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1. 发明申请

US20150376326A1 POLYURETHANES MADE USING ZINC CATALYSTS 有权
标题翻译：使用ZINC催化剂制备聚氨酯
公开(公告)号：US20150376326A1
公开(公告)日：2015-12-31
申请号：US14849546
申请日：2015-09-09
申请人： Richard Keaton , Peter Margl , Duane Romer , Nathan Wilmot , Rajat Duggal , Rashmi Chamsarkar
发明人： Richard Keaton , Peter Margl , Duane Romer , Nathan Wilmot , Rajat Duggal , Rashmi Chamsarkar
IPC分类号： C08G18/76 , C08G18/48 , C08G18/32 , C08G18/22
CPC分类号： C08G18/7671 , B01J31/2243 , B01J2231/14 , B01J2531/26 , C08G18/0885 , C08G18/18 , C08G18/222 , C08G18/3206 , C08G18/4841 , C08G18/4883 , C08G18/6674 , Y02P20/52
摘要： Polyisocyanate-based polymers are formed by curing a reaction mixture containing at least one polyisocyanate and at least one isocyanate-reactive compound having at least two isocyanate-reactive groups in the presence of a zinc catalyst that contains at least one zinc atom associated with a polydentate ligand that contains at least one nitrogen-containing complexing site.
摘要翻译：多异氰酸酯基聚合物通过在含有至少一个与多齿相关的锌原子的锌催化剂存在下固化含有至少一种多异氰酸酯和至少一种具有至少两个异氰酸酯反应性基团的异氰酸酯反应性化合物的反应混合物而形成配体，其含有至少一个含氮络合位点。

2. 发明授权

US09156935B2 Polyurethanes made using zinc catalysts 有权
标题翻译：使用锌催化剂制成的聚氨酯
公开(公告)号：US09156935B2
公开(公告)日：2015-10-13
申请号：US13806755
申请日：2011-07-05
申请人： Richard J. Keaton , Peter M. Margl , Duane R. Romer , Nathan Wilmot , Rajat Duggal , Rashmi Chamsarkar
发明人： Richard J. Keaton , Peter M. Margl , Duane R. Romer , Nathan Wilmot , Rajat Duggal , Rashmi Chamsarkar
IPC分类号： C08G18/08 , C08G18/18 , B01J31/22 , C08G18/22 , C08G18/48 , C08G18/66
CPC分类号： C08G18/7671 , B01J31/2243 , B01J2231/14 , B01J2531/26 , C08G18/0885 , C08G18/18 , C08G18/222 , C08G18/3206 , C08G18/4841 , C08G18/4883 , C08G18/6674 , Y02P20/52
摘要： Polyisocyanate-based polymers are formed by curing a reaction mixture containing at least one polyisocyanate and at least one isocyanate-reactive compound having at least two isocyanate-reactive groups in the presence of a zinc catalyst that contains at least one zinc atom associated with a polydentate ligand that contains at least one nitrogen-containing complexing site.
摘要翻译：多异氰酸酯基聚合物通过在含有至少一个与多齿相关的锌原子的锌催化剂存在下固化含有至少一种多异氰酸酯和至少一种具有至少两个异氰酸酯反应性基团的异氰酸酯反应性化合物的反应混合物而形成配体，其含有至少一个含氮络合位点。

