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1. 发明申请

US20180251591A9 BIO-BASED RESINS WITH HIGH CONTENT OF ETHYLENICALLY UNSATURATED FUNCTIONAL GROUPS AND THERMOSETS THEREOF 审中-公开
公开(公告)号：US20180251591A9
公开(公告)日：2018-09-06
申请号：US15034312
申请日：2014-11-07
申请人： NDSU RESEARCH FOUNDATION
发明人： Dean C. WEBSTER , Lindsey BULTEMA , Jingling YAN
IPC分类号： C08G59/17 , C09D147/00
CPC分类号： C08G59/1466 , C08F290/04 , C08F290/064 , C08G59/3236 , C08G65/22 , C08G65/2615 , C09D147/00 , C08F212/08
摘要： The invention provides polyfunctional bio-based methacrylate oligomers, which are synthesized via the ring-opening reaction between at least one ethylenically unsaturated acid selected from methacrylic acid, acrylic acid, and crotonic acid, and a polyfunctional bio-based epoxy resin, such as epoxidized sucrose soyate. The extent of reaction may be varied to generate a family of methacrylate oligomers with differing degrees of methacrylate. These methacrylate oligomers can optionally be mixed with a reactive diluent, such as styrene, and cured using, for example, a thermally-activated free radical initiator to form a thermoset polymer with high modulus. The thermosets can be used to form composites, adhesives, coatings, and dental restorative materials. Methods of making the methacrylate oligomers are disclosed as are coating compositions and coated objects, such as dental restorative materials, using the methacrylate oligomers.

2. 发明授权

US08865786B2 Antireflective coating compositions 有权
标题翻译：防反射涂料组合物
公开(公告)号：US08865786B2
公开(公告)日：2014-10-21
申请号：US12488309
申请日：2009-06-19
申请人： Yongan Yan , Satyabrata Raychaudhuri , Matthew Emilio Coda
发明人： Yongan Yan , Satyabrata Raychaudhuri , Matthew Emilio Coda
IPC分类号： C08K3/36 , C09D7/12 , C09D151/10 , C09D5/00 , G02B1/11 , C08F290/06 , C08F283/10 , C09D133/06
CPC分类号： G02B1/113 , C08F283/10 , C08F290/06 , C08F290/064 , C08K3/36 , C09D5/006 , C09D7/62 , C09D133/06 , C09D151/10 , Y10S977/773 , C08L2666/02
摘要： Coating compositions, and methods for depositing them on the surface of an article to produce an antireflection coating, are disclosed. In one embodiment, the coating composition includes a (meth)acrylate-functional silicon alkoxide, silica particles, a (meth)acrylate monomer, an epoxy (meth)acrylate oligomer, a photoinitiator, a solvent, an acid, and water. The relative amounts of these constituents are controlled such that, when the coating composition is deposited onto the surface of an article and cured, it has a refractive index less than about 1.60 at a wavelength of 510 nm. In another embodiment, the coating composition includes an organo-metallic compound other than an organo-metallic compound of silicon, an epoxy-functional silicon alkoxide, a non-epoxy-functional silicon alkoxide, a curing agent compatible with epoxy-functional molecules, a solvent, an inorganic acid, and water. The relative amounts of these constituents are controlled such that, when the coating composition is deposited onto the surface of an article and cured, it has a refractive index greater than about 1.70 at a wavelength of 510 nm. The coating compositions are deposited in a process that produces an antireflection coating in less than 90 minutes of processing time.
摘要翻译：公开了涂料组合物以及将它们沉积在制品的表面上以产生抗反射涂层的方法。在一个实施方案中，涂料组合物包含（甲基）丙烯酸酯官能的硅醇盐，二氧化硅颗粒，（甲基）丙烯酸酯单体，环氧（甲基）丙烯酸酯低聚物，光引发剂，溶剂，酸和水。控制这些成分的相对量，使得当涂料组合物沉积在制品的表面上并固化时，其在波长510nm处的折射率小于约1.60。在另一个实施方案中，涂料组合物包括除有机金属化合物硅之外的有机金属化合物，环氧官能的硅醇盐，非环氧官能的硅醇盐，与环氧官能的分子相容的固化剂，溶剂，无机酸和水。控制这些成分的相对量，使得当涂料组合物沉积在制品的表面上并固化时，其在波长510nm处具有大于约1.70的折射率。涂料组合物以不到90分钟处理时间产生抗反射涂层的方法沉积。

