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    • 5. 发明申请
    • PROCESS FOR PRODUCING HYDROXYALKYL CELLULOSES
    • 生产羟肟酸纤维素的方法
    • US20150307630A1
    • 2015-10-29
    • US14650391
    • 2013-10-17
    • KAO CORPORATION
    • Hideki GOTOKohei NAKANISHIYoichiro IMORITomoya WADA
    • C08B11/08C08B11/145C08B1/06
    • C08B11/08C08B1/00C08B1/06C08B1/08C08B11/145
    • The present invention relates to (1) a process for producing a hydroxyalkyl cellulose having an excellent water-solubility while maintaining a high reaction selectivity by adding a basic compound and an alkyleneoxide to a cellulose to conduct a reaction therebetween in which the basic compound is added in a total amount of from 0.3 to 1.5 mol per 1 mol of an anhydroglucose unit in the cellulose, and the alkyleneoxide is added in a total amount of from 1.0 to 3.0 mol per 1 mol of an anhydroglucose unit in the cellulose, the process including a step of adding the basic compound in an amount of from 50 to 95% of the total amount of the basic compound to be added during the process, and then adding the alkyleneoxide in an amount of from 30 to 80% of the total amount of the alkyleneoxide to be added during the process to react the compounds with the cellulose, thereby obtaining a reaction mixture; and a step of adding a remaining amount of the basic compound and a remaining amount of the alkyleneoxide to the reaction mixture obtained in the previous step to conduct a reaction therebetween; (2) a hydroxyalkyl cellulose produced by the process; and (3) a process for producing a cationized hydroxyalkyl cellulose using the resulting hydroxyalkyl cellulose.
    • 本发明涉及(1)通过向纤维素中加入碱性化合物和环氧烷以进行其中加入碱性化合物的反应而制备具有优异的水溶性同时维持高反应选择性的羟烷基纤维素的方法 在纤维素中每1mol脱水葡萄糖单元的总量为0.3至1.5mol,并且在纤维素中每1mol脱水葡萄糖单元的总量为1.0-3.0mol的环氧化物,其包括 将碱性化合物的添加量加入到该方法中添加的碱性化合物的总量的50〜95%的步骤,然后加入环氧化物的量为总量的30〜80% 在该方法中加入的环氧化物使化合物与纤维素反应,由此得到反应混合物; 以及将剩余量的碱性化合物和剩余量的环氧烷烃加入到前述步骤中获得的反应混合物中以进行反应的步骤; (2)通过该方法生产的羟烷基纤维素; 和(3)使用得到的羟烷基纤维素生产阳离子化羟烷基纤维素的方法。
    • 7. 发明授权
    • Method for solubilizing cellulose
    • 溶解纤维素的方法
    • US09133277B2
    • 2015-09-15
    • US14112378
    • 2012-04-02
    • Koichi ShiraishiTohru JobojiKento Taneda
    • Koichi ShiraishiTohru JobojiKento Taneda
    • C08B1/00C13K1/02
    • C08B1/00A23V2002/00C13K1/02A23V2250/5108
    • Provided is a method for solubilizing cellulose in which cellulose can be solubilized in a short period of time with a low amount of excess decomposition and without the use of a catalyst or other chemicals. A starting material containing cellulose is pulverized to reduce the crystallization thereof, adjusted for moisture content, reacted with water in the absence of a catalyst, and converted into a water-soluble component. At this point, the reaction is performed at a temperature of 100° C. or more and less than 300° C., and a total pressure of 0.05 MPa or more and less than 10 MPa. Water is added and extracted from the water soluble component, and solid-liquid separation is performed to separate the solids and the aqueous solution.
    • 提供了一种增溶纤维素的方法,其中纤维素可以在短时间内以低量的过量分解溶解并且不使用催化剂或其它化学品。 将含有纤维素的原料粉碎以减少其结晶度,根据含水量调节,在不存在催化剂的情况下与水反应,并转化成水溶性组分。 此时,反应在100℃以上且小于300℃的温度下进行,总压力为0.05MPa以上且小于10MPa。 从水溶性成分中加入水并提取水分,进行固液分离,分离固体和水溶液。