3. 发明授权

US08846809B2 Urethane adhesive composition 有权
标题翻译：聚氨酯粘合剂组成
公开(公告)号：US08846809B2
公开(公告)日：2014-09-30
申请号：US12681109
申请日：2008-09-10
申请人： Yoshinori Igarashi , Koichiro Higasa
发明人： Yoshinori Igarashi , Koichiro Higasa
IPC分类号： C08G18/08 , C08L75/00 , C08K5/34 , C08K5/3477 , C07C261/00 , C07C269/00 , C07C249/00 , C07C251/00 , C07C257/00 , C07C265/00 , C09K3/00 , C08G18/00 , C08G18/10 , C08G18/16 , C08G18/70 , C09J175/04 , C08G18/48 , C09J175/08 , C08G18/76 , C08G18/79 , C08K3/00 , C08K3/26
CPC分类号： C08G18/0885 , C08G18/10 , C08G18/4808 , C08G18/4833 , C08G18/7664 , C08G18/797 , C08K3/013 , C08K3/26 , C09J175/04 , C09J175/08 , C08G18/48 , C08G18/6674
摘要： A urethane adhesive composition includes a first liquid and a second liquid, the first liquid containing a prepolymer obtained by reacting a polyisocyanate and a high-molecular-weight polyol (I), and at least one filler selected from talc and calcium carbonate, and containing 20 parts by mass or more of talc, 0 to 40 parts by mass of calcium carbonate, and 10 parts by mass or more of zeolite based on 100 parts by mass of the polyisocyanate, the high-molecular-weight polyol (I), and the prepolymer in total, the second liquid containing a high-molecular-weight polyol (II) and a low-molecular-weight polyol, the ratio of the number of moles of hydroxyl groups derived from the low-molecular-weight polyol to the total number of moles of hydroxyl groups derived from the high-molecular-weight polyol (I) and the high-molecular-weight polyol (II) being four or more.
摘要翻译：聚氨酯粘合剂组合物包括第一液体和第二液体，所述第一液体含有通过使多异氰酸酯和高分子量多元醇（I）反应获得的预聚物和至少一种选自滑石和碳酸钙的填料，并且含有 20质量份以上的滑石，0〜40质量份的碳酸钙，10质量份以上的沸石，相对于100质量份的多异氰酸酯，高分子量多元醇（I）和总共预聚物，含有高分子量多元醇（II）和低分子量多元醇的第二液体，由低分子量多元醇衍生的羟基的摩尔数与总共衍生自高分子量多元醇（I）和高分子量多元醇（II）的羟基的摩尔数为4以上。

4. 发明授权

US08455101B2 Polyurethane lamination resin, laminate containing the polyurethane lamination resin, and skis or snowboards containing the laminate 有权
标题翻译：聚氨酯层压树脂，含有聚氨酯层压树脂的层压材料，以及含有层压板的滑雪板或滑雪板
公开(公告)号：US08455101B2
公开(公告)日：2013-06-04
申请号：US12738557
申请日：2008-10-22
申请人： Hans-Juergen Reese , Bert Neuhaus , Silvio Holl , Guenter Taenny
发明人： Hans-Juergen Reese , Bert Neuhaus , Silvio Holl , Guenter Taenny
IPC分类号： B32B27/40 , C08G18/72 , C08G18/10
CPC分类号： C08G18/10 , B32B27/40 , C08G18/0885 , C08G18/2063 , C08J5/043 , C08J5/24 , C08J2375/08 , Y10T428/31551 , C08G18/6677 , C08G18/7664
摘要： The present invention relates to a process for producing a polyurethane lamination resin, by mixing a) an isocyanate prepolymer based on diphenylmethane diisocyanate having a difunctionally started polyether, b) polyphenylene polymethylene polyisocyanate, c) trifunctionally started polyetherpolyol with an average molar mass of from 350 to 600 g/mol, d) a thermoactivatable capped catalyst, e) if appropriate, chain extender and/or crosslinking agent, f) if appropriate, water-absorbent substances, and g) if appropriate, other additives to give the polyurethane lamination resin. The present invention further relates to a polyurethane lamination resin, obtainable via a process of this type, and to the use of this type of polyurethane lamination resin for producing laminates, and also to skis or snowboards, comprising this type of laminate.
摘要翻译：本发明涉及一种制备聚氨酯层压树脂的方法，该方法是通过混合a）具有二官能起始聚醚的二苯基甲烷二异氰酸酯的异氰酸酯预聚物，b）聚亚苯基多亚甲基多异氰酸酯，c）三官能起始的平均摩尔质量为350的聚醚多元醇至600g / mol，d）可热活化的封端催化剂，e）如果合适，扩链剂和/或交联剂，f）如果合适，吸水物质，和g）如果合适的话，其它添加剂得到聚氨酯层压树脂。本发明还涉及通过这种方法获得的聚氨酯层压树脂，以及这种类型的聚氨酯层压树脂用于生产层压材料的用途，以及包括这种类型的层压体的滑雪板或滑雪板。

