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1. 发明申请

US20160362389A1 SYNTHETIC INTERMEDIATE OF 1-(2-DEOXY-2-FLUORO-4-THIO-ß-D-ARABINOFURANOSYL)CYTOSINE, SYNTHETIC INTERMEDIATE OF THIONUCLEOSIDE, AND METHOD FOR PRODUCING THE SAME 审中-公开
标题翻译： 1-（2-脱氧-2-氟-4-硫代-β-D-阿拉伯呋喃糖基）胞苷，合成中间体的合成中间体及其制备方法
公开(公告)号：US20160362389A1
公开(公告)日：2016-12-15
申请号：US15246177
申请日：2016-08-24
申请人： FUJIFILM Corporation
发明人： Kouki NAKAMURA , Satoshi SHIMAMURA , Junichi IMOTO , Motomasa TAKAHASHI , Katsuyuki WATANABE , Kenji WADA , Yuuta FUJINO , Takuya MATSUMOTO , Makoto TAKAHASHI , Hideki OKADA , Takehiro YAMANE , Takayuki ITO
IPC分类号： C07D333/32 , C07C309/73 , C07C47/277 , C07H7/04 , C07H13/04 , C07C309/66 , C07C69/78 , C07C69/618 , C07C69/76 , C07C69/28 , C07C69/96 , C07F7/18 , C07C251/38 , C07C251/40
CPC分类号： C07D333/32 , A61K31/7068 , C07B53/00 , C07C45/00 , C07C47/277 , C07C67/29 , C07C68/06 , C07C69/28 , C07C69/618 , C07C69/76 , C07C69/78 , C07C69/92 , C07C69/96 , C07C249/04 , C07C251/38 , C07C251/40 , C07C303/28 , C07C309/66 , C07C309/73 , C07F7/1804 , C07H1/00 , C07H7/04 , C07H13/04 , C07H13/08 , C07H15/04 , C07H15/18 , C07H15/203 , C07H17/02 , C07H19/06 , C07H19/067 , C07H19/073 , C07H23/00 , Y02P20/55
摘要： A compound represented by a formula [1D] as shown below (wherein R1A, R1B, R2A, R2B, R3A and R3B represent a hydrogen atom, an optionally substituted C1-6 alkyl group, and the like) is useful as an intermediate for producing a thionucleoside, and the production method of the present invention is useful as a method for producing a thionucleoside.

2. 发明授权

US09505714B2 Conversion of alkanes to organoseleniums and organotelluriums 有权
标题翻译：烷烃转化为有机硒和有机碲
公开(公告)号：US09505714B2
公开(公告)日：2016-11-29
申请号：US14910275
申请日：2014-08-06
申请人： The Scripps Research Institute
发明人： Roy A. Periana , Michael M. Konnick , Brian G. Hashiguchi
IPC分类号： C07C45/00 , C07C395/00 , C07C1/00 , C07C209/00 , C07C319/00 , C07F7/00 , C07C391/00 , C07C1/32 , C07C319/02 , C07C319/14 , C07C17/093 , C07B39/00 , C07B41/06 , C07B43/04 , C07B45/00 , C07B47/00 , C07C209/22 , C07C231/10 , C07F7/22 , C07F9/50
CPC分类号： C07C395/00 , C07B39/00 , C07B41/06 , C07B43/04 , C07B45/00 , C07B47/00 , C07C1/321 , C07C17/093 , C07C45/00 , C07C209/22 , C07C231/10 , C07C319/02 , C07C319/14 , C07C391/00 , C07F7/2208 , C07F9/5004 , C07C321/04 , C07C321/14 , C07C11/02
摘要： The invention provides processes and materials for the efficient and costeffective functionalization of alkanes and heteroalkanes, comprising contacting the alkane or heteroalkane and a soft oxidizing electrophile comprising Se(VI) or Te(VI), in an acidic medium, optionally further comprising an aprotic medium, which can be carried out at a temperature of less than 300 C. Isolation of the alkylselenium or alkyltellurium intermediate allows the subsequent conversion to products not necessarily compatible with the initial reaction conditions, such as amines, stannanes, organosulfur compounds, acyls, halocarbons, and olefins.
摘要翻译：本发明提供用于烷烃和杂烷烃的有效和成本有效的功能化的方法和材料，包括在酸性介质中使烷烃或杂烷烃与包含Se（VI）或Te（VI）的软氧化亲电试剂接触，任选地还包含非质子介质可以在小于300℃的温度下进行。烷基硒或烷基碲中间体的分离允许随后转化成与初始反应条件不一致的产物，例如胺，锡烷，有机硫化合物，酰基，卤代烃，和烯烃。

