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1. 发明授权

US09994657B2 Polymerization process using bis phenolate compounds supported on organoaluminum treated layered silicate supports 有权
公开(公告)号：US09994657B2
公开(公告)日：2018-06-12
申请号：US15242337
申请日：2016-08-19
申请人： ExxonMobil Chemical Patents Inc.
发明人： Crisita Carmen H. Atienza , Matthew W. Holtcamp , Xuan Ye , Gregory S. Day , David A. Cano , Michelle E. Titone , Machteld M. W. Mertens , Gerardo J. Majano Sanchez
IPC分类号： C08F4/76 , C08F4/64 , C08F210/16 , C08F4/60
CPC分类号： C08F210/16 , C08F4/60189 , C08F4/64 , C08F4/64189 , C08F4/65912 , C08F4/65916 , C08F110/02 , C08F210/14 , C08F2500/03 , C08F4/025 , C08F4/659
摘要： This invention relates to a process to polymerize olefins comprising: i) contacting one or more olefins with a catalyst system comprising: 1) a support comprising an organoaluminum treated layered silicate and an inorganic oxide; and 2) a bisphenolate compound; and ii) obtaining olefin polymer having high molecular weight and layered silicate dispersed therein. Preferably the support is in the form of spheroidal particles.

2. 发明授权

US09988469B2 Method for preparing polyolefin and polyolefin prepared thereby 有权
公开(公告)号：US09988469B2
公开(公告)日：2018-06-05
申请号：US15303437
申请日：2015-06-03
申请人： LG CHEM, LTD.
发明人： Eun Kyoung Song , Heon Yong Kwon , Hyuck Ju Kwon , Yong Ho Lee , Yi Young Choi , Dae Sik Hong , Ki Soo Lee , Kyung Jin Cho
IPC分类号： C08F4/6592 , C08F210/16 , C08F10/02 , C08F110/02 , C08F4/659 , C08F4/64 , C08F10/00
CPC分类号： C08F110/02 , C08F4/64 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F210/16 , C08F2420/06 , C08F2500/04 , C08F2500/03 , C08F2500/01
摘要： The present invention relates to a method for preparing polyolefin that can easily and effectively prepare polyolefin having high molecular weight and various molecular weight distributions, which was difficult to prepare using the existing metallocene catalyst, and polyolefin prepared thereby. The method for preparing polyolefin comprises the step of polymerizing olefin monomers, in the presence of a metallocene supported catalyst wherein a metallocene compound having a specific chemical structure is supported in a carrier, and hydrogen gas.

3. 发明授权

US09982076B2 Supported bis phenolate transition metals complexes, production and use thereof 有权
公开(公告)号：US09982076B2
公开(公告)日：2018-05-29
申请号：US15242357
申请日：2016-08-19
申请人： ExxonMobil Chemical Patents Inc.
发明人： Xuan Ye , Crisita Carmen H. Atienza , Matthew W. Holtcamp , David F. Sanders , Gregory S. Day , Michelle E. Titone , David A. Cano , Matthew S. Bedoya
IPC分类号： C08F4/76 , C08F4/64 , C08F210/16 , C08F4/60
CPC分类号： C08F210/16 , C08F4/60189 , C08F4/64 , C08F4/64189 , C08F4/65912 , C08F210/14 , C08F2500/03 , C08F4/65916 , C08F4/64186
摘要： A catalyst system including the reaction product of a fluorided support, an activator, and at least a first transition metal catalyst compound; methods of making such catalyst systems, polymerization processes using such catalyst systems, and polymers made therefrom.

4. 发明申请

US20170088641A1 Polymerization Process Using Pyridyldiamido Compounds Supported on Organoaluminum Treated Layered Silicate Supports 有权
公开(公告)号：US20170088641A1
公开(公告)日：2017-03-30
申请号：US15239036
申请日：2016-08-17
申请人： ExxonMobil Chemical Patents Inc.
发明人： Matthew W. Holtcamp , John R. Hagadorn , Gregory S. Day , Machteld M. W. Mertens , Gerardo J. Majano Sanchez , Rohan A. Hule
IPC分类号： C08F10/02
CPC分类号： C08F10/02 , C08F4/64 , C08F4/64148 , C08L23/06 , C08F110/02 , C08F2500/01 , C08F2500/03 , C08F2500/18 , C08F210/16 , C08F2500/14 , C08F4/64113 , C08F4/025
摘要： This invention relates to a process to polymerize olefins comprising: i) contacting one or more olefins with a catalyst system comprising: 1) a support comprising an organoaluminum treated layered silicate and an inorganic oxide; and 2) a pyridyldiamido compound; and ii) obtaining olefin polymer having high molecular weight and layered silicate dispersed therein. Preferably the support is in the form of spheroidal particles.