5. 发明授权

US08062709B2 Hot processing of polyurethane carpet backing systems using dual delayed action catalysts 有权
标题翻译：使用双延迟作用催化剂的聚氨酯地毯背衬系统的热加工
公开(公告)号：US08062709B2
公开(公告)日：2011-11-22
申请号：US12295836
申请日：2007-03-19
申请人： Randall C. Jenkines
发明人： Randall C. Jenkines
IPC分类号： B05D3/02 , C07F7/12 , C07F7/22 , C08G18/00 , C08G18/08 , C08G18/16 , C08G18/22 , C08G18/24 , C08G18/28 , C08J3/00 , C08K5/00 , C08K5/04 , C08K5/09 , C08K5/57 , C08L75/00 , D06M15/693 , H01B1/12
CPC分类号： C08G18/4841 , C08G18/0885 , C08G18/10 , C08G18/222 , C08G18/242 , C08G18/4812 , C08G2150/60 , D06N7/0071 , D06N7/0086 , D06N2203/068 , D06N2205/045 , C08G18/6674
摘要： A process for preparing polyurethane carpet backings uses a filled polyurethane-forming composition that contains a mixture of certain metal acetylacetonate and sulfur-containing organotin catalysts. The mixture of catalysts is particularly beneficial in instances where the composition is processed at temperatures of above 30 to about 500 C, as long pot life is provided together with a rapid thermally-induced cure.
摘要翻译：制备聚氨酯地毯背衬的方法使用含有某种金属乙酰丙酮化物和含硫有机锡催化剂的混合物的填充的形成聚氨酯的组合物。催化剂的混合物在组合物在高于30至约500℃的温度下加工的情况下是特别有益的，因为随着快速热诱导的固化而提供适用期。

6. 发明申请

US20110108183A1 ADHESIVE COMPOSITION ADAPTED FOR BONDING LARGE MASS PARTS TO STRUCTURES 有权
标题翻译：适用于粘结大型零件到结构的胶粘组合物
公开(公告)号：US20110108183A1
公开(公告)日：2011-05-12
申请号：US13002666
申请日：2009-07-14
申请人： Dietmar Golombowski
发明人： Dietmar Golombowski
IPC分类号： B32B37/12 , C08L75/04 , C09J175/04 , B32B37/02 , B32B37/14
CPC分类号： C09J175/08 , C08G18/0885 , C08G18/10 , C08G18/12 , C08G18/4812 , C08G18/632 , C08G18/3876
摘要： The invention is a two-part composition comprising: A) in one part (i) one or more isocyanate functional prepolymers; and B) in a second part (ii) one or more compounds having isocyanate reactive groups; (iii) one or more fillers selected such that the composition is nonconductive; (iv) one or more catalysts for the reaction of isocyanate groups with active hydrogen containing compounds wherein either or both of the one or more isocyanate functional prepolymers and the one or more compounds having isocyanate reactive groups have solid organic particles grafted thereto such that the composition contains from about 6 to about 13 percent by weight of the total composition of solid organic particles. In a preferred embodiment, the second part comprises from about 35 to about 65 percent by weight of one or more compound having isocyanate reactive groups which have solid organic particles grafted to the backbone. In another preferred embodiment, the one or more isocyanate functional prepolymers comprise about 14 to about 20 percent by weight of solid organic particles grafted to the backbone of the prepolymers. In another preferred embodiment, the solid particles comprise a thermoplastic polymer or rubber-modified thermoplastic polymer.
摘要翻译：本发明是两部分组合物，其包含：A）一部分（i）一种或多种异氰酸酯官能预聚物; 和B）在第二部分（ii）一种或多种具有异氰酸酯反应性基团的化合物; （iii）选择一种或多种填料使得该组合物不导电; （iv）用于使异氰酸酯基团与含活性氢化合物反应的一种或多种催化剂，其中一种或多种异氰酸酯官能预聚物和一种或多种具有异氰酸酯反应性基团的化合物中的一种或两种具有接枝到其上的固体有机颗粒，使得组合物含有总组合物的约6至约13重量％的固体有机颗粒。在优选的实施方案中，第二部分包含约35至约65重量％的一种或多种具有异氰酸酯反应性基团的化合物，其具有接枝到主链上的固体有机颗粒。在另一个优选的实施方案中，一种或多种异氰酸酯官能预聚物包含约14至约20重量％的接枝到预聚物主链上的固体有机颗粒。在另一个优选的实施方案中，固体颗粒包含热塑性聚合物或橡胶改性的热塑性聚合物。