3. 发明授权

US09481625B2 Process for producing cyclohexanone compound 有权
标题翻译：环己酮化合物的制备方法
公开(公告)号：US09481625B2
公开(公告)日：2016-11-01
申请号：US14779918
申请日：2014-04-01
申请人： Mitsui Chemicals, Inc.
发明人： Akira Matsuura , Takuro Watanabe
IPC分类号： C07C45/00 , B01J23/44 , B01J21/04 , B01J23/58 , B01J35/10 , B01J37/02 , B01J31/02 , C07D223/10
CPC分类号： C07C45/006 , B01J21/04 , B01J23/44 , B01J23/58 , B01J27/24 , B01J31/0237 , B01J31/0244 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J35/1066 , B01J37/0201 , B01J37/0203 , B01J37/0238 , C07C45/00 , C07D223/10 , C07C49/403
摘要： The invention has an object of providing an economical and highly efficient process for producing a cyclohexanone compound such as cyclohexanone. An aspect of the invention resides in a process for producing a cyclohexanone compound by performing hydrogenation reaction of a phenol compound in a gas phase in the presence of a palladium catalyst supported on a carrier to produce the corresponding cyclohexanone compound, wherein the hydrogenation reaction is carried out in the presence of at least one nitrogen compound selected from ammonia, amine compounds and heteroaromatic compounds.
摘要翻译：本发明的目的是提供一种用于生产环己酮化合物如环己酮的经济且高效的方法。本发明的一个方面在于通过在负载在载体上的钯催化剂的存在下在气相中进行酚化合物的氢化反应以制备相应的环己酮化合物来制备环己酮化合物的方法，其中进行氢化反应在至少一种选自氨，胺化合物和杂芳族化合物的氮化合物存在下进行。

4. 发明授权

US09475835B2 Synthetic intermediate of 1-(2-deoxy-2-fluoro-4-thio-β-D-arabinofuranosyl) cytosine, synthetic intermediate of thionucleoside, and method for producing the same 有权
标题翻译： 1-（2-脱氧-2-氟-4-硫代-β-D-阿拉伯呋喃糖基）胞嘧啶，硫代核苷的合成中间体及其制备方法的合成中间体
公开(公告)号：US09475835B2
公开(公告)日：2016-10-25
申请号：US14873966
申请日：2015-10-02
申请人： FUJIFILM Corporation
发明人： Kouki Nakamura , Satoshi Shimamura , Junichi Imoto , Motomasa Takahashi , Katsuyuki Watanabe , Kenji Wada , Yuuta Fujino , Takuya Matsumoto , Makoto Takahashi , Hideki Okada , Takehiro Yamane , Takayuki Ito
IPC分类号： C07D333/26 , C07D333/28 , C07D333/32 , C07H19/06 , A61K31/7068 , C07C303/28 , C07C45/00 , C07B53/00 , C07C309/73 , C07C249/04 , C07C251/38 , C07H13/04 , C07H13/08 , C07H15/04 , C07H15/18 , C07H15/203 , C07H17/02 , C07H19/067 , C07H19/073 , C07H23/00 , C07C69/78 , C07H1/00 , C07H7/04 , C07C67/29 , C07C68/06 , C07C69/28 , C07C69/618 , C07C69/76 , C07C69/92 , C07C69/96
CPC分类号： C07D333/32 , A61K31/7068 , C07B53/00 , C07C45/00 , C07C47/277 , C07C67/29 , C07C68/06 , C07C69/28 , C07C69/618 , C07C69/76 , C07C69/78 , C07C69/92 , C07C69/96 , C07C249/04 , C07C251/38 , C07C251/40 , C07C303/28 , C07C309/66 , C07C309/73 , C07F7/1804 , C07H1/00 , C07H7/04 , C07H13/04 , C07H13/08 , C07H15/04 , C07H15/18 , C07H15/203 , C07H17/02 , C07H19/06 , C07H19/067 , C07H19/073 , C07H23/00 , Y02P20/55
摘要： A compound represented by a formula [1D] as shown below (wherein R1A, R1B, R2A, R2B, R3A and R3B represent a hydrogen atom, an optionally substituted C1-6 alkyl group, and the like) is useful as an intermediate for producing a thionucleoside, and the production method of the present invention is useful as a method for producing a thionucleoside.