5. 发明授权

US09562118B2 Transition metal complexes supported on metal-organic frameworks for heterogeneous catalysts 有权
标题翻译：负载在金属 - 有机骨架上用于非均相催化剂的过渡金属络合物
公开(公告)号：US09562118B2
公开(公告)日：2017-02-07
申请号：US14824955
申请日：2015-08-12
申请人： Northwestern University
发明人： Omar K. Farha , Joseph T. Hupp , Massimiliano Delferro , Rachel C. Klet
IPC分类号： C07F7/00 , C08F10/14
CPC分类号： C08F10/14 , C07F7/00 , C07F7/003 , C08F4/64
摘要： A robust mesoporous metal-organic framework comprising a hafnium-based metal-organic framework and a single-site zirconium-benzyl species is provided. The hafnium, zirconium-benzyl metal-organic framework is useful as a catalyst for the polymerization of an alkene.
摘要翻译：提供了包含铪基金属 - 有机骨架和单位点锆 - 苄基物质的坚固的介孔金属 - 有机骨架。铪锆 - 苄基金属 - 有机骨架可用作烯烃聚合的催化剂。

6. 发明申请

US20170022305A1 HIGH PERFORMANCE ZIEGLER-NATTA CATALYST SYSTEMS, PROCESS FOR PRODUCING SUCH SUPPORTED CATALYSTS AND USE THEREOF 审中-公开
标题翻译：高性能ZIEGLER-NATTA催化剂体系，生产这种支持催化剂的方法及其用途
公开(公告)号：US20170022305A1
公开(公告)日：2017-01-26
申请号：US15286991
申请日：2016-10-06
申请人： Lummus Novolen Technology GmbH
发明人： Yvonne Denkwitz , Oliver Schuster , Andreas Winter
IPC分类号： C08F110/06
CPC分类号： C08F110/06 , C08F4/64 , C08F10/00 , C08F4/651 , C08F4/6546
摘要： A method for making a solid catalyst component for use in a Ziegler-Natta catalyst includes combining in a hydrocarbon solvent a porous particulate support with a hydrocarbon soluble organomagnesium compound to form a suspension. The organomagnesium compound is halogenated followed by addition of an alcohol and the mixture is then reacted with a titanium compound followed by a reaction with at least one diether compound to form the solid catalyst component. Afterwards the reaction product is extracted with a mixture of a titanium compound and a hydrocarbon solvent. The solid catalyst component recovered is combined with an aluminum cocatalyst to form a Ziegler-Natta catalyst system for the polymerization of olefins. In particular, the catalyst system including a diether internal electron donor may have an activity and hydrogen response suitable for the production of propylene polymers having a molecular weight distribution (PI(GPC)) in the range from about 5.75 to about 9.
摘要翻译：制备用于齐格勒 - 纳塔催化剂的固体催化剂组分的方法包括在烃溶剂中将多孔颗粒载体与可溶于烃的有机镁化合物混合以形成悬浮液。将有机镁化合物卤化，然后加入醇，然后将混合物与钛化合物反应，然后与至少一种二醚化合物反应形成固体催化剂组分。之后，用钛化合物和烃溶剂的混合物萃取反应产物。将回收的固体催化剂组分与铝助催化剂组合以形成用于烯烃聚合的齐格勒 - 纳塔催化剂体系。特别地，包括二醚内电子给体的催化剂体系可具有适用于生产分子量分布（PI（GPC））在约5.75至约9范围内的丙烯聚合物的活性和氢气响应。

7. 发明申请

US20160369020A1 OLEFIN-BASED POLYMER WITH EXCELLENT PROCESSABILITY 有权
标题翻译：基于烯烃的聚合物具有优异的可加工性
公开(公告)号：US20160369020A1
公开(公告)日：2016-12-22
申请号：US15032014
申请日：2014-09-11
申请人： LG CHEM, LTD.
发明人： Yu Taek SUNG , Heon Yong KWON , Ki Soo LEE , Dae Sik HONG , Dong Hoon JEONG , Eun Young SHIN
IPC分类号： C08F210/16 , C08J5/18
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65927 , C08F10/00 , C08F2420/02 , C08J5/18 , C08J2323/08 , C08F2500/01 , C08F2500/04 , C08F210/14 , C08F2500/12 , C08F4/65904 , C08F4/64
摘要： Provided is an olefin-based polymer with excellent processability. The olefin-based polymer according to the present invention has a high molecular weight and a broad molecular weight distribution to show excellent processability and improved transparency, thereby being used in desired applications.
摘要翻译：提供了具有优异加工性能的烯烃类聚合物。根据本发明的烯烃基聚合物具有高分子量和宽分子量分布，以显示优异的加工性能和改善的透明度，从而用于所需的应用。