7. 发明申请

US20110059319A1 METHOD FOR SPRAY FORMING HIGH MODULUS POLYURETHANE STRUCTURES 审中-公开
标题翻译：喷射形成高模量聚氨酯结构的方法
公开(公告)号：US20110059319A1
公开(公告)日：2011-03-10
申请号：US12947998
申请日：2010-11-17
申请人： Robert Michael Raday
发明人： Robert Michael Raday
IPC分类号： B32B27/06 , B05D3/00 , B05D5/00 , C09D175/04 , C08K3/26 , C08K3/22 , C08K3/30
CPC分类号： B29C70/025 , B05D1/02 , B05D1/34 , B05D7/52 , B05D2503/00 , B29C70/305 , B29C70/48 , B29K2075/00 , C08G18/0885 , C08G18/4825 , C08G18/5045 , C08G18/6674 , C08G18/6696 , C08G18/7671 , C08G2120/00 , C08J7/04 , C08J7/047 , C08J2475/00 , C08J2475/04 , C08K7/14 , Y10T428/31554
摘要： Sprayable polyurethane compositions contain particulate filler in both polyol and isocyanate components for a total content of minimally 20 weight percent of particulate filler. The isocyanate component is stable with respect to storage, and composite structures prepared therefrom exhibit high modulus and can be used as replacements for unsaturated polyester systems.
摘要翻译：可喷涂的聚氨酯组合物含有多元醇和异氰酸酯组分中的颗粒填料，总含量最低为20重量％的颗粒填料。异氰酸酯组分相对于储存是稳定的，并且由其制备的复合结构显示高模量并且可以用作不饱和聚酯体系的替代物。

8. 发明申请

US20100292384A1 URETHANE ADHESIVE COMPOSITION 有权
标题翻译： URETHANE粘合剂组合物
公开(公告)号：US20100292384A1
公开(公告)日：2010-11-18
申请号：US12681109
申请日：2008-09-10
申请人： Yoshinori Igarashi , Koichiro Higasa
发明人： Yoshinori Igarashi , Koichiro Higasa
IPC分类号： C08K3/34 , C08K3/26
CPC分类号： C08G18/0885 , C08G18/10 , C08G18/4808 , C08G18/4833 , C08G18/7664 , C08G18/797 , C08K3/013 , C08K3/26 , C09J175/04 , C09J175/08 , C08G18/48 , C08G18/6674
摘要： A urethane adhesive composition includes a first liquid and a second liquid, the first liquid containing a prepolymer obtained by reacting a polyisocyanate and a high-molecular-weight polyol (I), and at least one filler selected from talc and calcium carbonate, and containing 20 parts by mass or more of talc, 0 to 40 parts by mass of calcium carbonate, and 10 parts by mass or more of zeolite based on 100 parts by mass of the polyisocyanate, the high-molecular-weight polyol (I), and the prepolymer in total, the second liquid containing a high-molecular-weight polyol (II) and a low-molecular-weight polyol, the ratio of the number of moles of hydroxyl groups derived from the low-molecular-weight polyol to the total number of moles of hydroxyl groups derived from the high-molecular-weight polyol (I) and the high-molecular-weight polyol (II) being four or more.
摘要翻译：聚氨酯粘合剂组合物包括第一液体和第二液体，所述第一液体含有通过使多异氰酸酯和高分子量多元醇（I）反应获得的预聚物和至少一种选自滑石和碳酸钙的填料，并且含有 20质量份以上的滑石，0〜40质量份的碳酸钙，10质量份以上的沸石，相对于100质量份的多异氰酸酯，高分子量多元醇（I）和总共预聚物，含有高分子量多元醇（II）和低分子量多元醇的第二液体，由低分子量多元醇衍生的羟基的摩尔数与总共衍生自高分子量多元醇（I）和高分子量多元醇（II）的羟基的摩尔数为4以上。