5. 发明申请

US20160186073A1 METHODS AND SYSTEMS FOR PROCESSING CELLULOSIC BIOMASS 审中-公开
标题翻译：用于处理细胞生物质的方法和系统
公开(公告)号：US20160186073A1
公开(公告)日：2016-06-30
申请号：US14980262
申请日：2015-12-28
申请人： SHELL OIL COMPANY
发明人： Joseph Broun POWELL , Glenn Charles KOMPLIN , Juben Nemchand CHHEDA
IPC分类号： C10G3/00 , C07C29/88 , C07C29/86 , C07C29/80 , B01J19/24 , C07C45/00 , C07C45/82 , C07C45/85 , C07C45/80 , C07C29/00 , C07D307/33
CPC分类号： C10G3/49 , B01D3/00 , B01J19/24 , B01J19/245 , B01J2219/24 , C07C29/00 , C07C29/80 , C07C29/86 , C07C29/88 , C07C45/00 , C07C45/80 , C07C45/82 , C07C45/85 , C07D307/33 , C08H6/00 , C08H8/00 , C10G1/002 , C10G1/065 , C10G1/083 , C10G3/50 , C10G2300/1014 , D21C3/20 , D21C3/222 , D21C5/005 , D21C11/0007 , D21C11/0042 , Y02P30/20
摘要： Separation of a product of digestion of cellulosic biomass solids may be challenging due to the various components contained therein. Methods and systems for processing cellulosic biomass, particularly a reaction product of a hydrothermal reaction containing lignin-derived products, such as phenolics, and organic salts, comprise providing acid solution to the organic salt containing process stream to convert the organic acid salts to acids to for further processing.
摘要翻译：纤维素生物质固体的消化产物的分离可能是由于其中所含的各种组分而具有挑战性的。用于处理纤维素生物质的方法和系统，特别是含有木质素衍生产物如酚类和有机盐的水热反应的反应产物包括向含有机盐的工艺流提供酸溶液以将有机酸盐转化为酸，进一步处理。

6. 发明申请

US20160176812A1 CONVERSION OF ALKANES TO ORGANOSELENIUMS AND ORGANOTELLURIUMS 有权
标题翻译：碱向有机物和有机物的转化
公开(公告)号：US20160176812A1
公开(公告)日：2016-06-23
申请号：US14910275
申请日：2014-08-06
申请人： Roy A. PERIANA , Michael M. KONNICK , Brian G. HASHIGUCHI , THE SCRIPPS RESEARCH INSTITUTE
发明人： Roy A. PERIANA , Michael M. KONNICK , Brian G. HASHIGUCHI
IPC分类号： C07C395/00 , C07C209/22 , C07F7/22 , C07C319/02 , C07C231/10 , C07F9/50 , C07C45/00 , C07C17/093 , C07B47/00 , C07B45/00 , C07B43/04 , C07B41/06 , C07B39/00 , C07C1/32 , C07C391/00
CPC分类号： C07C395/00 , C07B39/00 , C07B41/06 , C07B43/04 , C07B45/00 , C07B47/00 , C07C1/321 , C07C17/093 , C07C45/00 , C07C209/22 , C07C231/10 , C07C319/02 , C07C319/14 , C07C391/00 , C07F7/2208 , C07F9/5004 , C07C321/04 , C07C321/14 , C07C11/02
摘要： The invention provides processes and materials for the efficient and costeffective functionalization of alkanes and heteroalkanes, comprising contacting the alkane or heteroalkane and a soft oxidizing electrophile comprising Se(VI) or Te(VI), in an acidic medium, optionally further comprising an aprotic medium, which can be carried out at a temperature of less than 300 C. Isolation of the alkylselenium or alkyltellurium intermediate allows the subsequent conversion to products not necessarily compatible with the initial reaction conditions, such as amines, stannanes, organosulfur compounds, acyls, halocarbons, and olefins.
摘要翻译：本发明提供用于烷烃和杂烷烃的有效和成本有效的功能化的方法和材料，包括在酸性介质中使烷烃或杂烷烃与包含Se（VI）或Te（VI）的软氧化亲电试剂接触，任选地还包含非质子介质可以在小于300℃的温度下进行。烷基硒或烷基碲中间体的分离允许随后转化成与初始反应条件不一致的产物，例如胺，锡烷，有机硫化合物，酰基，卤代烃，和烯烃。