3. 发明申请

US20130310530A1 USE OF SILICONE METHACRYLATE PARTICLES IN COSMETIC FORMULATIONS 审中-公开
标题翻译：在化妆品配方中使用有机硅甲基丙烯酸酯颗粒
公开(公告)号：US20130310530A1
公开(公告)日：2013-11-21
申请号：US13981366
申请日：2011-12-21
申请人： Brajesh Kumar Jha , Jürgen Meyer , Matthias Naumann , Joachim Venzmer , Susann Wiechers
发明人： Brajesh Kumar Jha , Jürgen Meyer , Matthias Naumann , Joachim Venzmer , Susann Wiechers
IPC分类号： A61K8/81
CPC分类号： A61K8/8152 , A61K8/0208 , A61K8/0241 , A61K8/895 , A61Q1/02 , A61Q1/06 , A61Q1/10 , A61Q1/12 , A61Q15/00 , A61Q17/04 , A61Q19/00 , C08F290/064 , C08F299/08 , C08G77/20 , C08L51/08
摘要： The present invention relates to cosmetic compositions comprising, as solid particles, silicone methacrylate particles which are obtainable by the steps a) producing an emulsion of water and an organic phase, where the organic phase comprises specifically organopolysiloxanes modified in the terminal and/or lateral position with methacrylate groups, or mixtures thereof, with the addition of at least one emulsifier and optionally one or more coemulsifiers, where the organic phase forms the internal phase of the emulsion, and fully polymerizing the internal phase in the presence of a radical initiator, which is added to the external phase (aqueous phase) in a concentration of from 0.1 to 40% by weight based on the internal phase, and also to corresponding cosmetic compositions.
摘要翻译：本发明涉及化妆品组合物，其包含作为固体颗粒的甲基丙烯酸硅氧烷颗粒，其可通过以下步骤获得：a）制备水和有机相的乳液，其中有机相特别包括在末端和/或侧面位置改性的有机聚硅氧烷与甲基丙烯酸酯基团或其混合物，加入至少一种乳化剂和任选的一种或多种共乳化剂，其中有机相形成乳液的内相，并在自由基引发剂存在下使内相完全聚合，其中以相对于内相为0.1〜40重量％的浓度加入到外相（水相）中，并且还添加到相应的化妆品组合物中。

4. 发明授权

US08148047B2 Carboxyl resin, hardening composition containing carboxyl resin, and hardened material thereof 有权
标题翻译：羧基树脂，含羧基树脂的硬化组合物及其硬化物
公开(公告)号：US08148047B2
公开(公告)日：2012-04-03
申请号：US12996852
申请日：2009-02-20
申请人： Koichi Ikegami , Noboru Kohiyama , Teppei Nishikawa , Michiya Higuchi , Nobuhito Hamada , Hiroko Daido , Chieko Inui , Tatsuya Kubo
发明人： Koichi Ikegami , Noboru Kohiyama , Teppei Nishikawa , Michiya Higuchi , Nobuhito Hamada , Hiroko Daido , Chieko Inui , Tatsuya Kubo
IPC分类号： G03F7/028 , G03F7/032 , C08F8/14 , C08F290/06 , C08G59/00
CPC分类号： C08G59/1494 , C08F8/14 , C08F220/14 , C08F283/10 , C08F290/06 , C08F290/064 , C08F290/14 , C08F290/144 , C08F2220/1825 , C08F2220/1858 , C08F2220/325 , C08F2810/20 , C08F2810/30 , C08G59/186 , G03F7/032 , G03F7/038 , G03F7/0388 , H05K3/287 , C08F220/10
摘要： A carboxyl resin according to the present invention is obtained by a process including following steps: epoxy groups on a resin (a) having two or more epoxy groups in one molecule is made to react with 0.3-0.85 mol of a monocarboxylic acid (b) per one epoxy-group equivalent weight to obtain a reaction product (c); the epoxy group or groups on the reaction product (c) are made to react with 0.15-0.95 mol of a polybasic acid (d) per one epoxy-group equivalent weight to obtain a reaction product (e); and the epoxy group or groups on the reaction product (e) are further made to react with 1.0-5.0 mol of a monocarboxylic acid (f) per one epoxy-group equivalent weight. The carboxyl resin thus obtained has an acid value within a range from 20 to 200 mgKOH/g and is soluble in an organic solvent.
摘要翻译：通过包括以下步骤的方法获得本发明的羧基树脂：使一分子中具有两个以上环氧基的树脂（a）上的环氧基与0.3-0.85摩尔一元羧酸（b）反应，每个环氧基当量，得到反应产物（c）; 反应产物（c）上的环氧基或基团与每一个环氧基当量的0.15-0.95摩尔多元酸（d）反应，得到反应产物（e）; 反应产物（e）上的环氧基或基团进一步与每个环氧基当量1.0-5.0摩尔一元羧酸（f）反应。由此得到的羧基树脂的酸值为20〜200mgKOH / g，可溶于有机溶剂。