8. 发明申请

US20140309387A1 TRANSITION METAL CATALYST COMPOSITION INCLUDING A TRANSITION METAL COMPOUND AND A METHOD OF PREPARING A POLYOLEFIN USING THE CATALYST COMPOSITION 有权
标题翻译：包含过渡金属化合物的过渡金属催化剂组合物和使用催化剂组合物制备聚烯烃的方法
公开(公告)号：US20140309387A1
公开(公告)日：2014-10-16
申请号：US14112849
申请日：2012-08-24
申请人： Won-Hee Kim , Kyung-Seop Noh , Nan-Young Lee , Sang-Jin Jeon
发明人： Won-Hee Kim , Kyung-Seop Noh , Nan-Young Lee , Sang-Jin Jeon
IPC分类号： C08F4/76
CPC分类号： C08F4/76 , B01J21/06 , C08F4/64 , C08F4/659 , C08F10/00 , C08F4/64141 , C08F4/65908 , C08F210/16 , C08F210/14 , C08F2500/03
摘要： The present invention relates to a transition metal catalyst composition which can exhibit high reactivity in a polymerization reaction of a polyolefin and can easily control characteristics such as chemical structure, molecular weight distribution, mechanical properties, and the like of a synthesized polyolefin, and a method of preparing a polyolefin using the catalyst composition.
摘要翻译：本发明涉及能够在聚烯烃的聚合反应中表现出高反应性的过渡金属催化剂组合物，并且可以容易地控制合成聚烯烃的化学结构，分子量分布，机械性能等特性，以及方法使用该催化剂组合物制备聚烯烃。

9. 发明申请

US20140148565A1 HIGH PERFORMANCE ZIEGLER-NATTA CATALYST SYSTEMS, PROCESS FOR PRODUCING SUCH SUPPORTED CATALYSTS AND USE THEREOF 有权
标题翻译：高性能ZIEGLER-NATTA催化剂体系，生产这种支持催化剂的方法及其用途
公开(公告)号：US20140148565A1
公开(公告)日：2014-05-29
申请号：US14082561
申请日：2013-11-18
申请人： Lummus Novolen Technology GmbH
发明人： Yvonne Denkwitz , Oliver Schuster , Andreas Winter
IPC分类号： C08F4/64
CPC分类号： C08F110/06 , C08F4/64 , C08F10/00 , C08F4/651 , C08F4/6546
摘要： A method for making a solid catalyst component for use in a Ziegler-Natta catalyst includes combining in a hydrocarbon solvent a porous particulate support with a hydrocarbon soluble organomagnesium compound to form a suspension. The organomagnesium compound is halogenated followed by addition of an alcohol and the mixture is then reacted with a titanium compound followed by a reaction with at least one diether compound to form the solid catalyst component. Afterwards the reaction product is extracted with a mixture of a titanium compound and a hydrocarbon solvent. The solid catalyst component recovered is combined with an aluminum cocatalyst to form a Ziegler-Natta catalyst system for the polymerization of olefins. In particular, the catalyst system including a diether internal electron donor may have an activity and hydrogen response suitable for the production of propylene polymers having a molecular weight distribution (PI(GPC)) in the range from about 5.75 to about 9.
摘要翻译：制备用于齐格勒 - 纳塔催化剂的固体催化剂组分的方法包括在烃溶剂中将多孔颗粒载体与可溶于烃的有机镁化合物混合以形成悬浮液。将有机镁化合物卤化，然后加入醇，然后将混合物与钛化合物反应，然后与至少一种二醚化合物反应形成固体催化剂组分。之后，用钛化合物和烃溶剂的混合物萃取反应产物。将回收的固体催化剂组分与铝助催化剂组合以形成用于烯烃聚合的齐格勒 - 纳塔催化剂体系。特别地，包括二醚内电子给体的催化剂体系可具有适用于生产分子量分布（PI（GPC））在约5.75至约9范围内的丙烯聚合物的活性和氢气响应。

10. 发明申请

US20070111883A1 Catalysts for olefin polymerization 有权
标题翻译：用于烯烃聚合的催化剂
公开(公告)号：US20070111883A1
公开(公告)日：2007-05-17
申请号：US11280426
申请日：2005-11-16
申请人： Kumudini Jayaratne , Michael Jensen , Matthew Thorn , Max McDaniel , Qing Yang
发明人： Kumudini Jayaratne , Michael Jensen , Matthew Thorn , Max McDaniel , Qing Yang
IPC分类号： B01J37/00 , C08F4/44 , C08F2/00
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F210/16 , C08F4/659 , C08F4/025 , C08F4/64 , C08F210/14 , C08F2500/12 , C08F2500/03 , C08F4/64041 , C08F4/64079 , C08F4/64062
摘要： This invention relates to the field of olefin polymerization catalyst compositions, and methods for the polymerization and copolymerization of olefins, including polymerization methods using a catalyst composition. One aspect of this invention is the formation and use of a catalyst composition comprising a transition metal compound and an activator for olefin polymerization processes.
摘要翻译：本发明涉及烯烃聚合催化剂组合物领域，以及烯烃聚合和共聚方法，包括使用催化剂组合物的聚合方法。本发明的一个方面是形成和使用包含过渡金属化合物和用于烯烃聚合方法的活化剂的催化剂组合物。

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