7. 发明授权

US09365477B2 Method for producing lavandulal 有权
标题翻译：薰衣草生产方法
公开(公告)号：US09365477B2
公开(公告)日：2016-06-14
申请号：US14778357
申请日：2014-03-06
申请人： KURARAY CO., LTD.
发明人： Junko Sato
IPC分类号： C07C45/51 , C07C45/00
CPC分类号： C07C45/00 , C07C45/515 , C07C47/21
摘要： Provided is a method of producing lavandulal at a high yield by controlling formation of its isomer of lavandulal as a by-product.In a method of producing lavandulal by making an acetal compound represented by the following formula (I) react with 3-methyl-1-butene-3-ol in the presence of an acid catalyst, the method includes: adding, to a liquid mixture comprising an acid catalyst, an acetal compound represented by the following formula (I), and 3-methyl-1-butene-3-ol in at least a portion of an amount to be used (3-methyl-1-butene-3-ol (a)), 3-methyl-1-butene-3-ol in the other portion of the amount to be used (3-methyl-1-butene-3-ol (b)); and maintaining the liquid mixture at a temperature of 110° C. or higher: in which Each R in the formula (I) represents an alkyl group.
摘要翻译：本发明提供通过控制其作为副产物形成薰衣草的异构体而以高产率生产薰衣草的方法。通过使下式（I）表示的缩醛化合物在酸催化剂的存在下与3-甲基-1-丁烯-3-醇反应来制造薰衣草的方法包括：向液体混合物包括酸催化剂，由下式（I）表示的缩醛化合物和至少一部分用量的3-甲基-1-丁烯-3-醇（3-甲基-1-丁烯-3 （3-甲基-1-丁烯-3-醇（b））的另一部分中的3-甲基-1-丁烯-3-醇。并将液体混合物保持在110℃或更高的温度：其中式（I）中的每个R表示烷基。

8. 发明申请

US20160108067A1 Method for Producing Fluorine-Containing Substituted Compound and Fluorine-Containing Substituted Compound 审中-公开
标题翻译：生产含氟取代的化合物和含氟取代的化合物的方法
公开(公告)号：US20160108067A1
公开(公告)日：2016-04-21
申请号：US14986238
申请日：2015-12-31
申请人： Kyoto University , Taiyo Nippon Sanso Corporation
发明人： Junichi Yoshida , Aiichiro Nagaki
IPC分类号： C07F7/22
CPC分类号： C07F7/2208 , C07C29/40 , C07C29/62 , C07C33/20 , C07C33/46 , C07C33/483 , C07C45/00 , C07C45/455 , C07C49/80 , C07C231/00 , C07C231/10 , C07C233/13 , C07C233/15 , C07F7/0805 , C07F7/12 , C07F7/122 , C07F9/28 , C07F9/5022 , C07F9/5068 , C07C233/07 , C07C233/05 , C07C49/233
摘要： A method for producing a fluorine-containing substituted compound, the method including: introducing an organofluorine compound and an organolithium compound into a microreactor provided with a flow path capable of mixing a plurality of liquids, to thereby obtain a reaction product; and introducing, into the microreactor, the reaction product and an electrophile exhibiting electrophilic effect on the reaction product, to thereby obtain a fluorine-containing substituted compound.
摘要翻译：一种含氟取代化合物的制造方法，其特征在于，将有机氟化合物和有机锂化合物引入到具有能够混合多种液体的流路的微反应器中，从而得到反应产物; 并向微反应器中引入反应产物和对反应产物显示亲电效应的亲电子试剂，从而获得含氟取代的化合物。

