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    • 3. 发明申请
    • METHODS FOR FORMING PEROXYFORMIC ACID AND USES THEREOF
    • 用于形成过氧酸的方法及其用途
    • US20160176814A1
    • 2016-06-23
    • US14972308
    • 2015-12-17
    • Ecolab USA Inc.
    • RAMAKRISHNAN BALASUBRAMANIANJUNZHONG LIRICHARD STAUBVICTOR KEASLERBRIAN BENNETTALLISON BREWSTER
    • C07C409/24A01N37/16A23L3/3463C07C407/00
    • C07C409/24A01N37/16A23L3/34635A23L3/3508A23V2002/00C07C407/00C07C407/006
    • The present invention relates generally to methods for forming peroxyformic acid, comprising contacting formic acid with hydrogen peroxide. The methods for forming peroxyformic acid can include adding formic acid with a relatively lower concentration of hydrogen peroxide, or adding formic acid to a peroxycarboxylic acid composition or forming composition to react with hydrogen peroxide in the compositions. The present invention also relates to peroxyformic acid formed by the above methods. The present invention further relates to the uses of peroxyformic acid for treating a variety of targets, e.g., target water, including target water used in connection with oil- and gas-field operations. The present invention further relates to methods for reducing or removing H2S or iron sulfide in the treated water source, improving clarity of the treated water source, or reducing the total dissolved oxygen or corrosion in the treated water source, using peroxyformic acid, including peroxyformic acid generated in situ.
    • 本发明一般涉及形成过氧甲酸的方法,包括使甲酸与过氧化氢接触。 形成过氧甲酸的方法可以包括以较低浓度的过氧化氢加入甲酸,或将甲酸加入到过氧羧酸组合物中或形成组合物中以与组合物中的过氧化氢反应。 本发明还涉及通过上述方法形成的过氧甲酸。 本发明还涉及过氧甲酸用于处理各种靶物(例如目标水,包括与油气田操作有关的目标水)的用途。 本发明还涉及使用过氧甲酸(包括过氧甲酸)来减少或除去处理水源中的硫化氢或硫化铁的方法,提高处理水源的透明度或降低处理水源中的总溶解氧或腐蚀 原地生成。
    • 4. 发明申请
    • AQUEOUS EMULSION COMPOSITION OF ORGANIC PEROXIDE
    • 有机过氧化物的水性乳液组合物
    • US20150218293A1
    • 2015-08-06
    • US14429674
    • 2013-09-06
    • ARKEMA FRANCE
    • Isabelle TartarinJacques CochetAlbert Blum
    • C08F114/06
    • C08F114/06C07C407/006C07C409/00C08F4/32C08K5/14C08L29/04C08L71/02C08K5/04C08L27/06
    • An aqueous emulsion composition of organic peroxide, including from 10 to 65% by weight of one or a plurality of organic peroxides, from 2 to 25% by weight of at least one antifreeze agent, from 0.01 to 10% by weight of at least one emulsifying agent, optionally at least one additive, water, of which the quantity is defined in order to form the remainder of the total composition (100%), wherein the emulsifying agent is a colloid agent of a polyvinyl acetate having a degree of hydrolysis greater than 80% and a viscosity, measured in solution in water at 4% by weight at 20° C., less than or equal to 5 mPa·s, said viscosity being measured with a Brookfield RVT viscometer, needle no. 3, 20 rpm, in accordance with the ISO 2555 standard. Also, to the method of preparing same and the use thereof.
    • 一种有机过氧化物的水乳液组合物,包括10至65重量%的一种或多种有机过氧化物,2至25重量%的至少一种防冻剂,0.01至10重量%的至少一种 乳化剂,任选的至少一种添加剂,水,其量定义为形成总组合物的剩余部分(100%),其中乳化剂是具有水解度大的聚乙酸乙烯酯的胶体剂 80%以上,粘度,在20℃,4%(重量)的水溶液中测定,小于或等于5mPa·s,所述粘度用Brookfield RVT粘度计,针号测定。 3,20 rpm,符合ISO 2555标准。 此外,关于其制备方法及其用途。
    • 8. 发明授权
    • Peroxide compositions with reactive diluents
    • 具有活性稀释剂的过氧化物组合物
    • US07160951B2
    • 2007-01-09
    • US10451049
    • 2001-12-19
    • Jan H UddingAgnes E WoltersHeinz WilhelmArmin PfeilThomas BürgelLutz Sager
    • Jan H UddingAgnes E WoltersHeinz WilhelmArmin PfeilThomas BürgelLutz Sager
    • C08F261/06
    • C07C407/006C07C407/00C08F4/32C07C409/22C07C409/38C07C409/34C07C409/10
    • The invention relates to peroxide compositions comprising a reactive diluent for the peroxide, wherein the diluent is either a component containing one or more vinyl ether group(s) and having a monomeric structure according to formula 1, (A—CH═CH—O)n—R, or is a suitable resinous compound comprising, in a covalently built-in manner, a component containing one or more vinyl ether group(s). In the formula A represents hydrogen or an alkyl group with 1–3 C atoms, and individual A groups may be different R either represents an aliphatic group, optionally branched, with 1–20 C atoms, etc.  or represents a polyethylene or polypropylene glycol with 2 to 120 glycol units, etc. and n is 1, 2, 3 or 4. The resinous compounds comprising, in a covalently built-in manner, a component containing one or more vinyl ether group(s)are obtained by reaction of: a) a first compound (the HVE-compound) containing at least one hydroxyl group and at least one vinyl ether group, and b) a second compound (the D/HIC-compound), being an isocyanate, reacting with formation of one or more urethane group(s), and c) a third compound (the G/P/HP-compound) chosen from the groups of (1) C2-6 glycols, (2) C5-20 polyols having 2–5 hydroxyl groups and (3) hydroxyl terminated polyester compounds, not being alkyd resins, having 1–5 free hydroxyl groups and from 2–50 monomeric ester units (the G/P/HP-compound), or mixtures thereof. The invention also relates to the preparation of such compositions and to the use of such reactive diluents for peroxides in radically curing of unsaturated polyester resins for structural applications.
    • 本发明涉及包含用于过氧化物的反应性稀释剂的过氧化物组合物,其中稀释剂是含有一个或多个乙烯基醚基团并且具有根据式1的单体结构的组分(A-CH-CH-O) 或者是合适的树脂化合物,其以共价内置的方式包含含有一个或多个乙烯基醚基团的组分。 式A表示氢或具有1-3个C原子的烷基,各个A基团可以不同,R表示任选支链的1-20个C原子的脂族基团等,或代表聚乙烯或聚丙二醇 2〜120个二醇单元等,n为1,2,3或4.含有一个或多个乙烯基醚基的成分以共价内置的方式包含的树脂化合物是通过 :a)含有至少一个羟基和至少一个乙烯基醚基团的第一化合物(HVE-化合物),和b)作为异氰酸酯的第二化合物(D / HIC-化合物)与形成一个 或更多个氨基甲酸酯基团,和c)选自(1)C 2-6 - 二醇的第三化合物(G / P / HP-化合物),(2)C < 具有2-5个羟基的(3)羟基封端的聚酯化合物,不具有1-5个游离羟基的醇酸树脂和2-50个单体酯单元(t 他G / P / HP-化合物)或其混合物。 本发明还涉及这种组合物的制备以及这种反应性稀释剂在不饱和聚酯树脂的自由基固化中用于结构应用的过氧化物的用途。