5. 发明授权

US08048949B1 Composite repair resins containing minimal hazardous air pollutants and volatile organic compound 有权
标题翻译：复合修复树脂含有最小的有害空气污染物和挥发性有机化合物
公开(公告)号：US08048949B1
公开(公告)日：2011-11-01
申请号：US11689191
申请日：2007-03-21
申请人： John Joseph La Scala , James Matthew Sands , Giuseppe Raffaello Palmese
发明人： John Joseph La Scala , James Matthew Sands , Giuseppe Raffaello Palmese
IPC分类号： C08K3/34 , C08K3/26
CPC分类号： C08F220/26 , C08F212/08 , C08F220/06 , C08F220/28 , C08F220/62 , C08F283/006 , C08F283/01 , C08F290/064 , C08G59/1466 , C08G59/22 , C08G59/4207 , C08J5/24 , C08K3/013 , C08L63/00 , C08L63/10 , C08L2205/05 , C08L2666/14 , C08L25/04 , C08L33/08
摘要： The present invention relates to a composition and method for fabricating composite resins that produce either reduced or zero volatile organic compound (VOC) and zero hazardous air pollutant (HAP) emissions. The non-volatile reactive diluents of the composite resin, fatty acid monomers, enhance the stability, shelf-life, flexibility and strength of the composite resin. The resins incorporating fatty acid monomers may be used to repair military equipment or for any commercial repair purposes.
摘要翻译：本发明涉及一种制备复合树脂的组合物和方法，所述复合树脂产生还原或零挥发性有机化合物（VOC）和零危险空气污染物（HAP）排放。复合树脂的非挥发性活性稀释剂，脂肪酸单体增强了复合树脂的稳定性，保存期限，柔韧性和强度。掺入脂肪酸单体的树脂可用于修理军事设备或用于任何商业维修目的。

6. 发明授权

US07897243B2 Structure having specific surface shape and properties and (meth)acrylic polymerizable composition for formation of the structure 有权
标题翻译：具有比表面形状和特性的结构和用于形成结构的（甲基）丙烯酸类聚合性组合物
公开(公告)号：US07897243B2
公开(公告)日：2011-03-01
申请号：US12064478
申请日：2006-09-28
申请人： Tsukasa Matsumoto
发明人： Tsukasa Matsumoto
IPC分类号： B23B3/00 , B05D5/06 , B32B1/00 , B32B37/02 , C08F26/02 , C08F20/06
CPC分类号： G02B1/118 , B29C43/06 , B29C43/222 , B29C43/28 , B29C2043/463 , B29K2105/0002 , B29K2105/256 , B29L2011/0016 , B29L2031/3475 , C08F283/12 , C08F290/00 , C08F290/06 , C08F290/061 , C08F290/064 , C08F290/065 , C08F299/00 , C08G18/3206 , C08G18/4238 , C08G18/672 , C08G18/755 , C08G65/3322 , C08L75/16 , G02B1/105 , G02B1/111 , G02B1/113 , Y10T156/1028 , Y10T428/24479 , Y10T428/24612 , C08G18/42
摘要： A surface shape and physical properties required for a structure having an antireflection performance of light and an improved performance of light permeability have been found, particularly the structure having surface scratch resistance is provided, a composition capable of forming the structure having such a particular structure and physical properties is provided, and further a composition which can easily form the structure which is excellent in antireflection performance of light and an improved performance of light permeability and has a large aspect ratio is provided. That is, the present invention is the structure having convex parts with an average height of 100 nm or more and 1000 nm or less or concave parts with an average depth of 100 nm or more and 1000 nm or less on its surface wherein the convex parts or the concave parts are present at an average cycle of 100 nm or more and 400 nm or less in at least one direction, characterized in that the structure is obtained by polymerizing a (meth)acrylic polymerizable composition by light irradiation, electron beam irradiation and/or heating and a storage elastic modulus at 180° C. or above is 0.5 GPa or more.
摘要翻译：已经发现具有光的抗反射性能和改善的透光性能的结构所需的表面形状和物理特性，特别是提供了具有表面耐刮擦性的结构，能够形成具有这种特定结构的结构的组合物和提供了物理性质，并且还提供了一种可以容易地形成具有优异的光的抗反射性能和改善的透光性能并且具有大的纵横比的结构的组合物。也就是说，本发明是具有平均高度为100nm以上且1000nm以下的凸部的平面深度为100nm以上且1000nm以下的凹部的结构，其中凸部或凹部在至少一个方向上以100nm以上且400nm以下的平均周期存在，其特征在于，所述结构体是通过光照射，电子束照射和（甲基）丙烯酸系聚合性组合物聚合而得到的或者在180℃以上的加热和储能弹性模量为0.5GPa以上。