9. 发明申请

US20160075824A1 NOVEL COORDINATION COMPLEXES AND PROCESS OF PRODUCING POLYCARBONATE BY COPOLYMERIZATION OF CARBON DIOXIDE AND EPOXIDE USING THE SAME AS CATALYST 审中-公开
标题翻译：通过二氧化碳和环氧化物的共聚合制备聚碳酸酯的新协调复合物及其制备方法使用其作为催化剂
公开(公告)号：US20160075824A1
公开(公告)日：2016-03-17
申请号：US14941988
申请日：2015-11-16
申请人： SK INNOVATION CO., LTD.
发明人： Myungahn OK , Jisu JEONG , BunYeoul LEE , Sujith S. , Anish CYRIAC , JaeKi MIN , JongEon SEONG
IPC分类号： C08G64/34 , C07C45/00 , C07C249/02 , C07C37/16 , C07C251/24 , C07F15/06
CPC分类号： C08G64/34 , C07C37/16 , C07C39/24 , C07C45/00 , C07C45/63 , C07C45/68 , C07C249/02 , C07C251/24 , C07C2601/14 , C07F15/065 , C07C47/565
摘要： Provided are a complex prepared from ammonium salt-containing ligands and having such an equilibrium structural formula that the metal center takes a negative charge of 2 or higher, and a method for preparing polycarbonate via copolymerization of an epoxide compound and carbon dioxide using the complex as a catalyst. When the complex is used as a catalyst for copolymerizing an epoxide compound and carbon dioxide, it shows high activity and high selectivity and provides high-molecular weight polycarbonate, and thus easily applicable to commercial processes. In addition, after forming polycarbonate via carbon dioxide/epoxide copolymerization using the complex as a catalyst, the catalyst may be separately recovered from the copolymer.
摘要翻译：提供了由含铵盐的配位体制备的复合物，并具有金属中心取2或更高的负电荷的平衡结构式，以及使用该络合物通过环氧化合物和二氧化碳的共聚制备聚碳酸酯的方法催化剂当络合物用作共聚环氧化合物和二氧化碳的催化剂时，其显示高活性和高选择性，并提供高分子量聚碳酸酯，因此易于适用于商业方法。此外，通过使用络合物作为催化剂通过二氧化碳/环氧化物共聚形成聚碳酸酯之后，可以从共聚物中单独回收催化剂。

10. 发明授权

US09259722B2 Process for producing cumene 有权
标题翻译：异丙苯生产工艺
公开(公告)号：US09259722B2
公开(公告)日：2016-02-16
申请号：US14415960
申请日：2013-07-23
申请人： BADGER LICENSING LLC
发明人： Ronald Birkhoff , Shyh-Yuan H. Hwang
IPC分类号： C07C407/00 , B01J29/90 , C07C2/86 , B01J29/08 , B01J29/40 , B01J29/70 , B01J38/04 , B01J38/10 , C07C29/145 , C07C37/08 , C07C45/00
CPC分类号： B01J29/90 , B01J29/084 , B01J29/40 , B01J29/70 , B01J29/703 , B01J29/7034 , B01J29/7038 , B01J29/7042 , B01J29/7046 , B01J38/04 , B01J38/10 , C07C2/864 , C07C29/145 , C07C37/08 , C07C45/00 , C07C407/00 , C07C2529/70 , Y02P20/52 , C07C15/085
摘要： In a process for producing cumene, benzene and a C3 alkylating agent comprising isopropanol are supplied to an alkylation zone comprising a molecular sieve alkylation catalyst under alkylation conditions such that the isopropanol reacts with the benzene to produce a reaction product comprising cumene. Subsequently, the supply of benzene and C3 alkylating agent to the alkylation zone is ceased and a gaseous stripping agent is supplied to the molecular sieve alkylation catalyst under conditions effective to remove nitrogenous impurities deposited on the catalyst during the preceding alkylation reaction. The supply of benzene and C3 alkylating agent to the alkylation zone is then reinitiated.
摘要翻译：在生产异丙基苯的方法中，将苯和含有异丙醇的C3烷基化剂在烷基化条件下供给到包含分子筛烷基化催化剂的烷基化区，使得异丙醇与苯反应产生包含枯烯的反应产物。随后，停止向烷基化区供应苯和C3烷基化剂，并在有效去除在前述烷基化反应期间沉积在催化剂上的含氮杂质的条件下，向分子筛烷基化催化剂提供气态汽提剂。然后重新开始向烷基化区供应苯和C3烷基化剂。

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