9. 发明申请

US20100098934A1 ELASTOMERIC URETHANE COMPOSITION 失效
标题翻译：弹性尿素组合物
公开(公告)号：US20100098934A1
公开(公告)日：2010-04-22
申请号：US11178062
申请日：2005-07-08
申请人： Robert B. Stearns
发明人： Robert B. Stearns
IPC分类号： B32B27/08 , C08J9/06
CPC分类号： C08G18/0885 , B32B5/18 , B32B7/02 , B32B27/065 , B32B27/18 , B32B27/20 , B32B27/22 , B32B27/26 , B32B27/40 , B32B2266/0278 , B32B2307/50 , B32B2307/54 , B32B2307/546 , B32B2307/554 , B32B2307/5825 , B32B2605/00 , B32B2605/003 , C08G18/222 , C08G18/2825 , C08G18/4841 , C08G18/6674 , Y10T428/249991 , Y10T428/31554
摘要： An elastomeric urethane composition that is substantially free of particulates includes the reaction product of a resin composition, including a polyetherol, and an isocyanate. The resin composition and the isocyanate are reacted, in the presence of a catalyst, to form a polyurethane elastomer. The catalyst includes a metal selected from the group of titanium, zirconium and hafnium. The elastomeric urethane composition is used in a method of making an article in a mold. The method includes reacting the resin composition and the isocyanate to form the elastomeric urethane composition, applying the elastomeric urethane composition to the mold cavity, and allowing the elastomeric urethane composition to cure to form a first layer. The method also includes applying a urethane composition, different from the elastomeric urethane composition, to the mold to form a second layer. The method further includes curing the article in the mold and de-molding the article from the mold.
摘要翻译：基本上不含微粒的弹性体氨基甲酸酯组合物包括含有聚己二酸酯和异氰酸酯的树脂组合物的反应产物。在催化剂存在下使树脂组合物和异氰酸酯反应形成聚氨酯弹性体。催化剂包括选自钛，锆和铪的金属。弹性聚氨酯组合物用于将制品制成模具的方法。该方法包括使树脂组合物与异氰酸酯反应以形成弹性聚氨酯组合物，将弹性聚氨酯组合物施加到模腔，并使弹性聚氨酯组合物固化形成第一层。该方法还包括将不同于弹性聚氨酯组合物的聚氨酯组合物施加到模具以形成第二层。该方法还包括固化模具中的制品并将模具从模具中脱模。

10. 发明授权

US07691481B2 Composite article 有权
标题翻译：综合文章
公开(公告)号：US07691481B2
公开(公告)日：2010-04-06
申请号：US11224263
申请日：2005-09-12
申请人： Calvin T. Peeler , Michael C. May , Theresa A. Howard
发明人： Calvin T. Peeler , Michael C. May , Theresa A. Howard
IPC分类号： B32B27/28 , B32B27/40 , B32B27/30 , B32B27/00 , E04H4/00 , A47K3/00 , B63B17/00
CPC分类号： C08J7/04 , C08G18/0885 , C08G18/6674 , C08J2333/06 , C09D175/04 , Y10T428/24736 , Y10T428/31504 , Y10T428/31551 , Y10T428/31573 , Y10T428/31576
摘要： A composite article includes an acrylic layer, a UV-cured layer formed from a UV-curable composition, and a polyurethane backing layer. A method of forming the composite article includes applying the UV-curable composition to the acrylic layer such that the composition is between the acrylic layer and the polyurethane backing layer to enhance bonding between these layers. The UV-curable composition includes at least one monomer which is an ethylenically unsaturated methacrylate monomer, an ethylenically unsaturated acrylate monomer, or both. The at least one monomer has a hydroxy functional group. The monomer is compatible with the acrylic layer and the hydroxy functional group of the monomer is reactive with a polyisocyanate from the polyurethane backing layer. The UV-curable composition also includes a curing initiator that is reactive with the monomer. Upon exposure of the UV-curable composition to UV electromagnetic radiation, the curing initiator enables the composition to cure to the acrylic layer.
摘要翻译：复合制品包括丙烯酸层，由UV可固化组合物形成的UV固化层和聚氨酯背衬层。形成复合制品的方法包括将UV可固化组合物施加到丙烯酸层，使得组合物在丙烯酸层和聚氨酯背衬层之间以增强这些层之间的粘合。 UV可固化组合物包括至少一种单体，其是烯键式不饱和甲基丙烯酸酯单体，烯属不饱和丙烯酸酯单体或两者。所述至少一种单体具有羟基官能团。单体与丙烯酸层相容，单体的羟基官能团与聚氨酯背衬层的多异氰酸酯反应。 UV可固化组合物还包括与单体反应的固化引发剂。当UV可固化组合物暴露于UV电磁辐射时，固化引发剂使组合物固化成丙烯酸层。

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