7. 发明申请

US20100274043A1 ADAMANTYL GROUP-CONTAINING EPOXY-MODIFIED (METH)ACRYLATE AND RESIN COMPOSITION CONTAINING THE SAME 有权
标题翻译：含有铵基团的环氧改性（甲基）丙烯酸酯和含有它的树脂组合物
公开(公告)号：US20100274043A1
公开(公告)日：2010-10-28
申请号：US12831763
申请日：2010-07-07
申请人： Yasunari OKADA , Hajime ITO , Hideki YAMANE , Nobuaki MATSUMOTO
发明人： Yasunari OKADA , Hajime ITO , Hideki YAMANE , Nobuaki MATSUMOTO
IPC分类号： C07C69/732
CPC分类号： C08F290/06 , C08F222/1006 , C08F290/061 , C08F290/064 , C08G59/186
摘要： The present invention provides an adamantyl group containing epoxy-modified (meth)acrylate and a resin composition containing it which are imparted by transparency, optical characteristics such as (durable) light resistance and the like, heat-resistance, and good mechanical properties.For example, they are an adamantyl group containing epoxy-modified (meth)acrylate having the following general formula (I) and a composition containing it. In the formula, R1 represents a hydrogen atom or a methyl group, and R2 represents a halogen atom or an aliphatic hydrocarbon group which may contain a hetero atom. Plural R2 may be the same or different, and m represents an integer of 0 to 4 and n represents an integer of 0 or more. A:
摘要翻译：本发明提供含有环氧改性（甲基）丙烯酸金刚烷基和含有它的树脂组合物，它们由透明性，耐光性等光学特性赋予耐热性和良好的机械性能。例如，它们是含有具有以下通式（I）的环氧改性（甲基）丙烯酸酯和含有它的组合物的金刚烷基。在该式中，R 1表示氢原子或甲基，R 2表示卤素原子或可含有杂原子的脂肪族烃基。多个R2可以相同或不同，m表示0〜4的整数，n表示0以上的整数。 A：

8. 发明申请

US20090030151A1 Gel Time Drift-Free Resin Compositions 审中-公开
标题翻译：凝胶时间漂移树脂组合物
公开(公告)号：US20090030151A1
公开(公告)日：2009-01-29
申请号：US11886740
申请日：2006-03-23
申请人： Johan Franz Jansen , Engelina Catharina Kleuskens , Ivo Ronald Kraeger
发明人： Johan Franz Jansen , Engelina Catharina Kleuskens , Ivo Ronald Kraeger
IPC分类号： C08L67/06
CPC分类号： C08F290/144 , C08F283/01 , C08F290/06 , C08F290/061 , C08F290/064 , C08F290/14 , C08F290/141 , C08K5/07 , C08K5/14 , C08L67/06
摘要： The present invention relates to unsaturated polyester resin or vinyl ester resin compositions that are essentially free of cobalt; that are curable with a peroxide component; and that, comprise a polymer containing reactive unsaturations, optionally a reactive diluent, and a dioxo component; which dioxo component consists of one or more dioxo-compounds having a calculated reduction energy (CRE), being the energy difference in kcal/mole between the lowest energy conformations of the radical anion and the corresponding neutral molecule as calculated by means of the Turbomole Version 5 program, in the range of from −5 to −30 kcal/mole. These resin compositions show a reduced gel-time drift tendency.The present invention further also relates to objects and structural parts prepared from such unsaturated polyester or vinyl ester resin compositions by curing with a peroxide. The present invention finally also relates to methods of peroxide curing of unsaturated polyester resin or vinyl ester resin compositions.
摘要翻译：本发明涉及基本上不含钴的不饱和聚酯树脂或乙烯基酯树脂组合物; 可用过氧化物组分固化; 并且包括含有反应性不饱和的聚合物，任选的反应性稀释剂和二氧代组分; 该二氧代组分由一种或多种具有计算的还原能量（CRE）的二氧代化合物组成，其为通过Turbomol版本计算的自由基阴离子和相应中性分子的最低能量构象之间的kcal /摩尔的能量差 5程序，范围为-5至-30 kcal / mole。这些树脂组合物显示出降低的凝胶时间漂移趋势。本发明还涉及通过用过氧化物固化由这种不饱和聚酯或乙烯基酯树脂组合物制备的物体和结构部件。本发明最终还涉及不饱和聚酯树脂或乙烯基酯树脂组合物的过氧化物固化方法。

