditions such as resin condition and operating conditions change, faults such as neck-in and its resultant thickening at both ends of the resin film can be suppressed. In the production of a laminate by nipping a support and a resin film of a thermoplastic resin by means of a nip roller and a cooling roller while coating the resin film onto the surface of the support, the accompanying air following the rotation of the cooling roller to the nip point is shut off by blowing a gas permeable through the resin film from a gas jet nozzle toward the surface of the cooling roller. Thereby, the occurrence of craters can be inhibited, a laminate excellent in surface appearance can be produced and the production of a laminate effective especially at the time of a line speed rise in the laminate production is performable.
    • 在从挤出机模头挤出熔融树脂以形成树脂膜的树脂膜形成方法中,在树脂膜的宽度方向两端形成的第二树脂使用的树脂的延伸粘度大于形成宽度中心的第一树脂 树脂膜的方向。 由此,即使在树脂状态,工作条件等生产条件变化的情况下,也能够抑制树脂膜的两端的颈部及其加厚等缺陷。 在通过夹持辊和冷却辊夹持支撑体和热塑性树脂的树脂膜同时将树脂膜涂覆到支撑体的表面上来生产层压体时,随着冷却辊旋转的伴随空气 通过从气体喷射喷嘴朝向冷却辊的表面吹入可透过树脂膜的气体来切断夹点。 由此,可以抑制凹坑的发生,可以制造表面外观优异的层压体,特别是在层叠体制造中的线速度上升时,可以实现层叠体的生产。
    • 7. 发明授权
    • Low orientation thermoplastic sheet products and processes
    • 低取向热塑片材产品和工艺
    • US06093462A
    • 2000-07-25
    • US943716
    • 1997-10-03
    • Michael R. O'HerronGeorge R. Wright
    • Michael R. O'HerronGeorge R. Wright
    • B29C47/06B29C47/88B32B27/08B29D22/00
    • B29C47/065B29C47/0021B29C47/145B29C47/8845B29C47/8855B29C47/8875B32B27/08Y10T428/1334Y10T428/1341Y10T428/1379Y10T428/1383Y10T428/31533Y10T428/31728Y10T428/31786Y10T428/31855Y10T428/31909Y10T428/31928
    • Inherently low orientation sheet is produced by extruding a thermoplastic material in its melt phase onto the surface of a chill roller and thereafter solidifying the sheet at a relatively slow chill rate. Importantly, the just extruded thermoplastic polymeric sheet (i.e., the melt) is urged into continuous surface-to-surface contact with the chill roll by a curtain of air impinging upon the sheet at a velocity sufficient to ensure such continuous surface-to-surface contact between the sheet and the chill roll, but insufficient to impart substantial stress to the sheet. In such a manner, therefore, the resulting sheet will exhibit a low inherent internal stress level as evidenced by an unusually low shrink rate (ASTM D-1204) of less than about 18%. The sheets of the present invention are thus especially characterized by such unusually low shrink rates, and hence unusually low inherent internal stress levels which find particular utility as containers for the packaging industry--especially containers produced by melt-phase deep-draw thermoforming techniques.
    • 通过将其熔融相中的热塑性材料挤出到冷却辊的表面上,然后以相对较慢的冷却速率固化片材,从而产生固有的低取向片材。 重要的是,刚刚挤出的热塑性聚合物片材(即,熔体)通过以足以确保这种连续的表面到表面的速度通过撞击在片材上的空气的窗帘而被迫与冷却辊连续的表面 - 表面接触 片材和冷却辊之间的接触,但不足以对片材施加显着的应力。 因此,以这种方式,所得到的片材将表现出低固有的内应力水平,这是由于异常低的收缩率(ASTM D-1204)小于约18%所证明的。 因此,本发明的片材特别地特征在于这种异常低的收缩率,因此特别是低的固有内部应力水平,其特别用作包装工业的容器,特别是通过熔融相深拉伸热成型技术生产的容器。