9. 发明申请

US20080003373A1 Antireflective coating compositions and methods for depositing such coatings 审中-公开
标题翻译：防反射涂料组合物和沉积这种涂料的方法
公开(公告)号：US20080003373A1
公开(公告)日：2008-01-03
申请号：US11432685
申请日：2006-05-10
申请人： Yongan Yan , Satyabrata Raychaudhuri , Matthew Coda
发明人： Yongan Yan , Satyabrata Raychaudhuri , Matthew Coda
IPC分类号： B05D3/00 , C04B41/50 , C09D183/04
CPC分类号： G02B1/113 , C08F283/10 , C08F290/06 , C08F290/064 , C08K3/36 , C09D5/006 , C09D7/62 , C09D133/06 , C09D151/10 , Y10S977/773 , C08L2666/02
摘要： Coating compositions, and methods for depositing them on the surface of an article to produce an antireflection coating, are disclosed. In one embodiment, the coating composition includes a (meth)acrylate-functional silicon alkoxide, silica particles, a (meth)acrylate monomer, an epoxy(meth)acrylate oligomer, a photoinitiator, a solvent, an acid, and water. The relative amounts of these constituents are controlled such that, when the coating composition is deposited onto the surface of an article and cured, it has a refractive index less than about 1.60 at a wavelength of 510 nm. In another embodiment, the coating composition includes an organo-metallic compound other than an organo-metallic compound of silicon, an epoxy-functional silicon alkoxide, a non-epoxy-functional silicon alkoxide, a curing agent compatible with epoxy-functional molecules, a solvent, an inorganic acid, and water. The relative amounts of these constituents are controlled such that, when the coating composition is deposited onto the surface of an article and cured, it has a refractive index greater than about 1.70 at a wavelength of 510 nm. The coating compositions are deposited in a process that produces an antireflection coating in less than 90 minutes of processing time.
摘要翻译：公开了涂料组合物以及将它们沉积在制品的表面上以产生抗反射涂层的方法。在一个实施方案中，涂料组合物包含（甲基）丙烯酸酯官能的硅醇盐，二氧化硅颗粒，（甲基）丙烯酸酯单体，环氧（甲基）丙烯酸酯低聚物，光引发剂，溶剂，酸和水。控制这些成分的相对量，使得当涂料组合物沉积在制品的表面上并固化时，其在波长510nm处的折射率小于约1.60。在另一个实施方案中，涂料组合物包括除有机金属化合物硅之外的有机金属化合物，环氧官能的硅醇盐，非环氧官能的硅醇盐，与环氧官能的分子相容的固化剂，溶剂，无机酸和水。控制这些成分的相对量，使得当涂料组合物沉积在制品的表面上并固化时，其在波长510nm处具有大于约1.70的折射率。涂料组合物以不到90分钟处理时间产生抗反射涂层的方法沉积。

10. 发明授权

US07157507B2 Ultraviolet curable silver composition and related method 失效
标题翻译：紫外线固化银成分及相关方法
公开(公告)号：US07157507B2
公开(公告)日：2007-01-02
申请号：US10721577
申请日：2003-11-24
申请人： Roy C. Krohn
发明人： Roy C. Krohn
IPC分类号： C08L63/00 , C08L75/04 , C08K3/08
CPC分类号： G03F7/0047 , C08F2/44 , C08F2/48 , C08F283/006 , C08F283/10 , C08F290/06 , C08F290/064 , C08F290/067 , C08K3/08 , C08K5/10 , C09D4/00 , C09D4/06 , C09D175/16 , C23C24/08 , G03F7/027 , H05K1/095 , H05K2201/0245 , C08F220/18 , C08F290/14
摘要： A photocurable silver composition is provided which comprises an ultraviolet light curable organic mixture, a photoinitiator, a silver powder, and a silver flake composition. The silver flake composition comprises at least 20% of the weight of the silver powder. The disclosed compositions may be used to produce silver-containing coatings on a variety of different substrates. Related methods are provided.
摘要翻译：提供了一种可光固化的银组合物，其包含紫外光固化有机混合物，光引发剂，银粉和银薄片组合物。银薄片组合物包含至少20％的银粉重量。所公开的组合物可用于在各种不同的基底上产生含银涂层。提供相关方法。

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